Article
Chemistry, Multidisciplinary
Alejandra Romero-Moran, Joel Molina-Reyes
Summary: The study focuses on the evaluation of photocatalytic activity for the inactivation of bacteria in wastewater using catalysts fixed to surfaces. It addresses the lack of standardized methods and systematic studies in analyzing the antibacterial activity of these materials, as well as the difficulty in comparing results across different experimental conditions. The study introduces new parameters, PBIE and BIPHR, to evaluate the photocatalytic activity and demonstrates their applicability in comparing different photocatalytic coatings.
Article
Nanoscience & Nanotechnology
Nikhil Dhabarde, Svetlana Khaiboullina, Timsy Uppal, Kabita Adhikari, Subhash C. Verma, Vaidyanathan Ravi Subramanian
Summary: This study demonstrates the effectiveness of TiO2 nanotubes (T_NTs) in photocalytic inactivation of human coronaviruses and SARS-CoV-2. T_NTs with different structural features were prepared and shown to completely inactivate the viruses within 30 seconds. The cyclic stability of T_NTs was also observed. These findings are significant for developing self-disinfecting surfaces to reduce virus transmission.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Ceramics
Marcela Sepulveda, Ivan Saldan, Alijani Mahnaz, Veronika Cicmancova, Jan Michalicka, Ludek Hromadko, Roman Bulanek, Hanna Sopha, Jan M. Macak
Summary: For the first time, this study investigated the influence of annealing temperature, crystallinity, and tubular morphology on the photocatalytic decomposition of model organic dye using magnetically guidable anodic TiO2 nanotubes in the form of single tube powders. The powders were prepared from anodic TiO2 nanotube layers grown on Ti by etching, detachment, and annealing in a wide range of temperatures. The best photocatalytic performance was achieved at annealing temperatures of 600 and 700 degrees C for TiO2 ST-NT and TiO2 ST-NT@Fe3O4NPs powders, respectively. The synergistic effects of annealing, crystallite size, and specific surface area enhanced the photocatalytic activity of the powders under UV light.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Di Zhang, Hogli Hu, Ji-an Wei, Xin Xu, Lei Chen, Xiaohui Wu, Qianqian Yu, Bo-xing Zhang, LinGe Wang
Summary: This study designed and investigated Zr-doped TiO2 ceramic nanofibrous membranes with enhanced photocatalytic properties for dye scavenging and bacteria inactivation.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Environmental Sciences
Ernesto Valadez-Renteria, Rafael Perez-Gonzalez, Christian Gomez-Solis, Luis Armando Diaz-Torres, Armando Encinas, Jorge Oliva, Vicente Rodriguez-Gonzalez
Summary: The structural, morphological, and photocatalytic properties of stretchable composites made with carbon nanotubes (CNTs), silicon rubber, and Ni@TiO 2 :W nanoparticles (TiWNi NPs) were studied. The TiWNi NPs decorated the surface of CNT fibers in a preferential direction. The stretchable CNT + TiWNi composites showed enhanced photocatalytic degradation of diclofenac (DCF) drug, with a degradation percentage increasing from 97.1% to 100% through stretching.
JOURNAL OF ENVIRONMENTAL SCIENCES
(2023)
Article
Materials Science, Multidisciplinary
Fucheng Yu, Junpeng Cui, Yadong Zhou, Yuanmeng Li, Zhengyan Liu, Ling He, Jianbin Zhang, Xianxi Tang, Yangshuo Liu
Summary: The ternary nanocomposite of g-C3N4/Ag/Ag2CrO4, prepared by depositing Ag nanoparticles on g-C3N4 nanotubes and partially oxidizing them, shows improved photocatalytic performance and effective separation efficiency of photo-generated electron-hole pairs, while also inhibiting photocorrosion.
Article
Engineering, Environmental
Ahlam Belgroune, Linda Aissani, Akram Alhussein, Mourad Zaabat, John Kiwi, Sami Rtimi
Summary: The bacterial inactivation kinetics of Escherichia coli (E. coli) by sputtered TiMoON and TiMoON-Ag films were studied under simulated solar light irradiation. The study found that genetically modified porinless E. coli degraded slower than normal E. coli due to the transfer of Ag+-ions from the Ag-films. The TiMoON-Ag films showed potential for disinfection of medical surfaces and devices under solar light.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Optics
Leland Nordin, Priyanka Petluru, Abhilasha Kamboj, Aaron J. Muhowski, Daniel Wasserman
Summary: This work presents an infrared photodetector with a device architecture leveraging quantum-engineered detector structure integrated with a designer epitaxial plasmonic metal in a mature III-V semiconductor material system. The strong confinement of incident light into surface plasmon-polariton modes allows for a sub-diffractive detector absorber layer thickness, achieving high-performance detectors at non-cryogenic temperatures.
