☆ 4.7 Article

Template-Directed Photochemical [2+2] Cycloaddition in Crystalline Materials: A Useful Tool to Access Cyclobutane Derivatives

CRYSTAL GROWTH & DESIGN (2018)

期刊

CRYSTAL GROWTH & DESIGN

卷 18, 期 2, 页码 553-565

出版社

AMER CHEMICAL SOC

DOI: 10.1021/acs.cgd.7b01308

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Chemistry, Multidisciplinary Crystallography Materials Science, Multidisciplinary

资金

NSFC [21722105, 21371036, 21531007]
Shaanxi Key Laboratory of Physical-inorganic Chemistry [17JS133]
FM&EM International Joint Lab of Northwest University
China Postdoctoral Science Foundation [2017M613185]

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摘要

The photochemical [2 + 2] cycloaddition reaction in crystalline materials is one of most important routes for the synthesis of cyclobutane compounds, which are otherwise difficult to prepare by conventional organic synthesis. In this perspective, a series of olefins that undergo photochemical [2 + 2] cycloaddition reactions is summarized and categorized according to their various functionality. Using these olefins, a range of cyclobutane derivatives were prepared by this [2 + 2] cycloaddition protocol.

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