期刊
CORROSION SCIENCE
卷 137, 期 -, 页码 13-32出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2018.03.011
关键词
zinc; acid solutions; EIS; XPS; passive films; organic coatings
资金
- CNPq [200490/2014-1]
- CAPES [11995-13-0]
- FAPESP [15/09952-0, 16/504554-6]
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [15/09952-0] Funding Source: FAPESP
The interactions between oxalic acid and zinc substrates have been studied through the deposition of zinc oxalate coating by immersion. The corrosion behaviour of zinc was investigated by surface observation and electrochemical impedance spectroscopy (EIS). Better protective properties were observed for samples treated with 10(-1) M oxalic acid compared to other concentrations and the enrichment of corrosion product by Na was observed. The electrochemical results reveal that the oxalate coating increases corrosion protection in corrosive medium. It is proposed that the zinc oxalate coating formed act as a basis for anchoring zinc corrosion products forming simonkolleite improving corrosion resistance.
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