期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 24, 期 44, 页码 11498-11502出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201802384
关键词
boronic esters; inverse boron ylids; Matteson rearrangement; radical reactions; single-electron transfer
资金
- Swiss National Science Foundation [200020_172621]
- University of Bern
An operationally simple protocol to affect a radical addition to alkenylboronates that spontaneously undergo a [1,2]-metalate shift is described. Overall, the reaction is a three-component coupling of an organolithium, alkenylboronic ester, and halide which takes place with broad scope and good to excellent yields. Experimental mechanistic investigations support the formation of a boron inverse ylid intermediate.
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