4.7 Article

A multifunctional Eu-CP as a recyclable luminescent probe for the highly sensitive detection of Fe3+/Fe2+, Cr2O72-, and nitroaromatic explosives

期刊

DALTON TRANSACTIONS
卷 47, 期 22, 页码 7480-7486

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt01518j

关键词

-

资金

  1. National Natural Science Foundation of China [21431002]

向作者/读者索取更多资源

A novel 2D lanthanide coordination polymer (Eu-CP (1)) based on a 3-bis(3-carboxyphenyl)imidazolium (L) ligand was successfully assembled through a solvothermal method. Luminescence tests indicate that 1 has excellent selectivity and sensitivity to detect Fe3+/Fe2+, Cr2O72-, and a series of nitroaromatic explosives. Interestingly, 1 can effectively distinguish Cr-VI anions (CrO42-/Cr2O72-), which is difficult for most of the reported CPs. Furthermore, in the detection process, 1 can be simply and quickly regenerated and reused at least five times. As far as we know, 1 is the first multifunctional Eu-CP used as a luminescent probe to detect Fe3+/Fe2+, Cr2O72-, and a series of nitroaromatic explosives (NAEs) based on the imidazolium derivative.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Inorganic & Nuclear

A Discrete 3d-4f Metallacage as an Efficient Catalytic Nanoreactor for a Three-Component Aza-Darzens Reaction

Shengbin Zhou, Zhichao Zhang, Dongjie Bai, Jingzhe Li, Xiang Cui, Zhichuan J. Xu, Yu Tang, Xiaoliang Tang, Weisheng Liu

Summary: The exploration and development of coordination nanocages have significant applications in the field of molecular recognition, supramolecular catalysis, and molecular self-assembly. In this study, a unique 3d-4f metallacage with a stable structure was constructed using a semirigid and nonsymmetric bridging ligand. The metallacage acts as a nanoreactor and has active bimetallic lanthanide cluster units. The experiments demonstrate that the metallacage shows excellent catalytic activity and specificity in three-component aza-Darzens reactions.

INORGANIC CHEMISTRY (2022)

Article Chemistry, Inorganic & Nuclear

Multi-mode anti-counterfeiting guarantees from a single material CaCd2Ga2Ge3O12:Tb3+,Yb3+ - two stimuli-responsive and four-state emission

Zhuobing Wang, Liwei Yang, Zhenbin Wang, Jiajia Cao, Cunhua Ma, Mingjin Zhang, Weisheng Liu

Summary: Multi-mode anti-counterfeiting is achieved using a single luminescent material CaCd2Ga2Ge3O12:Tb3+,Yb(3+) via high-temperature solid-state reaction. The material exhibits excellent photoluminescence, afterglow, thermoluminescence, and up-conversion luminescence, attributed to Tb3+ transitions. Photo-stimuli and thermo-stimuli responsiveness are achieved through co-doping with Yb3+. The material is used to prepare optical devices with different luminescence modes.

DALTON TRANSACTIONS (2023)

Article Chemistry, Inorganic & Nuclear

Multimodal and Multicolor Anti-counterfeiting Realized in CaCd2Ga2Ge3O12 with a Single Activator of Mn2+

Mi Wang, Xinxing Ming, Jiajia Cao, Liwei Yang, Zhenbin Wang, Cunhua Ma, Mingjin Zhang, Weisheng Liu

Summary: The growing importance of information security and authentication has posed new requirements and challenges for luminescent materials and anti-counterfeiting technologies. This study successfully designed and synthesized a highly efficient multicolor and multimodal luminescence material CaCd2Ga2Ge3O12:Mn2+. By increasing the dopant concentration of Mn2+, the material exhibited tunable emission colors from blue to cyan to yellow under UV lamp, and strong yellow emission under afterglow and thermoluminescence luminescence modes. The material was used to create anti-counterfeiting ink with excellent multicolor properties, contributing to the development of luminescent anti-counterfeiting materials for security purposes.

