4.7 Article

Effect of fly ash microsphere on the rheology and microstructure of alkali-activated fly ash/slag pastes

期刊

CEMENT AND CONCRETE RESEARCH
卷 109, 期 -, 页码 198-207

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.cemconres.2018.04.008

关键词

Fly ash microsphere; Alkali-activated cement (D); Rheology (A); Microstructure (B)

资金

  1. National Natural Science Foundation of China [51702278, 51572234, 51502259, 51672236, 51502272]
  2. Natural Science Foundation of Jiangsu Province of China [BK20170476]
  3. Australian Research Council DECFtA project [DE170101070]

向作者/读者索取更多资源

The highly viscous property of alkali silicate-activated cements is one of the critical challenges that hinder their wide application. The present study focuses on ameliorating the rheological performance of sodium silicate activated fly ash/slag pastes by using fly ash microsphere (FAM), which are highly spherical particles collected from fly ash with electrostatic adsorption classification technology. The FAM particles work as 'ball-bearings' in the pastes to reduce the internal friction between fly ash and slag grains, and meanwhile mitigate the agglomeration of flocs and fragmentation to release the locked water. The interrelationship between the FAM particle geometry and plastic viscosity of the paste is well described by the Krieger-Dougherty equation, which supports the proposed mechanisms of 'ball-bearings' effects. FAM can work as an inorganic dispersing agent to improve the workability of alkali-activated cement products for a variety of application aspects.

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