期刊
ENZYME AND MICROBIAL TECHNOLOGY
卷 112, 期 -, 页码 6-13出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.enzmictec.2018.01.007
关键词
Lignin modification; Chemoenzymatic epoxidation; Epoxy resins; Candida antarctica lipase B
资金
- CONICYT [21130772]
An innovative chemoenzymatic catalytic system for functionalizing lignin from Organosolv and Kraft pulping processes to obtain oxirane rings was investigated. Novozym435 (immobilized C. antarctica lipase B: Call) was used to catalyze the peroxidation of caprylic acid to peroxycaprylic acid, which in turn reacted with unsaturated C-C bonds to form the oxirane ring. The conversion of OH groups to oxirane rings (epoxides) reached 90% and 55% after 12 h for the two processes, respectively. The residual enzyme activity over the time course of the reactions indicated transient denaturing due to association with the lignin substrate (10-50%) as well as irreversible denaturation due to exposure to hydrogen peroxide. Functionalized lignin has potential applications in the production of epoxy adhesive resins, and chemoenzymatic synthesis represents a greener pathway to this synthesis.
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