期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 18, 页码 2200-2203出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc09443d
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资金
- Grants-in-Aid for Scientific Research [16J01036, 15H03788] Funding Source: KAKEN
The first free cyclobutadiene (CBD) germanium analogue was obtained as room-temperature stable dark red crystals via the reaction of the bulky EMind-substituted 1,2-dichlorodigermene with lithium naphthalenide. The cyclic 4-electron antiaromaticity is essentially stabilized by the polar Jahn-Teller distortion in the germanium CBD producing a planar rhombic-shaped charge-separated structure.
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