Article
Chemistry, Multidisciplinary
Wenyan Li, Xinying Lin, Jing Long, Bo Zheng, Zhaorui Pan, Leiming Lang, Guangxiang Liu
Summary: The mesoporous core-shell structure Ag@SiO2 nanospheres are constructed to prevent aggregation of Ag nanoparticles during hydrogenation, leading to superior catalytic performance in terms of 100% conversion and selectivity in the hydrogenation of nitro compounds, with good recycling performance for multiple uses.
Article
Chemistry, Multidisciplinary
Jianbo Zhao, Xiaomeng Li, Meng Zhang, Zhuo Xu, Xiaomei Qin, Yingfan Liu, Lifeng Han, Gao Li
Summary: In this study, a hollow mesoporous Co-N-C@mSiO(2) nanostructure derived from ZIF-67 was designed via the encapsulation-pyrolysis strategy. The Co-N-C@mSiO(2) catalyst exhibited excellent catalytic performance in the furfural hydrogenation towards furfuryl alcohol with good stability, and it was much better than other reported transition metal catalysts. This work provides a novel and facile strategy for preparing highly efficient non-precious metal catalysts to replace Cr-based and noble metal catalysts for furfural hydrogenation.
Article
Environmental Sciences
Hao Hou, Shichu Xu, Suyan Ding, Weijie Lin, Qiang Yu, Jia Zhang, Guangren Qian
Summary: This study successfully synthesized spinel catalyst from electroplating sludge and utilized the transition metals and multi-hetero atoms for CO2 catalytic hydrogenation to produce CH3OH. Metal doping increased the CO2 conversion efficiency but decreased the CH3OH selectivity. Further doping of S significantly increased the CH3OH selectivity.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Chemistry, Applied
Yu Chen, Zemin Zhao, Ze Li, Jieying Jing, Wenying Li
Summary: In this study, a series of Ni-Co/NiAlOx catalysts were synthesized by reducing at different temperatures, and the catalytic activity for the hydrogenation of phenanthrene was evaluated. The catalyst reduced at 560 degrees C (Cat-560) showed high activity with a phenanthrene conversion amount of 8.0 mmol·g-1·h-1 and 98% perhydrophenanthrene selectivity. Cat-560 also exhibited superior specific activity and turnover frequency for symmetric octahydrophenanthrene hydrogenation, attributed to its special geometric and electronic structure.
FUEL PROCESSING TECHNOLOGY
(2023)
Article
Energy & Fuels
Guilin Zhou, Xing Ai, Yunqi Tian, Rui Huang, Yongcheng Feng, Jianmin Ren
Summary: In this study, a Co/KIT-6 catalyst with high specific surface area and well-developed ordered mesoporous structure was prepared and characterized. The active metal Co species highly dispersed on the catalyst were identified as the main active centers for CO2 hydrogenation. The catalyst showed high activity and stability in CO2 hydrogenation, with over 47% CO2 conversion and selective generation of CO and CH4.
GREENHOUSE GASES-SCIENCE AND TECHNOLOGY
(2021)
Article
Chemistry, Physical
Carmen Ciotonea, Alexandru Chirieac, Brandusa Dragoi, Jeremy Dhainaut, Maya Marinova, Stephane Pronier, Sandrine Arii-Clacens, Jean-Philippe Dacquin, Emil Dumitriu, Adrian Ungureanu, Sebastien Royer
Summary: The preparation of bimetallic materials based on transition metals has attracted interest for their use as catalysts in hydrogenation reactions. The study successfully synthesized Cu and Co based bimetallic materials with high dispersion of active sites and thermal stability. CuCo1:4 exhibited the highest conversion and selectivity towards cinnamyl alcohol in the hydrogenation reaction.
APPLIED CATALYSIS A-GENERAL
(2021)
Article
Chemistry, Inorganic & Nuclear
Zeyu Shen, Lirui Hong, Baishu Zheng, Guanyu Wang, Beibei Zhang, Zhaoxu Wang, Feiyang Zhan, Shaohua Shen, Ruirui Yun
Summary: The Co/Ni bimetallic nanoparticle supported by nitrogen-doped porous carbon (NPC) showed high catalytic performance in hydrogenating nitro compounds into amines using hydrazine hydrate at mild conditions, thanks to the synergistic effects of the bimetal nanoparticles and the porous structure of NPC with more accessible active sites.
