期刊
CERAMICS INTERNATIONAL
卷 44, 期 1, 页码 120-127出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2017.09.146
关键词
FeCo2O4; Hetero-structure; Morphological evolution; Supercapacitors
资金
- National Natural Science Foundation of China [11504312]
- Provincial Natural Science Foundation of Hunan [2016JJ2132]
- Open Fund based on innovation platform of Hunan Colleges and Universities [15K128]
- Scientific Research Fund of Hunan Provincial Education Department [15C1322]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT_17R91]
The exploration of high performance supercapacitors has received emerging the worldwide research interests in satisfying the gradually increased energy consumption. In this paper, we adopt a facile hydrothermal strategy to synthesize ternary FeCo2O4 directly on nickel foam. A series of structure such as nanowires, nanoflake@nanowire hetero-structure and hierarchical nanospheres have been achieved via modulating the synthetic time. The morphology and structure of the as-prepared samples are characterized by using scanning electron microscopy and X-ray diffraction spectroscopy. The relationship between the detail processing parameters and electrochemical performance are also revealed by cyclic voltammetry, galvanostatic charge-discharge measurements, cycle stability tests and electrochemical impedance spectroscopy. Notably, the as-prepared nanoflake@nanowire hetero-structure exhibits a high specific capacitance of about 969 F g(-1) at 2 A g(-1) in alkaline aqueous solution and a remarkable cycling stability (91% capacity retention after 2000 cycles). The excellent supercapacitors performance of nanoflake@nanowire hetero-structure can be attributed to the high conductivity, large active area as well as robust architectures that derive from structural synergetic effects. Furthermore, a symmetric all solid-state supercapacitor has been fabricated by using nanofiake@nanowire hetero-structure as both the anode and cathode electrodes. The as-fabricated supercapacitor delivers excellent electrochemical performance. It's anticipated that FeCo2O4 would be a promising material for electrochemical energy storage applications.
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