期刊
CORROSION SCIENCE
卷 132, 期 -, 页码 214-222出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2017.12.026
关键词
Stainless steel; XPS; Interfaces; Segregation; Oxidation
资金
- Academy of Finland [141481, 286713, 141492, 283967, 273694, 309920, 310359]
- Jenny and Antti Wihuri Foundation
- Graduate School of Tampere University of Technology
- Academy of Finland (AKA) [309920, 273694, 141492, 283967, 273694, 141492, 283967, 309920] Funding Source: Academy of Finland (AKA)
Microalloying of stainless steel with reactive elements increases oxidation resistance but makes the alloy prone to microstructural changes. XPS results reveal changes in the initial oxidation mechanism on Ti-Nb stabilized ferritic stainless steel (EN 1.4521) after 120 h heat treatment at 650 degrees C. Age-precipitation of (FeCrSi)(2)(MoNb)-type Laves phase resulted in less pronounced surface segregation and oxidation of microalloying elements. Si oxidizes preferentially at the Laves precipitate locations via outward diffusion forming diffusion barrier for the other scale forming elements. Most significantly the diffusion of Mn and the formation of low volatile (Mn,Cr)(3)O-4 spinel oxide at the surface was strongly suppressed.
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