INORGANIC CHEMISTRY
(2021)
Article
Materials Science, Multidisciplinary
Anand Parkash, Nizamuddin Solangi, Shafeeque Ahmed Wahocho, Abdul Sami Channa, Muhammad Ali Inam, Shafqat Ali
Summary: Using unsupported catalysts improves stability and durability in electrochemical reactions due to the non-corrosive carbon component. Advanced mesoporous structures with controlled pore and metal composition at the nanoscale were created. Rigid template-assisted synthesis was used to produce mesoporous platinum and platinum bimetallic catalysts, eliminating the carbon corrosion problem and enhancing catalyst activity.
ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY
(2022)
Article
Chemistry, Applied
Agata Wawrzynczak, Sylwia Jarmolinska, Izabela Nowak
Summary: In this study, ordered nanostructured KIT-6 silica with different numbers of sulfonic groups were synthesized. The amount of the functional group precursor used affected the structural and textural parameters of the synthesized materials. The samples modified by grafting exhibited a stable mesoporous structure, while the ones synthesized by co-condensation showed characteristics of KIT-6 materials. The developed synthesis procedures yielded potential solid acid catalysts with desirable catalytic performances.
Article
Chemistry, Applied
Chaozhong Li, Weiyue Zhao, Xueyi Lu, Zhangsen Chen, Bing Han, Xiaorong Zhang, Jiaxiang Chen, Yijia Shao, Junlang Huo, Yuexiang Zhu, Yonghong Deng, Shuhui Sun, Shijun Liao
Summary: We report a high-performance catalyst consisting of ordered PtCoNi ternary nanoparticles anchored on N, Co, and Ni co-doped dodecahedral mesoporous carbon (DMC). The catalyst exhibits enhanced electrocatalytic activity towards oxygen reduction reaction due to the formation of PtCoNi intermetallic compounds and the dual active centers of Co-N and Ni-N coordination. The optimized sample Pt3Co0.7Ni0.3/DMC demonstrates excellent performance with mass activity and specific activity 7.33 and 6.19 times higher than commercial Pt/C, respectively. This study provides critical insights into constructing efficient catalysts using a ternary intermetallic strategy and synergetic effect between active components and support.
JOURNAL OF ENERGY CHEMISTRY
(2023)
Article
Biochemistry & Molecular Biology
Alevtina N. Gosteva, Mayya V. Kulikova, Yulya P. Semushina, Mariya V. Chudakova, Nikita S. Tsvetov, Vasilii V. Semushin
Summary: The study examined the activity of DCS-based catalysts in high-temperature Fischer-Tropsch synthesis and revealed the influence of aluminum in the catalyst composition on the distribution of reaction products.
Review
Chemistry, Multidisciplinary
Barbara Thijs, Jan Ronge, Johan A. Martens
Summary: This article discusses the concentration requirements of formic acid in the electrochemical production process as a carbon capture and utilization product. It explains how the specifications of electrochemical formic acid production can be matched with the requirements of emerging applications.
Review
Materials Science, Multidisciplinary
Zhenhui Liu, Yue Du, Pengfei Zhang, Zechao Zhuang, Dingsheng Wang
Summary: Rationally designing an appropriate support is crucial for catalysis, and nitrogen-doped ordered mesoporous carbons (NOMCs) are emerging as intriguing supports with well-defined pore channels and abundant functional groups, offering potential for improved catalysis. Various synthetic strategies can be used to prepare NOMCs, and their applications in electrocatalysis and organic synthesis show promising prospects for future developments.
Article
Chemistry, Multidisciplinary
Ziyue Liu, Long Yan, Qian Jiang, Yuhui Huang, Chengmei Yang, Chenguang Wang, Xi Lu, Longlong Ma, Qi Zhang
Summary: A non-acidic mesoporous silica-supported Pt catalyst was developed to produce biomass-derived 5-methylpyrrolidone under room temperature and atmospheric hydrogen. The suitable mesoporous structure created high dispersion of Pt species and accelerated the reaction processes. The isomerization of imine to enamine on the catalyst made this conversion easy under mild conditions.
