期刊
GREEN CHEMISTRY
卷 20, 期 11, 页码 2611-2623出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7gc03397d
关键词
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资金
- Spanish Ministry of Economy and Competitiveness (Severo Ochoa) [CTQ2015-69563-CO2-R1]
- Spanish Ministry of Economy and Competitiveness (Grapas)
- UEFISCDI [PN-III-P4-ID-PCE-2016-0146, 121/2017]
- [PN 16 47 01 04]
H2 plasma has been used to generate carbon vacancies on reduced graphene oxide to increase its catalytic activity as a hydrogenation catalyst. A relationship between the power of the plasma treatment and the exposure time with the activity of the material was observed for CvC double bond hydrogenation. The activity data in the case of 1-octene, showing skeletal isomerization besides hydrogenation, indicate that H2 plasma treatment can introduce hydrogenating and acid sites rendering a bifunctional catalyst that is reminiscent of the activity of noble metals supported on acid supports.
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