Copper-Catalyzed Regio- and Enantioselective Aminoboration of Unactivated Terminal Alkenes

Copper/Bisphosphine Catalysts in the Internally Borylative Aminoboration of Unactivated Terminal Alkenes with Bis(pinacolato)diboron

(2017) Kodai Kato et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism-based enhancement of scope and enantioselectivity for reactions involving a copper-substituted stereogenic carbon centre

(2017) Jaehee Lee et al.   Nature Chemistry

Copper-Catalyzed Asymmetric Borylallylation of Vinyl Arenes

(2017) Namhyeon Kim et al.   ORGANIC LETTERS

Elusive Phosphine Copper(I) Boryl Complexes: Synthesis, Structures, and Reactivity

(2017) Corinna Borner et al.   ORGANOMETALLICS

Catalytic Enantioselective Functionalization of Unactivated Terminal Alkenes

(2016) John R. Coombs et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of β-Boryl-α-Aminosilanes by Copper-Catalyzed Aminoboration of Vinylsilanes

(2016) Kodai Kato et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN)

(2016) Erik A. Romero et al.   CHEMICAL COMMUNICATIONS

Mechanism of Ligand-Controlled Regioselectivity-Switchable Copper-Catalyzed Alkylboration of Alkenes

(2016) Zheng-Yang Xu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of Chiral Piperidines via the Stepwise Dearomatization/Borylation of Pyridines

(2016) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbohydrate-Catalyzed Enantioselective Alkene Diboration: Enhanced Reactivity of 1,2-Bonded Diboron Complexes

(2016) Lichao Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Regio- and Stereoselective Aminoboration of Alkenylboronates

(2016) Daiki Nishikawa et al.   ORGANIC LETTERS

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Alkenes

(2015) Wei Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Borylative Dearomatization of Indoles through Copper(I) Catalysis

(2015) Koji Kubota et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes

(2015) Michael T. Pirnot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)/PAr3-Catalyzed Intermolecular Amination of C(sp3)H Bonds: Synthesis of β-Amino Acids

(2015) Jian He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Oxyboration of Unactivated Alkenes

(2015) Taisuke Itoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Synthesis of α-Aminoboronic Acid Derivatives by Copper-Catalyzed Enantioselective Hydroamination

(2015) Daiki Nishikawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regiodivergent Cu-Catalyzed Aminoboration of Unactivated Terminal Alkenes

(2015) Ryosuke Sakae et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines

(2015) Y. Yang et al.   SCIENCE

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex

(2014) Fanke Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Diastereo- and Enantioselective Desymmetrization of Cyclopropenes: Synthesis of Cyclopropylboronates

(2014) Alejandro Parra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Stereoselective Synthesis of (Borylmethyl)cyclopropylamines by Copper-Catalyzed Aminoboration of Methylenecyclopropanes

(2014) Ryosuke Sakae et al.   ORGANIC LETTERS

Recent Advances in Electrophilic Amination Reactions

(2014) Corinne Gosmini et al.   SYNTHESIS-STUTTGART

Asymmetric Diboration of Terminal Alkenes with a Rhodium Catalyst and Subsequent Oxidation: Enantioselective Synthesis of Optically Active 1,2-Diols

(2013) Kenji Toribatake et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective and Stereospecific Copper-Catalyzed Aminoboration of Styrenes with Bis(pinacolato)diboron and O-Benzoyl-N,N-dialkylhydroxylamines

(2013) Naoki Matsuda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism of the Pt-Catalyzed Enantioselective Diboration of Monosubstituted Alkenes

(2013) John R. Coombs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Borylative exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond

(2013) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

(2013) Scott N. Mlynarski et al.   NATURE

Preparation of Organotrifluoroborate Salts: Precipitation-Driven Equilibrium under Non-Etching Conditions

(2012) Alastair J. J. Lennox et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elusive Metal-Free Primary Amination of Arylboronic Acids: Synthetic Studies and Mechanism by Density Functional Theory

(2012) Chen Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Stereospecific Amination of Alkyl and Aryl Pinacol Boronates

(2012) Scott N. Mlynarski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Tertiary Alkyl Amines from Terminal Alkenes: Copper-Catalyzed Amination of Alkyl Boranes

(2012) Richard P. Rucker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reinvestigation of Aminomethyltrifluoroborates and Their Application in Suzuki−Miyaura Cross-Coupling Reactions

(2011) Jessica Raushel et al.   JOURNAL OF ORGANIC CHEMISTRY

Practical procedure for copper(I)-catalyzed allylic boryl substitution with stoichiometric alkoxide base

(2011) Hajime Ito et al.   TETRAHEDRON

Umpolung Amination: Nickel-Catalyzed Coupling Reactions ofN,N-Dialkyl-N-chloroamines with Diorganozinc Reagents

(2009) Timothy J. Barker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pt-Catalyzed Enantioselective Diboration of Terminal Alkenes with B2(pin)2

(2009) Laura T. Kliman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Simple, Modular Synthesis of Substituted Pyridines

(2008) Songbai Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY