期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 39, 页码 4963-4966出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc01284a
关键词
-
资金
- National Natural Science Foundation of China [21572198, 21362043, 21302162]
- Applied Basic Research Project of Yunnan Province [2017FA004]
- Department of Education of Yunnan Province [2017ZDX046, ZD2015012]
A palladium/zinc co-catalytic system was established and successfully utilized in the asymmetric transfer hydrogenation reactions of N-sulfonylimines with alcohols as hydrogen sources. Simple alcohols such as methanol, ethanol and benzyl alcohols are all variable hydrogen sources that can reduce various N-sulfonylimines to the corresponding chiral amines with high optical purities in presence of this co-catalytic system. Primary mechanistic study revealed that the reaction may initiate with a Pd-hydride intermediate.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据