期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 20, 页码 2510-2513出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc00447a
关键词
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资金
- National Natural Science Foundation of China [21371054, 21671063]
- Hunan Provincial Natural Science Foundation of China [2016JJ2048]
- Polish National Science Center [2013/09/B/ST5/00326]
The antiaromatic ring of norcorrole, a contracted tetrapyrrolic porphyrinoid, was subjected to [2+3] dipolar cycloaddition of iminonitriles. The paratropic character of the resulting chiral chlorins was retained. The chlorins were easily dehydrogenated in the presence of air, yielding pyrazole-fused norcorroles with markedly enhanced paratropicity.
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