期刊
FUEL
卷 160, 期 -, 页码 282-290出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2015.07.107
关键词
Polyhydroxybutyrate; Solid phosphoric acid; Biofuels; Bio-based aromatics; Renewable gasoline
资金
- Office of Naval Research, USA [N00014-13-1-0463]
Polyhydroxybutyrate (PHB) is an energy storage material formed from renewable feedstock in many bacterial species. The biopolyester (C4H6O2)(n) was degraded, deoxygenated and reformed into hydrocarbon oil (C-6-C-18) on solid phosphoric acid (SPA) in one-pot reaction. The reaction started at 213 degrees C and completed below 240 degrees C as measured with a differential scanning calorimeter. In addition to the oil, other products included carbon dioxide (CO2), propylene (C3H6), water (H2O) and some char-like solid. The mass yields in a typical reaction were determined with a total mass recovery of 94 wt%. About 80% of oxygen in PHB was removed as CO2 via decarboxylation. By using a gas chromatograph-mass spectrometer, the oil composition was analyzed according to the chemical structure and carbon number of major compounds. In contrast to conventional biofuels derived from plant biomass, the PHB-oil has a high content of alkenes or aromatics, depending on the solid acid catalyst. The catalyst properties that affected the reaction include the calcination temperature in catalyst preparation, the catalyst dosage in the reaction, the total acid and free acid contents of fresh or used catalyst, and working time when the catalyst was repeatedly reused. The hydrocarbon oil (30 wt% yield) was separated into two fractions according to their boiling temperature range: a light oil (bp 40-240 degrees C) with 23 wt% yield and a heavy oil (bp 240-310 degrees C) with 7 wt% yield. The light oil has the same elemental composition and high heating value (HHV 41.4/kg) of a commercial gasoline and the heavy oil (HHV 38.4 MJ/kg) has the similar elemental composition of biodiesel. The oil is a good source of bio-based alkenes and aromatics that can improve the performance of bio-based fuels in modern motor engines. (C) 2015 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
Article
Energy & Fuels
Preparation of surface modified nano-hydrotalcite and its applicaiton as a flow improver for crude oil
Yingna Du, Chen Huang, Wei Jiang, Qiangwei Yan, Yongfei Li, Gang Chen
Summary: In this study, anionic surfactants modified hydrotalcite was used as a flow improver for crude oil under low-temperature conditions. The modified hydrotalcite showed a significant viscosity reduction effect on crude oil. The mechanism of the modified hydrotalcite on viscosity and pour point of crude oil was explored through characterization and analysis of the modified hydrotalcite and oil samples.
FUEL (2024)
Article
Energy & Fuels
Effect of incorporated hybrid MIL-53(Al) and MWCNT into PES membrane for CO2/CH4 and CO2/N2 separation
Mohammad Saeid Rostami, Mohammad Mehdi Khodaei
Summary: In this study, a hybrid structure, MIL-53(Al)@MWCNT, was synthesized by combining MIL-53(Al) particles and -COOH functionalized multi-walled carbon nanotube (MWCNT). The hybrid structure was then embedded in a polyethersulfone (PES) polymer matrix to prepare a mixed matrix membrane (MMM) for CO2/CH4 and CO2/N2 separation. The addition of MWCNTs prevented MIL-53(Al) aggregation, improved membrane mechanical properties, and enhanced gas separation efficiency.
FUEL (2024)
Article
Energy & Fuels
Phase behaviour and physical properties of dimethyl ether (DME)/flue gas/ water/heavy oil systems under reservoir conditions
Yunlong Li, Desheng Huang, Xiaomeng Dong, Daoyong Yang
Summary: This study develops theoretical and experimental techniques to determine the phase behavior and physical properties of DME/flue gas/water/heavy oil systems. Eight constant composition expansion (CCE) tests are conducted to obtain new experimental data. A thermodynamic model is used to accurately predict saturation pressure and swelling factors, as well as the phase boundaries of N2/heavy oil systems and DME/CO2/heavy oil systems, with high accuracy.
