期刊
FUEL PROCESSING TECHNOLOGY
卷 131, 期 -, 页码 175-181出版社
ELSEVIER
DOI: 10.1016/j.fuproc.2014.11.011
关键词
Lignin; Alkaline hydrogen peroxide; Giant reed; Miscanthus; DFRC; H-1-C-13 HSQC-NMR; P-31-NMR
资金
- MIUR [PON01_01966/2]
Separation of water-soluble lignins from lignocellulosic biomass provides a new and still poorly exploited feed-stock to increase the sustainability of biorefineries. We applied derivatization followed by a reductive cleavage (DFRC) method, 2D-HSQC-NMR, and (PNMR)-P-31 after P-31-labeling, to investigate molecular composition in water-soluble lignins obtained by alkaline oxidation from three biomass materials for energy (miscanthus, giant reed and an industrially pre-treated giant reed). Chromatographic identification of lignin products cleaved by DFRC showed a large predominance of guaiacyl (G) units in all biomasses and a lesser abundance of syringyl (S) and p-coumaryl (P) monomers. Our S/G ratios disagree with those reported in literature by other lignin separation methods. Carboxyl functions (ferulic and pcoumaric acids) were revealed by heterocorrelated H-1-C-13 HSQC-NMR, and confirmed by P-31-NMR spectra of (31) P-labeled lignin molecules. An understanding of molecular composition of water-soluble lignins from biomass sources for energy is essential for lignin most efficient exploitation in either industrial or agricultural applications. (C) 2014 Elsevier B.V. All rights reserved.
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