INORGANIC CHEMISTRY (2023)

Article Nanoscience & Nanotechnology

Ratiometric Luminescent Thermometer Based on the Lanthanide Metal-Organic Frameworks by Thermal Curing

Huiru Guan, Mixiang Qi, Lifeng Shi, Weisheng Liu, Lizi Yang, Wei Dou

Summary: In this work, Tb-MOFs@TGIC composite was successfully prepared and exhibited enhanced fluorescence properties, quantum yield, lifetime, and thermal stability. The composite showed excellent temperature sensing properties in various temperature ranges and can be easily coated on different substrates, making it applicable for a wider temperature range measurement.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Nanoscience & Nanotechnology

Mesoporous Mixed-Metal-Organic Framework Incorporating a [Ru(Phen)3]2+ Photosensitizer for Highly Efficient Aerobic Photocatalytic Oxidative Coupling of Amines

Dongjie Bai, Jinlin Qiu, Jingzhe Li, Shengbin Zhou, Xiang Cui, Xiaoliang Tang, Yu Tang, Weisheng Liu, Banglin Chen

Summary: In this study, a photosensitizer-embedded heterometallic Ni(II)/Ru(II) meso-MOF (LTG-NiRu) was developed by integrating the intrinsic advantages of ruthenium-based photosensitizer and mesoporous metal-organic frameworks. LTG-NiRu exhibited exceptional activities for photocatalytic oxidative coupling reactions with high stability and reusability. It provides a potential platform for the synthesis of various chemicals on a gram-scale.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Chemistry, Inorganic & Nuclear

Construction of High Quantum Yield Lanthanide Luminescent MOF Platform by In Situ Doping and Its Temperature Sensing Performance

Shiying Liu, Wei Liu, Yiliang Sun, Weisheng Liu

Summary: The in situ doping method was used to construct Ln-MOFs with excellent luminescent properties. A novel Bi-MOF was constructed and doped with different lanthanide metal ions to achieve high luminescence quantum yields. The doped MOFs showed potential for temperature sensing and color change applications.

INORGANIC CHEMISTRY (2023)

Article Chemistry, Inorganic & Nuclear

Dual-Function Precious-Metal-Free Metal-Organic Framework for Photocatalytic Conversion and Chemical Fixation of Carbon Dioxide

Xiaoli Wang, Jingzhe Li, Manchang Kou, Wei Dou, Dongjie Bai, Xiaoliang Tang, Yu Tang, Weisheng Liu

Summary: This study developed a precious-metal-free and heterogeneous MOF catalyst with high activity and stability for the conversion of CO2. It can efficiently convert CO2 into formic acid under visible-light irradiation and synthesize cyclic carbonates in the absence of light.

INORGANIC CHEMISTRY (2023)

Article Optics

Opto-Mechano-Thermo-Sensitive Allochroic Luminescence Based on Solution-Grown Halide Double Perovskite Crystal

Peng Zhang, Wanying Xie, Zenggang Lin, Xiuxiang Huang, Yuzhu Yang, Weisheng Liu

Summary: In this study, multimodal luminescent Cs2Ag0.8Na0.2InCl6 perovskite material was successfully synthesized at a low reaction temperature, demonstrating long-persistent luminescence and multicolor luminescence in response to various types of excitations.

LASER & PHOTONICS REVIEWS (2023)

Article Chemistry, Inorganic & Nuclear

Insights into blue-light activated red-emitting persistent luminescence from Pr3+-doped phosphors

Zikai Meng, Zhen Guo, Jiajia Cao, Zihui Li, Jihua Zhu, Zhenbin Wang, Cunhua Ma, Mingjin Zhang, Weisheng Liu

Summary: In recent years, there have been significant advancements in the development and utilization of persistent luminescence materials that can be excited by blue light. However, the challenge of developing a highly efficient red-emitting persistent phosphor remains. This study successfully synthesized a novel blue-light excited red-emitting persistent phosphor CaCd2Ga2Ge3O12:Pr3+ and investigated its luminescence properties. This phosphor holds great promise for applications in AC-LEDs, bio-imaging, and other fields.

DALTON TRANSACTIONS (2023)

Article Chemistry, Inorganic & Nuclear

Co-doped long persistent luminescence materials LiSr3SiO4Cl3:Eu2+,Ln(3+) (Ln = Dy, Ho, Er): construction and verification of VRBE and HRBE scheme and their multifunctional applications

Yuanying Lin, Chengzhuo Ming, Zhenbin Wang, Bin Yu, Yuzhu Yang, Weisheng Liu

Summary: In this study, novel LPL materials LiSr3SiO4Cl3:Eu2+,Ln(3+) (Ln = Dy, Ho, Er) were synthesized at 650°C, which have the perfect trap depth for information storage. The host-referred and vacuum-referred binding energy of LSSOC were constructed and verified using the refined chemical shift model, optical spectroscopy, and thermoluminescence. LSSOC:Eu,Ho showed excellent LPL performance under partial 808 nm and 980 nm near infrared laser photo-stimulated luminescence or comprehensive thermally-stimulated luminescence.

