期刊
GREEN CHEMISTRY
卷 20, 期 15, 页码 3457-3462出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8gc00740c
关键词
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资金
- NSFC [21633013, 91745106]
- National Key Research and Development Program of China [2017YFA0403100]
- Key Research Program of Frontier Sciences of CAS [QYZDJ-SSW-SLH051]
Herein, surprising results for bulk Pd-catalyzed carbonylation reactions are presented. Three types of carbonylation reactions can be realized efficiently under organic ligand-free conditions, namely, hydroaminocarbonylation of olefins, aminocarbonylation of aryl iodides and oxidative carbonylation of amines, which almost cover all the known mechanisms in carbonylation reactions. Notably, the bulk Pd catalyst system exhibited better catalytic activity than the classical homogeneous PdCl2/(2-OMePh)(3)P catalyst system. This study will create a momentous and new field of green carbonylation reactions.
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