FUEL (2024)
Article
Energy & Fuels
Comparison of CO2 absorption in DETA solution and [bmim]-[PF6] using thermodynamic and process modelling
Morteza Afkhamipour, Ebad Seifi, Arash Esmaeili, Mohammad Shamsi, Tohid N. Borhani
Summary: Non-conventional amines are being researched worldwide to overcome the limitations of traditional amines like MEA and MDEA. Adequate process and thermodynamic models are crucial for understanding the applicability and performance of these amines in CO2 absorption, but studies on process modeling for these amines are limited. This study used rate-based modeling and Deshmukh-Mather method to model CO2 absorption by DETA solution in a packed column, validated the model with experimental data, and conducted a sensitivity analysis of mass transfer correlations. The study also compared the CO2 absorption efficiency of DETA solution with an ionic solvent [bmim]-[PF6] and highlighted the importance of finding optimum operational parameters for maximum absorption efficiency.
FUEL (2024)
Article
Energy & Fuels
Interfacial tension of smart water and various crude oils
Arastoo Abdi, Mohamad Awarke, M. Reza Malayeri, Masoud Riazi
Summary: The utilization of smart water in EOR operations has gained attention, but more research is needed to understand the complex mechanisms involved. This study investigated the interfacial tension between smart water and crude oil, considering factors such as salt, pH, asphaltene type, and aged smart water. The results revealed that the hydration of ions in smart water plays a key role in its efficacy, with acidic and basic asphaltene acting as intrinsic surfactants. The pH also influenced the interfacial tension, and the aged smart water's interaction with crude oil depended on asphaltene type, salt, and salinity.
FUEL (2024)
Article
Energy & Fuels
Co-based metal-organic frameworks confined N-hydroxyphthalimide for enhancing aerobic desulfurization of diesel fuels
Dongao Zhu, Kun Zhu, Lixian Xu, Haiyan Huang, Jing He, Wenshuai Zhu, Huaming Li, Wei Jiang
Summary: In this study, cobalt-based metal-organic frameworks (Co-based MOFs) were used as supports and co-catalysts to confine the NHPI catalyst, solving the leaching issue. The NHPI@Co-MOF with carboxyl groups exhibited stronger acidity and facilitated the generation of active oxygen radicals O2•, resulting in enhanced catalytic activity. This research provides valuable insights into the selection of suitable organic linkers and broadens the research horizon of MOF hybrids in efficient oxidative desulfurization (ODS) applications.
FUEL (2024)
Article
Energy & Fuels
Influence of carbon-coated zero-valent iron-based nanoparticle concentration on continuous photosynthetic biogas upgrading
Edwin G. Hoyos, Gloria Amo-Duodu, U. Gulsum Kiral, Laura Vargas-Estrada, Raquel Lebrero, Rail Munoz
Summary: This study investigated the impact of carbon-coated zero-valent nanoparticle concentration on photosynthetic biogas upgrading. The addition of nanoparticles significantly increased microalgae productivity and enhanced nitrogen and phosphorus assimilation. The presence of nanoparticles also improved the quality of biomethane produced.
FUEL (2024)
Article
Energy & Fuels
Effect of aqueous phase recycling on iron evolution and environmental assessment during hydrothermal carbonization of dyeing sludge
Yao Xiao, Asma Leghari, Linfeng Liu, Fangchao Yu, Ming Gao, Lu Ding, Yu Yang, Xueli Chen, Xiaoyu Yan, Fuchen Wang
Summary: Iron is added as a flocculant in wastewater treatment and the hydrothermal carbonization (HTC) of sludge produces wastewater containing Fe. This study investigates the effect of aqueous phase (AP) recycling on hydrochar properties, iron evolution and environmental assessment during HTC of sludge. The results show that AP recycling process improves the dewatering performance of hydrochar and facilitates the recovery of Fe from the liquid phase.
FUEL (2024)
Article
Energy & Fuels
Investigation on the lower flammability limit and critical inhibition concentration of hydrogen under the influence of inhibitors
He Liang, Tao Wang, Zhenmin Luo, Jianliang Yu, Weizhai Yi, Fangming Cheng, Jingyu Zhao, Xingqing Yan, Jun Deng, Jihao Shi
Summary: This study investigated the influence of inhibitors (carbon dioxide, nitrogen, and heptafluoropropane) on the lower flammability limit of hydrogen and determined the critical inhibitory concentration needed for complete suppression. The impact of inhibitors on explosive characteristics was evaluated, and the inhibitory mechanism was analyzed with chemical kinetics. The results showed that with the increase of inhibitor quantity, the lower flammability limit of hydrogen also increased. The research findings can contribute to the safe utilization of hydrogen energy.