INORGANIC CHEMISTRY FRONTIERS (2023)

Article Chemistry, Inorganic & Nuclear

Enhancement of the catalytic performance of UIO-66 for the CO2 synthesis of cyclic carbonate using natural nanomaterials as a carrier

Yunshuai Bi, Zibei Yao, Zhen Zhu, Weisheng Liu

Summary: This paper presents an efficient method for preparing composite catalysts using attapulgite as a carrier, which improves the CO2 catalytic performance of MOF materials. Attapulgite, with its excellent catalytic activity and unique nanorod shape, shows potential as a carrier material. The design of this nanocomposite catalyst provides a new pathway for CO2 capture and conversion, and offers development space for the synthesis of such materials.

DALTON TRANSACTIONS (2023)

Article Chemistry, Multidisciplinary

Mesoporous CeO2-supported ultrafine PdCu nanoparticle catalyst for selective hydrogenation of alkynols

Cheng Zhang, Yi Zheng, Jianfeng Li, Hongzhang Cao, Yanhui Xu, Weisheng Liu, Zhengping Dong

Summary: In this study, a sacrificial template strategy was used to prepare PdCu@CeO2 catalyst, which exhibited high selectivity and good recyclability in the selective hydrogenation of alkynol compounds. Introducing non-precious metallic Cu improved the selectivity of precious metal Pd catalysts. This research provides a feasible strategy for efficient selective hydrogenation of alkynols in the fine chemical industry.

REACTION CHEMISTRY & ENGINEERING (2023)

Article Chemistry, Inorganic & Nuclear

A COF template-derived mesoporous CeO2-supported Au nanoparticles catalyst for the oxidative esterification of benzaldehydes and benzyl alcohols

Cheng Zhang, Tianhang Huang, Jinhua Liang, Hongzhang Cao, Yanhui Xu, Weisheng Liu, Zhengping Dong

Summary: In this study, a mesoporous CeO2-supported Au nanoparticles catalyst was constructed using a covalent organic framework (COF) material and demonstrated excellent catalytic performance in the direct oxidative esterification of benzaldehydes and benzyl alcohols. The obtained catalyst achieved the synthesis of high-value-added aromatic esters under mild and green reaction conditions. Furthermore, the catalyst was recyclable.

DALTON TRANSACTIONS (2023)

Article Chemistry, Inorganic & Nuclear

Achieving excitation wavelength-power-dependent colorful luminescence via multiplexing of dual lanthanides in fluorine oxide particles for multilevel anticounterfeiting

Chenyang Zhao, Zikai Meng, Zhen Guo, Zhenbin Wang, Jiajia Cao, Jihua Zhu, Cunhua Ma, Mingjin Zhang, Weisheng Liu

Summary: The optical characteristics of multimode luminescent materials, such as photoluminescence, afterglow, and thermoluminescence, play important roles in optical data storage and anticounterfeiting. A highly integrated multimode and multicolor material has been developed, which shows excitation wavelength and power dependence. This material has been used to design a multilevel anticounterfeiting device. These findings provide unique insights for designing highly integrated multimode, multicolor luminescence materials and advanced anticounterfeiting technology.

DALTON TRANSACTIONS (2023)

Article Materials Science, Multidisciplinary

Achieving mechano-upconversion-downshifting-afterglow multimodal luminescence in Pr3+/Er3+ coactivated Ba2Ga2GeO7 for multidimensional anticounterfeiting

Pengxiang Pei, Kui Liu, Zhenghua Ju, Ruiping Wei, Weisheng Liu

Summary: Luminescent materials play a vital role in information encryption and anti-counterfeiting. However, the existing materials have limitations in terms of color and output. This study developed a multimodal luminescent material with adjustable color, variable excitation patterns and multitemporal features. The fabricated anticounterfeiting device based on this material achieved synchronous multidimensional information encryption and anti-counterfeiting, showing high-level security.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Chemistry, Inorganic & Nuclear

The impact of Lewis acid variation on reactions with di-tert-butyl diazo diesters

Vaibhav Bedi, Dipendu Mandal, Zahid Hussain, Shi-Ming Chen, Yile Wu, Zheng-Wang Qu, Stefan Grimme, Douglas W. Stephan