Article
Chemistry, Physical
Jaspal Singh, Shrawan Roy, Trang Thu Tran, Sophia Akhtar, Eunji Lee, Jeongyong Kim
Summary: The use of ultrathin nanohybrid films in photocatalytic applications is effective for decomposing pollutants. In this study, ultrathin films composed of Au nanoparticles and Fe2O3 oxy-hydroxides were prepared. These films exhibited outstanding photodecomposition ability and superior photocatalytic activity due to their broad absorption and efficient charge transfer.
SURFACES AND INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Mantas Sriubas, Kristina Bockute, Paulius Palevicius, Marius Kaminskas, Zilvinas Rinkevicius, Minvydas Ragulskis, Sandrita Simonyte, Modestas Ruzauskas, Giedrius Laukaitis
Summary: Metal-based nanoparticles decorated TiO2 thin films show promising antibacterial activity against bacteria associated with oral diseases. The size and spacing of nanoparticles play a crucial role in determining the antibacterial efficacy. In addition, the presence of bacteria can be observed and identified using deep learning techniques.
Article
Chemistry, Multidisciplinary
Katherine Villa, Hanna Sopha, Jaroslav Zelenka, Martin Motola, Lukas Dekanovsky, Darya Chylii Beketova, Jan M. Macak, Tomas Ruml, Martin Pumera
Summary: The study introduces a novel hybrid enzyme/photocatalytic microrobot that can swim in urea and respond to visible light, effectively removing bacterial biofilms. The results demonstrate a synergistic effect between self-propulsion provided by the enzyme and photocatalytic activity induced under light stimuli, showcasing potential applications in microbiology and biomedicine.
Article
Chemistry, Physical
Lukasz Harynski, Jakub Karczewski, Jacek Ryl, Katarzyna Grochowska, Katarzyna Siuzdak
Summary: In this study, earth abundant transition metal oxides are investigated as potential catalyst candidates for oxygen evolution reaction due to their availability and low cost. The pulsed laser treated TiO2 nanotubes sputtered with chromium layer exhibit enhanced activity towards OER and increased donor density, impacting the electrode/electrolyte interface effectively. Results show promising application of direct laser interaction with materials exhibiting poor initial OER activity and visible light response.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Murielle Schreck, Nicole Kleger, Fabian Matter, Junggou Kwon, Elena Tervoort, Kunal Masania, Andre R. Studart, Markus Niederberger
Summary: The use of carefully designed 3D printed polymeric scaffolds in monolithic aerogels composed of crystalline nanoparticles allows for the optimization of photocatalytic performance and mechanical stability. By controlling the geometry of the photocatalysts, fundamental parameters in gas phase photocatalysis can be systematically studied and improved, leading to significant increases in hydrogen production rate and overall performance.
Article
Materials Science, Multidisciplinary
Yasemin Ozbek, Cooper Brooks, Xuanyi Zhang, Athby Al-Tawhid, Vladmir A. Stoica, Zhan Zhang, Divine P. Kumah
Summary: The complex relationship between the growth conditions and the structural and transport properties of TixOy thin films grown by molecular beam epitaxy is investigated. The O/Ti ratio is effectively tuned by the Ti flux rate and the O partial pressure P-Ox, leading to the stabilization of transport properties ranging from metallicity to superconductivity and insulating states. A cubic c-TiO1 +/-delta buffer layer or a corundum cr-Ti2O3 layer is formed depending on the O/Ti ratio. The insulator-superconducting transition is observed in 85 nm thick films at 4.5 K (T-C(onset)=6K) with the nucleation of the superconducting gamma-Ti3O5 Magneli phase on a c-TiO1-delta buffer.
PHYSICAL REVIEW MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Zhenni Wu, Imgon Hwang, Gihoon Cha, Shanshan Qin, Ondrej Tomanec, Zdenek Badura, Stepan Kment, Radek Zboril, Patrik Schmuki
Summary: Anodic TiO2 nanotubes are shown to have excellent properties for harvesting Pt single atoms from highly dilute solutions. The tube walls provide suitable trapping sites for Pt SAs, and a high activity for photocatalytic H-2 generation can be achieved by immersing the nanotubes in a low concentration Pt solution. Overall, these findings demonstrate the potential of anodic TiO2 nanotubes for efficient Pt extraction and recovery, leading to highly active photocatalysts.
