期刊
COORDINATION CHEMISTRY REVIEWS
卷 375, 期 -, 页码 285-332出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2018.01.012
关键词
kappa(3)-N pincer ligand; Pyridine-pyrrolide metal complexes; X-ray crystal structures; Electronic properties; Reactions; Applications
资金
- Australian Research Council [DP160104383]
- Australian Postgraduate Award
This review covers all aspects of the chemistry of metal complexes of tridentate kappa(3)-N pyridine-pyrrolide ligands, from the syntheses of the ligands to what is known about the metal complexes - their structural and physical properties, and their reactivities, including use in catalytic processes. Applications of the complexes range from the switching elements in molecular devices, to luminophores in electroluminescent devices and photosensitisers in light-driven catalyses, to anticancer therapeutics and to efficient catalysts for organic transformations. The general properties of the ligands and metal complexes are deduced from the available literature, and areas of kappa(3)-N pyridine-pyrrolide metal complex chemistry ripe for development are pinpointed. (C) 2018 Elsevier B.V. All rights reserved.
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