FUEL (2024)
Article
Energy & Fuels
Phosphotungstic acid supported on Zr-SBA-15 as an efficient catalyst for one-pot conversion of furfural to ?-valerolactone
Zonghui Liu, Zhongze Zhang, Yali Zhou, Ziling Wang, Mingyang Du, Zhe Wen, Bing Yan, Qingxiang Ma, Na Liu, Bing Xue
Summary: In this study, high-performance solid catalysts based on phosphotungstic acid (HPW) supported on Zr-SBA-15 were synthesized and evaluated for the one-pot conversion of furfural (FUR) to γ-valerolactone (GVL). The catalysts were characterized using various techniques, and the ratio of HPW and Zr was found to significantly affect the selectivity of GVL. The HPW/Zr-SBA-15 (2-4-15) catalyst exhibited the highest GVL yield (83%) under optimized reaction conditions, and it was determined that a balance between Bronsted acid sites (BAS) and Lewis acid sites (LAS) was crucial for achieving higher catalytic performance. The reaction parameters and catalyst stability were also investigated.
FUEL (2024)
Article
Energy & Fuels
Experimental study of droplet vaporization for conventional and renewable transportation fuels: Effects of physical properties and chemical composition
Michael Stoehr, Stephan Ruoff, Bastian Rauch, Wolfgang Meier, Patrick Le Clercq
Summary: As part of the global energy transition, an experimental study was conducted to understand the effects of different fuel properties on droplet vaporization for various conventional and alternative fuels. The study utilized a flow channel to measure the evolution of droplet diameters over time and distance. The results revealed the temperature-dependent effects of physical properties, such as boiling point, liquid density, and enthalpy of vaporization, and showed the complex interactions of preferential vaporization and temperature-dependent influences of physical properties for multi-component fuels.
FUEL (2024)
Article
Energy & Fuels
An experimental and modeling study on the oxidation of ammonia-methanol mixtures in a jet stirred reactor
Yuan Zhuang, Ruikang Wu, Xinyan Wang, Rui Zhai, Changyong Gao
Summary: Through experimental validation and optimization of the chemical kinetic model, it was found that methanol can accelerate the oxidation reaction of ammonia, and methanol can be rapidly oxidized at high concentration. HO2 was found to generate a significant amount of OH radicals, facilitating the oxidation of methanol and ammonia. Rating: 7.5/10.
FUEL (2024)
Article
Energy & Fuels
Improving the biodiesel combustion and emission characteristics in the lean pre-vaporized premixed system using diethyl ether as a fuel additive
Radwan M. EL-Zohairy, Ahmed S. Attia, A. S. Huzayyin, Ahmed I. EL-Seesy
Summary: This paper presents a lab-scale experimental study on the impact of diethyl ether (DEE) as an additive to waste cooking oil biodiesel with Jet A-1 on combustion and emission features of a swirl-stabilized premixed flame. The addition of DEE to biodiesel significantly affects the flame temperature distribution and emissions. The W20D20 blend of DEE, biodiesel, and Jet A-1 shows similar flame temperature distribution to Jet A-1 and significantly reduces UHC, CO, and NOx emissions compared to Jet A-1.
FUEL (2024)
Article
Energy & Fuels
Condensation characteristics of ammonia vapor during supersonic separation: A novel approach to ammonia-hydrogen separation
Jiang Bian, Ziyuan Zhao, Yang Liu, Ran Cheng, Xuerui Zang, Xuewen Cao
Summary: This study presents a novel method for ammonia separation using supersonic flow and develops a mathematical model to investigate the condensation phenomenon. The results demonstrate that the L-P nucleation model accurately characterizes the nucleation process of ammonia at low temperatures. Numerical simulations also show that increasing pressure and concentration can enhance ammonia condensation efficiency.
FUEL (2024)
Article
Energy & Fuels
Multivariate time series prediction for CO2 concentration and flowrate of flue gas from biomass-fired power plants
Shiyuan Pan, Xiaodan Shi, Beibei Dong, Jan Skvaril, Haoran Zhang, Yongtu Liang, Hailong Li
Summary: Integrating CO2 capture with biomass-fired combined heat and power (bio-CHP) plants is a promising method for achieving negative emissions. This study develops a reliable data-driven model based on the Transformer architecture to predict the flowrate and CO2 concentration of flue gas in real time. The model validation shows high prediction accuracy, and the potential impact of meteorological parameters on model accuracy is assessed. The results demonstrate that the Transformer model outperforms other models and using near-infrared spectral data as input features improves the prediction accuracy.
FUEL (2024)
分享论文