Article
Engineering, Chemical
A. Maytorena-Sanchez, J. Hernandez-Torres, L. Zamora-Peredo, F. Lopez-Huerta, A. Baez-Rodriguez, L. Garcia-Gonzalez
Summary: This article presents the oxidation tests of titanium Grade 2 at different temperatures and reveals that oxide crystals start to form at 750 degrees C. The growth of the oxide layers is promoted with increasing temperature and the best results in terms of hardness and friction coefficient are obtained at 750 degrees C. The oxidation at high temperatures also leads to an increase in surface roughness.
Article
Crystallography
Guillermo Barcena-Gonzalez, Andrei Hernandez-Robles, Alvaro Mayoral, Lidia Martinez, Yves Huttel, Pedro L. Galindo, Arturo Ponce
Summary: Electron backscattering diffraction analyzes crystalline phases at large scales, while precession electron diffraction obtains 4D-STEM data for nanometric structure elucidation. Both techniques have limitations due to probe size and complexity of image acquisition. Advanced machine learning techniques, such as deep learning, can overcome these limitations. This research demonstrates how Gabor filters can effectively extract features from electron microscopy images, reducing the need for large training datasets. The combination of Gabor filters and unsupervised learning enables particle segmentation and crystal orientation mapping at atomic scale.
CRYSTAL RESEARCH AND TECHNOLOGY
(2023)
Article
Materials Science, Multidisciplinary
E. Gutierrez, E. Salazar, A. Salinas, R. Deaquino, A. Ponce, M. Yacaman, D. Alducin, E. Ortega, A. Bedolla, B. Fernandez, R. Martinez, C. Garay
Summary: This paper investigates the influence of graphite and milling time on the texture, microstructure, and mechanical properties of AA7075-graphite composites produced through mechanical alloying and hot extrusion. Various characterization techniques were used, including electron microscopy, X-ray diffraction, and electron diffraction, and mechanical properties were evaluated through tensile tests. The results show that the particle and crystallite size of the milled powders affect the grain size of the extruded samples. The presence of deformation texture components in recrystallized samples is explained by the oriented nucleation mechanism. Hardness, yield strength, and ultimate tensile strength increase with graphite content and milling time, while elongation to fracture decreases. The size of recrystallized grains decreases with increasing milling time and graphite content. The investigated composites are enhanced by grain refinement, dispersion of certain compounds, and the development of a random texture.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Analytical
Chris Rightsell, David Sanchez, Jose Escudero, Eduardo Ortega, Gangadharan Ajithkumar, Dhiraj Sardar, Arturo Ponce
Summary: Single-crystal Er3+:YAG has traditionally been used as a laser material, but recent research suggests that polycrystalline ceramic Er3+:YAG is a cost-effective and easily produced alternative. However, there has been limited research on the synthesis and spectroscopic characterization of Er3+:YAG nanocrystals. This study presents the synthesis of nanocrystalline Er3+:YAG and compares its spectroscopic properties with single-crystal and polycrystalline ceramic counterparts. The results show similar optical properties among the three hosts, with the nanocrystals demonstrating higher intensity in the 1.53 mu m emission. These findings highlight the potential of Er3+:YAG nanocrystals as laser materials.
Article
Materials Science, Characterization & Testing
N. J. Montes de Oca-Mora, R. M. Woo-Garcia, A. Sanchez-Vidal, R. Galvan-Martinez, R. Orozco-Cruz, A. Carmona-Hernandez, A. L. Herrera-May, J. Restrepo, I. Algredo-Badillo, F. Lopez-Huerta
Summary: Defect inspection techniques are necessary for monitoring the structural integrity of ferromagnetic structures. Early detection of failures is crucial for safety and accident prevention, allowing for timely replacement of damaged parts and cost savings. A model for numerical simulations and detection of magnetic field variations caused by rectangular defects in ferromagnetic materials is presented.
JOURNAL OF NONDESTRUCTIVE EVALUATION
(2023)
Article
Chemistry, Analytical
Ernesto A. Elvira-Hernandez, Omar I. Nava-Galindo, Elisa K. Martinez-Lara, Enrique Delgado-Alvarado, Francisco Lopez-Huerta, Arxel De Leon, Carlos Gallardo-Vega, Agustin L. Herrera-May
Summary: Researchers have developed a portable triboelectric nanogenerator (NOP-TENG) based on dehydrated nopal powder, which can convert green energy into electrical energy. This nanogenerator can be used for Internet-of-Things devices and offers a more sustainable alternative to chemical batteries. It has a simple structure, easy manufacturing process, stable electric behavior, and cost-effective output performance.