Article
Chemistry, Multidisciplinary
Haoyang Jiang, Feng Zhu, Renjie Zhou, Linyu Wang, Yongcheng Xiao, Miao Zhong
Summary: Co-modified Fe5C2 on TiC catalyst promotes photothermal catalytic CO hydrogenation with high C2+ selectivity and CO conversion rate by modulating the chemical state of Fe through light-induced hot electron injection from TiC to Fe5C2.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Lidan Deng, Xin Ai, Fengqiong Xie, Guilin Zhou
Summary: The addition of Cu to Ni catalysts significantly affects CO2 hydrogenation activity and CO selectivity, with the Ni/Cu ratios playing a crucial role. The reduction temperatures of the studied catalysts also influence the reaction, highlighting the importance of active species and their dispersion. The Ni1Cu1-400 catalyst shows promise as a superior catalyst for the reverse water-gas shift reaction, with high stability, CO selectivity, and fast formation rate at 400 degrees C.
CHEMISTRY-AN ASIAN JOURNAL
(2021)
Article
Chemistry, Physical
Guilin Zhou, Tao Li, Jiongyi Chen, Lidan Deng, Hongmei Xie
Summary: Different preparation methods of Nano-CeO2 supports were used to prepare nano-Pd/CeO2 catalysts, showing excellent catalytic performance in benzene hydrogenation and cyclohexane dehydrogenation reactions. The synergy between metal Pd, CeO2 support, and their structures effectively promotes hydrogen storage capacity.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Multidisciplinary
Yuan Gao, Kun Xiong, Haidong Zhang, Bingfeng Zhu
Summary: Ru doping in LiFePO4 significantly improves the electrochemical performance, showing enhanced lithium diffusion coefficient and electrical conductivity. This work represents a significant advancement in exploring a new class of lithium iron phosphates with excellent performance in new energy storage and conversion systems.
Article
Chemistry, Physical
Jingjing Wang, Jun Chen, Lishan Peng, Haidong Zhang, Zhiquan Jiang, Kun Xiong, Qi Yang, Jia Chen, Na Yang
Summary: The study provides a new understanding of the active site of CuMnOx catalysts and suggests a new perspective in the development of effective and low-cost CuMnOx catalysts for heterogeneous catalytic oxidation reactions. The CuMnOx catalysts were found to consist of uniform CuO-Mn2O3 oxide pair structure, with highly isolated/dispersed CuO species anchored in the framework of Mn2O3. The speciation in these CuMnOx catalysts shifts from highly isolated or single Cu2+ oxide species to CuO nanoclusters and CuO microcrystalline with increasing Cu content.
APPLIED SURFACE SCIENCE
(2022)
Article
Environmental Sciences
Haoyu Wang, Hongmei Xie, Qihong Cao, Xiaole Li, Biyan Liu, Zuoxiang Gan, Huijun Zhang, Xue Gao, Guilin Zhou
Summary: Activated carbon adsorbents were prepared using waste Zanthoxylum bungeanum branches as raw materials and H3PO4/H2SO4 as composite activator. The adsorption properties for toluene in the air were evaluated, and it was found that the dosage of auxiliary activator H2SO4 significantly affected the adsorption performance of the activated carbon.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Chemistry, Physical
Yang Xiang, Kun Xiong, Linjian Yu, Haidong Zhang, Jia Chen, Meirong Xia
Summary: In this study, nickel telluride nanosheets with three different crystal phases were grown on Ni Foam through a one-step hydrothermal tellurization followed by annealing process. Among them, the non-stoichiometric Ni2.86Te2/NF exhibited superior electrocatalytic HER performance, providing valuable insights for the rational modulation of crystal phase on nickel telluride for catalyzing HER.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Multidisciplinary
Guilin Zhou, Shiyu Xu, Yue Li, Qingqing Jiang, Benjing Xu, Hongmei Xie, Guizhi Zhang
Summary: A soft template method was used to introduce Ni component into CeO2 to prepare porous NiCe composite catalysts. The synergistic effect of Ni and Ce species significantly improved the reducibility of the catalysts and formed CO2 hydrogenation active sites. The structure and performance of the prepared NiCe composite catalysts were affected by the n(Ni)/n(Ce) ratio.
Article
Environmental Sciences
Jia Zeng, Hongmei Xie, Hanyi Zhang, Min Huang, Xuecheng Liu, Guilin Zhou, Yi Jiang
Summary: By fabricating alpha-MnO2 catalysts with abundant oxygen vacancies (OVs) via a novel redox-precipitation approach, the role of OVs in toluene oxidation has been clarified. The OVs induce new bandgap states, promote the formation of active oxygen species, and result in the elongation of Mn-O bonds. Therefore, the OVs have synergistic effects on the catalytic activity of the prepared catalysts.
