期刊
DYES AND PIGMENTS
卷 149, 期 -, 页码 188-192出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2017.09.064
关键词
Supramolecular polymer; Host-guest interaction; Pseudorotaxane; Photo-switchable
资金
- National Basic Research 973 Program [2013CB733700]
- National Natural Science Foundation of China [21302056, 21421004, 21476075]
- Fundamental Research Funds for the Central Universities [222201717003]
A novel light-driven noncovalent-covalent switchover linear supramolecular polymer was constructed in aqueous solution via the host-guest molecular recognition of gamma-cyclodextrin and cucurbit[7]uril-based pseudo[3]-rotaxane containing two photoresponsive coumarin moieties. This supramolecular polymer also could convert between noncovalent polymers and corresponding covalent polymers due to the photo-induced reversible dimerization and cleavage properties of the coumarin moiety in the cavity of gamma-cyclodextrin. So the fabrication of linear supramolecular polymer based on the molecular shuttle could provide more possibility for increasing the performance of supramolecular polymer with well-defined functionalities.
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