Nucleophilic addition of tertiary propargylic amines to arynes followed by a [2,3]-sigmatropic rearrangement

Stereospecific Nucleophilic Substitution of Enantioenriched Tertiary Benzylic Amines via in Situ Activation with Benzyne

(2017) Yang Gui et al.   ORGANIC LETTERS

Highly Regioselective Carbamoylation of Electron-Deficient Nitrogen Heteroarenes with Hydrazinecarboxamides

(2017) Zeng-Yang He et al.   ORGANIC LETTERS

Activation and Substitution of 1-Ferrocenylalkylamines with Allenones: Application to Three-Component Synthesis of 4-(1-Ferrocenylalkyl)pyrazoles

(2017) Zhixiong Chen et al.   ORGANIC LETTERS

Palladium-Catalyzed Stereospecific Allylation of Nitroacetates with Enantioenriched Primary Allylic Amines

(2016) Jing-Kun Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition-metal catalysed C–N bond activation

(2016) Quanjun Wang et al.   CHEMICAL SOCIETY REVIEWS

Tandem Aryne-Capture/Sigmatropic Rearrangement as a Metal-Free Entry to Functionalized N -Aryl Pyrrolidines

(2016) Sam G. Moss et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Arylation of Tertiary Amines under Mild Conditions

(2016) Maayan Hirsch et al.   ORGANIC LETTERS

Aryne-Mediated [2,3]-Sigmatropic Rearrangement of Tertiary Allylic Amines

(2016) Juan Zhang et al.   ORGANIC LETTERS

The Aryne [2,3] Stevens Rearrangement

(2016) Tony Roy et al.   ORGANIC LETTERS

Substrate-Controlled Selectivity Switch in the Three-Component Coupling Involving Arynes, Aromatic Tertiary Amines, and CO2

(2016) Sachin Suresh Bhojgude et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Cleavage of C–N Single Bonds

(2015) Kunbing Ouyang et al.   CHEMICAL REVIEWS

Transition metal-catalyzed allylic substitution reactions with unactivated allylic substrates

(2015) Nicholas A. Butt et al.   CHEMICAL SOCIETY REVIEWS

Kinetic resolution of primary allylic amines via palladium-catalyzed asymmetric allylic alkylation of malononitriles

(2015) Yong Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Three-Component Coupling Involving Arynes, Aromatic Tertiary Amines, and Aldehydes via Aryl–Aryl Amino Group Migration

(2015) Sachin Suresh Bhojgude et al.   ORGANIC LETTERS

Synthesis of allenic diamines via the Stevens rearrangement of ammonium salts

(2015) M. O. Manukyan   RUSSIAN JOURNAL OF GENERAL CHEMISTRY

The interaction of 4-hydroxymethyl isoindolines with dehydrobenzene. Synthesis of 3-phenylaminomethyldihydrobenzo[c]furanes

(2015) Alexey V. Varlamov et al.   TETRAHEDRON

Direct enantiospecific substitution of primary α-aminoalkylferrocenes via Lewis acid-catalyzed C–N bond cleavage

(2014) Meng-Guang Zhou et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed aerobic oxidative coupling of enantioenriched primary allylic amines with sulfonyl hydrazides leading to optically active allylic sulfones

(2014) Ting-Ting Wang et al.   CHEMICAL COMMUNICATIONS

Synthesis, X-ray structure, and stevens rearrangement of 1,1-di(prop-2-yn-1-yl)-2,5-dihydro-1H-pyrrol-1-ium bromide

(2014) A. Kh. Gyul’nazaryan et al.   RUSSIAN JOURNAL OF GENERAL CHEMISTRY

Facile synthetic protocols for perfluoroalkyl-substituted diazapentaphenes

(2014) Shigeyuki Yamada et al.   TETRAHEDRON

Catalytic stereospecific allylation of protected hydrazines with enantioenriched primary allylic amines

(2014) Yong Wang et al.   Organic Chemistry Frontiers

Employing Arynes in Transition-Metal-Free Monoarylation of Aromatic Tertiary Amines

(2013) Sachin Suresh Bhojgude et al.   ORGANIC LETTERS

Palladium-Catalyzed Chemoselective Catellani ortho-Arylation Reactions and Their Applications in Natural Products Synthesis

(2013) Zhenhua Gu et al.   SYNLETT

Formation of Acridones by Ethylene Extrusion in the Reaction of Arynes with β-Lactams and Dihydroquinolinones

(2012) Yuesi Fang et al.   JOURNAL OF ORGANIC CHEMISTRY

A C–N insertion of β-lactam to benzyne: unusual formation of acridone

(2012) Jimin Kim et al.   TETRAHEDRON LETTERS

Reaction of Benzyne with Formamides and Acetylimidazole

(2011) Kentaro Okuma et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Synthesis of functionalized CF3-containing heterocycles via [2,3]-sigmatropic rearrangement and sequential catalytic carbocyclization

(2011) Daria V. Vorobyeva et al.   TETRAHEDRON

A facile N-arylation of acetanilides with arynes

(2011) James C. Haber et al.   TETRAHEDRON LETTERS

The Benzyne Aza-Claisen Reaction

(2009) Alastair A. Cant et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insertion of Benzene Rings into the Amide Bond: One-Step Synthesis of Acridines and Acridones from Aryl Amides

(2009) Didier G. Pintori et al.   ORGANIC LETTERS

Iron(III) Corroles and Porphyrins as Superior Catalysts for the Reactions of Diazoacetates with Nitrogen- or Sulfur-Containing Nucleophilic Substrates: Synthetic Uses and Mechanistic Insights

(2008) Iris Aviv et al.   CHEMISTRY-A EUROPEAN JOURNAL