期刊
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
卷 25, 期 28, 页码 27704-27723出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11356-018-1913-6
关键词
Diclofenac; Carbamazepine; Pharmaceutical compounds; Advanced oxidation processes; Radiolytic decomposition; Advanced oxidation-reduction processes
资金
- Polish National Center of Science (NCN) [2014/15/B/ST4/04601]
Carbamazepine and diclofenac are two examples of drugs with widespread geographical and environmental media proliferation that are poorly removed by traditional wastewater treatment processes. Advanced oxidation processes (AOPs) have been proposed as alternative methods to remove these compounds in solution. AOPs are based on a wide class of powerful technologies, including UV radiation, ozone, hydrogen peroxide, Fenton process, catalytic wet peroxide oxidation, heterogeneous photocatalysis, electrochemical oxidation and their combinations, sonolysis, and microwaves applicable to both water and wastewater. Moreover, processes rely on the production of oxidizing radicals (center dot OH and others) in a solution to decompose present pollutants. Water radiolysis-based processes, which are an alternative to the former, involve the use of concentrated energy (beams of accelerated electrons or -rays) to split water molecules, generating strong oxidants and reductants (radicals) at the same time. In this paper, the degradation of carbamazepine and diclofenac by means of all these processes is discussed and compared. Energy and byproduct generation issues are also addressed.
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