Summary: The reaction of (tBuO(2)CN)(2) with 9-BBN leads to the formation of a bicyclic heterocyclic compound, while its reactions with BF3 or [Et3Si][B(C6F5)(4)] result in the isolation of different compounds. Computational studies reveal that the steric and electronic properties of the Lewis acid are important in the formation of one of the compounds.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

Post-synthetic molecular modifications based on Schiff base condensation reactions for designing functional paddlewheel diruthenium(ii,ii) complexes

Chisa Itoh, Haruka Yoshino, Taku Kitayama, Wataru Kosaka, Hitoshi Miyasaka

Summary: A new synthetic route for constructing functional paddlewheel diruthenium(II,II) complexes was developed, utilizing Schiff base condensation reactions. The attached Schiff base groups significantly affected the electronic states of the resulting complexes, as revealed by cyclic voltammetry and DFT calculations.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

The pressure-stabilized polymorph of indium triiodide

Danrui Ni, Haozhe Wang, Xianghan Xu, Weiwei Xie, Robert J. Cava

Summary: A layered rhombohedral polymorph of indium(iii) triiodide is synthesized at high pressure and temperature. It has an orange color, which is different from ambient pressure InI3, which has a monoclinic molecular structure and a light-yellow color.

DALTON TRANSACTIONS (2024)

Review Chemistry, Inorganic & Nuclear

Unlocking the catalytic potential of gold(II) complexes: a comprehensive reassessment

Juan Carlos Perez-Sanchez, Raquel P. Herrera, M. Concepcion Gimeno

Summary: Gold(II) complexes have been less utilized in catalysis compared to their gold(I) and gold(III) counterparts. However, gold(II) complexes offer potential in homo-coupling and cross-coupling reactions, as they are more easily accessible through simplified oxidation and reduction processes. Gold(II) exhibits characteristics of both soft acid gold(I) and hard acid gold(III). This review explores the unique reactivity and potential applications of gold(II) species, highlighting their significance in catalytic transformations.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

Enhancing isoprene polymerization with high activity and adjustable monomer enchainment using cyclooctyl-fused iminopyridine iron precatalysts

Nighat Yousuf, Yanping Ma, Qaiser Mahmood, Wenjuan Zhang, Yizhou Wang, Hassan Saeed, Wen-Hua Sun

Summary: In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes were synthesized and used with methylaluminoxane for isoprene polymerization. The extent of steric hindrance of the ligand framework was found to significantly affect catalytic performance, with less hindrance leading to better activity and stability.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

Improving the performance of perovskite solar cells using a dual-hole transport layer

Chenghao Song, Huiwei Du, Menglei Xu, Jie Yang, Xinyu Zhang, Jungan Wang, Yuanfang Zhang, Chengjun Gu, Rui Li, Tao Hong, Jingji Zhang, Jiangying Wang, Yongchun Ye

Summary: This study improves the performance of perovskite solar cells by using a dual-hole transport layer strategy. This strategy enhances the charge transfer efficiency of the transport layer, reduces charge recombination, and improves the quality of the perovskite film layer. Ultimately, the stability of the device is enhanced.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

Aryl selenonium vs. aryl sulfonium counterions in polyoxometalate chemistry: the impact of Se+ cationic centers on the photocatalytic reduction of dichromate

Mahender Singh, Aakash Yadav, Ranjit Singh, Chullikkattil P. Pradeep

Summary: A new aryl selenonium polyoxometalate hybrid was developed and compared with an aryl sulfonium polyoxometalate hybrid in terms of their photocatalytic properties. It was found that the aryl selenonium hybrid exhibited better catalytic performance, which could be attributed to the larger atomic radii of selenium stabilizing the photogenerated electron-hole pair more efficiently. Additionally, the generation of elemental selenium through cleavage of C-Se bonds during catalysis was observed.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

Construction of core-shell CoSe2/ZnIn2S4 heterostructures for efficient visible-light-driven photocatalytic hydrogen evolution

Yuhan Xie, Boyu Dong, Xuemin Wang, Siyuan Wang, Jinxi Chen, Yongbing Lou

Summary: This study successfully fabricated visible-light-responsive three-dimensional core-shell CoSe2/ZnIn2S4 heterostructures and achieved attractive activity in photocatalytic hydrogen evolution. The presence of CoSe2 improved light absorption and accelerated charge transfer kinetics. The strong interaction between CoSe2 and ZnIn2S4 reduced charge recombination, further enhancing photocatalytic activity for hydrogen evolution.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