Article
Chemistry, Multidisciplinary
Alfredo Morales-Sanchez, Karla Esther Gonzalez-Flores, Sergio Alfonso Perez-Garcia, Sergio Gonzalez-Torres, Blas Garrido-Fernandez, Luis Hernandez-Martinez, Mario Moreno-Moreno
Summary: In this research, the resistive-switching (RS) characteristics in a memristor based on silicon nanocrystals (Si-NCs) integrated into a complementary metal-oxide-semiconductor (MOS) structure were investigated. Si-NCs with a diameter of 5.48 +/- 1.24 nm embedded in a SiO2/Si-NCs/SiO2 multilayer structure acted as an RS layer. The devices exhibited bipolar RS with an intermediate resistance step during SET and RESET processes, and showed an ON/OFF ratio of similar to 10^6 and a retention time larger than 10^4 s.
Article
Crystallography
Javier Flores Mendez, Aurelio Heredia H. Jimenez, Gustavo M. Minquiz, A. Morales-Sanchez, Mario Moreno, Jose Alberto Luna Lopez, Francisco Severiano, A. C. Pinon Reyes
Summary: Using a homogenization theory, the frequency dependence of the effective elastic parameters of a phononic crystal was analyzed. In particular, the high-frequency branch of the crystal exhibited a metamaterial behavior with negative values for the effective shear modulus and dynamic mass density. This study has the potential to guide the design of double negative metamaterial systems.
Article
Computer Science, Information Systems
Silvestre Salas-Rodriguez, Joel Molina-Reyes, Jaime Martinez-Castillo, Rosa M. Woo-Garcia, Agustin L. Herrera-May, Francisco Lopez-Huerta
Summary: We analyzed and modeled several conduction mechanisms in ultrathin aluminum oxide (Al2O3) films of 6 nm thickness deposited by atomic layer deposition (ALD). Our modeling results revealed the presence of ohmic conduction, Poole Frenkel emission, Schottky emission, and trap-assisted tunneling mechanisms in the Al2O3 layer. We measured a dielectric conductivity of 5 x 10(-15) S/cm, a barrier height at oxide/semiconductor interface of 2 eV, and an energy trap level into bandgap of 3.11 eV.
Article
Materials Science, Multidisciplinary
Alok Ranjan, Hejun Xu, Chaolun Wang, Joel Molina, Xing Wu, Hui Zhang, Litao Sun, Junhao Chu, Kin Leong Pey
Summary: In this study, the resistive switching in hafnium dioxide (HfO2) and aluminum oxide (Al2O3) bilayered stacks was investigated using in-situ transmission electron microscopy and X-ray energy dispersive spectroscopy. The change in conductance of the HfO2/Al2O3 stack during electrical stressing is attributed to the formation of extended nanoscale defects at the HfO2/Al2O3 interface and the migration and re-crystallization of Al into the oxide bulk. Two competing physical mechanisms, oxygen ion redistribution and Al species migration, were found to be involved in the switching process. The low diffusion barrier of the active Al electrode causes severe Al migration in the bilayered oxides, leading to device failure in resetting and limiting overall switching performance and material reliability.
APPLIED MATERIALS TODAY
(2023)
Article
Computer Science, Hardware & Architecture
Rosa M. Woo-Garcia, V. Herrera-Nevraumont, E. Osorio-de-la-Rosa, S. E. Vazquez-Valdes, F. Lopez-Huerta
Summary: A monitoring and locating system for sailboats has been developed using GPRS/GSM and GPS technology. This system can track the location of sailboats that stay within 10 km of the coast. It utilizes a GPS module to obtain boat coordinates and includes a sensing station for environmental measurements and ship movement. Data received via AVR-GPRS is stored in a SQL database. System monitoring tests were conducted on a 24-km sailboat route along the coast of the Atlantic Ocean and Gulf of Mexico.
IEEE EMBEDDED SYSTEMS LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Alejandra Romero-Moran, Joel Molina-Reyes
Summary: The study focuses on the evaluation of photocatalytic activity for the inactivation of bacteria in wastewater using catalysts fixed to surfaces. It addresses the lack of standardized methods and systematic studies in analyzing the antibacterial activity of these materials, as well as the difficulty in comparing results across different experimental conditions. The study introduces new parameters, PBIE and BIPHR, to evaluate the photocatalytic activity and demonstrates their applicability in comparing different photocatalytic coatings.
