期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 7, 页码 885-889出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201800042
关键词
Metal-organic frameworks; Mixed-metal strategy; Adsorption; Nickel; Zinc
资金
- U.S. Department of Energy (DOE), ARPA-E Building Energy Efficiency Through Innovative Thermodevices (BEETIT) program
- U.S. Department of Energy (DOE), Energy Efficiency and Renewable Energy's Geothermal Technologies Office (GTO)
- U.S. Department of Energy (DOE) [DE-AC05-76RL01830]
- Materials Synthesis and Simulation Across Scales (MS3 Initiative)
The mixed-metal strategy, by which a MOF framework with two different metal nodes was prepared, was utilized with MOF-74 for potential adsorption chiller applications. The Ni salt precursor was partially replaced during synthesis with the relatively inexpensive Zn salt. The bimetallic MOF-74 containing only a fraction of Ni was shown to provide efficient H2O adsorption performance, while utilizing the more inexpensive Zn salt thus significantly mitigated the material costs of industrial scale synthesis/applications.
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