Promising TMDC-like optical and excitonic properties of the TiBr2 2H monolayer

Andre L. de O. Batista, Joao Marcos T. Palheta, Mauricio J. Piotrowski, Celso R. C. Rego, Diego Guedes-Sobrinho, Alexandre C. Dias

Summary: This study presents a simulation protocol that provides a solid foundation for exploring two-dimensional materials. Using the TiBr2 2H monolayer as an example, the study reveals its promising properties for optoelectronic and valleytronic applications, including its stability, spin-orbit coupling effects, and optical helicity selection rule.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

The {Cu2I2} cluster bearing metal organic frameworks: crystal structures and fluorescence detecting performances towards cysteine and explosive molecules

Jiang Jiang, Zi-Wei Li, Zhi-Zhuan Zhang, Bin Tan, Zhao-Feng Wu, Xiao-Ying Huang

Summary: In this work, two metal organic frameworks (MOFs) containing {Cu2I2} clusters, Eu-CuI-INA and Sr-K-CuI-INA, were synthesized and characterized. Both materials have a three-dimensional structure with {Cu2I2} clusters coordinated by INA(-) ligands and Eu3+ or Sr2+ ions. The Sr-K-CuI-INA material exhibited sensitive fluorescence sensing behaviors towards cysteine and nitro-bearing molecules, showing potential applications in bio and explosive molecule sensing. This work provides a good reference for designing fluorescent MOF probes containing CuI molecules.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

Coral-like CoSe2@N-doped carbon with a high initial coulombic efficiency as advanced anode materials for Na-ion batteries

Zhiya Lin, Jiasheng Wu, Qianwen Ye, Yulong Chen, Hai Jia, Xiaohui Huang, Shaoming Ying

Summary: Na-ion batteries (NIBs) have attracted great interest as a potential technology for grid-scale energy storage due to the wide distribution, low cost, and environmental friendliness of sodium resources. However, their implementation is hindered by low rate capability and cycling stability caused by the large ionic size of Na+. In this study, a three-dimensional nanoarchitectured coral-like CoSe2@N-doped carbon (CL-CoSe2@NC) was synthesized, and it exhibited improved sodium storage properties with better electrode kinetics and a stable SEI film.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

Mechanism of photocatalytic CO2 reduction to HCO2H by a robust multifunctional iridium complex

Ya-Qiong Zhang, Yu Zhang, Guoping Zeng, Rong-Zhen Liao, Man Li

Summary: The mechanism and selectivity of CO2 reduction under visible light were investigated using density functional calculations. The results showed that a tetradentate PNNP-type Iridium(III) complex exhibited high activity and selectivity in the reaction.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

Enhanced thermoelectric properties of In-filled Co4Sb12 by dispersion of reduced graphene oxide

Sanyukta Ghosh, Shubhanth Jain, Soumya Ranjan Mishra, Gerda Rogl, Peter Rogl, Ernst Bauer, B. S. Murty, A. Govindaraj, Ramesh Chandra Mallik

Summary: In this study, reduced graphene oxide (rGO) was uniformly dispersed in the In0.5Co4Sb12 bulk material by ultrasonication, which effectively reduced the lattice thermal conductivity and improved the thermoelectric efficiency.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

An effective visible-light driven fumarate production from gaseous CO2 and pyruvate by the cationic zinc porphyrin-based photocatalytic system with dual biocatalysts

Mika Takeuchi, Yutaka Amao

Summary: This study developed an effective visible-light driven system for fumaric acid production using renewable resources such as biomass derivatives, providing an alternative to the current petroleum-based synthesis methods.

DALTON TRANSACTIONS (2024)

Article Chemistry, Inorganic & Nuclear

Tin-doped NiFe2O4 nanoblocks grown on an iron foil for efficient and stable water splitting at large current densities

Juan Jian, Meiting Wang, Zhuo Wang, Jingwen Meng, Yuqin Yang, Limin Chang

Summary: Developing low-cost and self-supported bifunctional catalysts is crucial for highly efficient water splitting devices. In this study, nano-NiFe2O4 was directly grown onto iron foil surface and Sn4+ was introduced into the NiFe2O4. The resulting Sn-NiFe2O4/IF showed low overpotentials and high current densities during oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), making it a promising catalyst for large-scale hydrogen production.

DALTON TRANSACTIONS (2024)