期刊
CHEMICAL PHYSICS LETTERS
卷 706, 期 -, 页码 47-52出版社
ELSEVIER
DOI: 10.1016/j.cplett.2018.05.055
关键词
Layered double hydroxides (LDHs); H-2 NMR; Paramagnetic; Ni
资金
- National Natural Science Foundation of China (NSFC) [21603182, 21573103, 21607122]
- NSFC - Royal Society Joint Program [21661130149, 21611130177]
- University Science Research Project of Jiangsu Province [2016097]
- Royal Society
- Newton Fund
H-2 MAS NMR spectroscopy was applied to investigate the local structure of deuterated paramagnetic Ni2+-containing layered double hydroxides (LDHs) for the first time. Due to significantly smaller electronic dipole interaction, H-2 NMR spectra of NiAl-LDHs show much better resolution than H-1 NMR spectra, and different hydrogen species, including Ni3OD, Ni2AlOD and interlayer water, can be resolved in H-2 NMR spectra. Quantitative analysis of the NMR spectra of LDHs with different Al percentages confirms the ordering of Al3+ ions in the hydroxide sheets (Al-O-Al avoidance). H-2 MAS NMR spectroscopy gives new insight into different hydrogen species in paramagnetic NiAl-LDH and this approach can be extended to study the detailed structural information and properties of other paramagnetic LDHs. (C) 2018 Elsevier B.V. All rights reserved.
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