Article
Chemistry, Applied
Xiaojie Li, Yuantao Tang, Jingjing Wang, Haidong Zhang, Kun Xiong, Jia Chen
Summary: A new ordered mesoporous carbon material with highly ordered carbon nano-channels was successfully synthesized using a novel mesoporous silica material as template agent. This material shows a 7 times faster adsorption rate and 3.2 times higher adsorption capacity for the removal of Cr(VI) in aqueous solution compared to a commercial activated carbon material.
JOURNAL OF POROUS MATERIALS
(2022)
Article
Chemistry, Physical
Qi Yang, Yuantao Tang, Haidong Zhang, Jun Chen, Zhiquan Jiang, Kun Xiong, Jingjing Wang, Xinai Liu, Na Yang, Qiuyue Du, Yuting Song
Summary: This study presents a new method for the synthesis of CuMnOx catalysts using a half carbonized citrus grandis peel assisted hard template method. The shift of the oxide pairs from CuO-Cu1.4Mn1.6O4 to Mn2O3- Cu1.4Mn1.6O4 has been achieved by tuning the Cu/Mn molar ratio, resulting in high selectivity and efficiency in the oxidation of benzyl alcohol using H2O2 as oxidant. The interaction between the Cu1.4Mn1.6O4 constituent and Mn2O3 constituent enhances the formation of Cu+ species, leading to a Fenton-like catalytic oxidation process.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Physical
Yuan Gao, Kun Xiong, Bingfeng Zhu
Summary: In this study, a series of Cu-based catalysts supported by MoOx were synthesized for noble metal-free RWGS reactions, and the effects of MoOx support on catalyst performance were investigated. The results show that the introduction of MoOx can effectively improve the catalytic performance of RWGS reactions.
Article
Chemistry, Multidisciplinary
Qiuyue Du, Haidong Zhang, Zhiquan Jiang, Kun Xiong, Qi Yang, Na Yang, Yuting Song, Jia Chen
Summary: As a metal-free material, graphitic carbon nitride (g-C3N4) finds widespread applications in catalytic and energy storage materials. However, limited light absorption, low conductivity, and high recombination rate of electron-hole pairs hinder its further development. To overcome these limitations, integrating g-C3N4 with carbon materials to construct composite materials is common and effective. This paper reviews the photoelectrocatalytic performance of carbon/g-C3N4 composite materials (CCNCS) that combine g-C3N4 with carbon dots, carbon nanotubes, graphene, and carbon spheres. The effects of carbon material types, content, nitrogen content, g-C3N4 morphology, and carbon-g-C3N4 interfacial interactions on the performance of CCNCS are analyzed, providing insights into the synergistic effect between g-C3N4 and carbon in CCNCS.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Kun Xiong, Jiayao Chen, Na Yang, Shangkun Jiang, Li Li, Zidong Wei
Summary: In this study, a series of transition-metal-doped carbon material catalysts were systematically investigated for electrochemical NRR under actual ambient conditions using DFT and AIMD simulations. The results showed high thermodynamic stability of the catalysts, with VN3C1 catalyst demonstrating the best performance in the presence of water. These findings suggest potential for artificial ammonia synthesis using single-atom catalysts under realistic conditions.
ACTA CHIMICA SINICA
(2021)
Article
Chemistry, Physical
Jia Zeng, Hongmei Xie, Zhao Liu, Xuecheng Liu, Guilin Zhou, Yi Jiang
Summary: This study demonstrates the tuning of oxygen vacancies on alpha-MnO2 for catalytic toluene oxidation, resulting in superior activity and stability. The control of oxygen vacancies weakens the Mn-O bond strength, increases the amount of surface adsorbed active oxygen species, and promotes catalytic activity.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Engineering, Environmental
Guizhi Zhang, Bingman Lei, Shengming Chen, Hongmei Xie, Guilin Zhou
Summary: In this study, waste biomass was successfully used to prepare activated carbon adsorbents for toluene removal from air. The results showed that the activation temperature significantly influenced the structural characteristics and toluene adsorption performance of the adsorbents.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)