Article
Chemistry, Multidisciplinary
Juan Ramirez-Rios, Karla Esther Gonzalez-Flores, Jose Juan Aviles-Bravo, Sergio Alfonso Perez-Garcia, Javier Flores-Mendez, Mario Moreno-Moreno, Alfredo Morales-Sanchez
Summary: In this study, the stochastic model was used to simulate the SET and RESET processes in bipolar resistive switching memories with silicon nanocrystals embedded in an oxide matrix. The simulation data were compared with experimental current-voltage data from Si-NCs/SiO2 multilayer-based memristor devices. The results showed that the Si-NCs act as agglomerates of fixed oxygen vacancies, promoting the formation of conductive filaments through the multilayer. An intermediate resistive state was observed in the forming process of the 3-BL device, which can be explained by the preferential generation of oxygen vacancies through Si-NCs.
Article
Nanoscience & Nanotechnology
Jorge Luis Vazquez-Arce, Joel Molina-Reyes, Oscar Edel Contreras, Hugo Tiznado
Summary: The physics behind the switching kinetics of memristors is gradually being understood. This study introduces a model for ion migration as the rate-limiting step and shows its applicability in determining threshold voltage and diffusivity. By exploring parallel plate cells, the model is demonstrated and its potential importance is discussed for various charge carriers.
ADVANCED ELECTRONIC MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
N. E. Gonzalez-Sierra, Javier Flores Mendez, M. A. Meraz-Melo, Ana C. Pinon Reyes, German Ardul Munoz-Hernandez, Alfredo Morales-Sanchez, Mario Moreno Moreno, Gustavo M. Minquiz
Summary: This study investigates the wear characteristics of ceramic and coated carbide tools in machining gray cast iron (GCI). It is found that GCI with aging treatment has increased tensile strength, leading to improved tool life. The wear mechanisms of the tools are predominantly abrasive and adhesive wear for ceramic inserts and adhesive and oxidative wear for coated carbide tools.
APPLIED SCIENCES-BASEL
(2023)
Article
Chemistry, Applied
Qingyuan Zheng, Jack H. Williams, Scott Elgersma, Mick D. Mantle, Andrew J. Sederman, G. Leendert Bezemer, Constant M. Guedon, Lynn F. Gladden
Summary: In this study, a pilot-scale fixed-bed reactor compatible with NMR/MRI was developed for Fischer-Tropsch synthesis. Multiple magnetic resonance techniques were applied to quantitatively characterize different product species within catalyst pellets, providing valuable information for catalyst and reactor optimization.
Article
Chemistry, Applied
Lisa Ramisch, Sebastian Pfaff, Sabrina M. Gericke, Edvin Lundgren, Johan Zetterberg
Summary: We present a combination of optical operando techniques that allow simultaneous measurement of adsorbed species on catalyst surfaces, monitoring of surface oxide formation, and imaging of the gas phase above the catalyst surface. The experimental setup was validated by studying CO oxidation on Pd(100) at different pressures, revealing the effects of pressure on the heterogeneous catalytic reaction.
Article
Chemistry, Applied
Marta Paniagua, Gabriel Morales, Juan A. Melero, Daniel Garcia-Salgado
Summary: The influence of common impurities in levulinic acid on the catalytic performance of different acid catalysts for bio-jet fuel production was studied. It was found that furfural had the greatest detrimental effect on catalyst performance, while propyl-sulfonic acid-modified SBA-15 and sulfonic acid resin Amberlyst-70 showed good regeneration ability.
Article
Chemistry, Applied
Jesus Tapiador, Pedro Leo, Guillermo Calleja, Gisela Orcajo
Summary: This study presents a new MOF material, Zn-URJC-13, with acid and basic sites, permanent porosity, and high affinity to CO2 molecules. The Zn-URJC-13 catalyst exhibits efficient performance in CO2 cycloaddition reactions and can be reused multiple times.
Article
Chemistry, Applied
Dan Zhao, Vita A. Kondratenko, Dmitry E. Doronkin, Shanlei Han, Jan-Dierk Grunwaldt, Uwe Rodemerck, David Linke, Evgenii V. Kondratenko
Summary: This study demonstrates the potential of cheap and commercially available Zr or Ti-based supports and ZnO to serve as active and selective catalysts for propane dehydrogenation (PDH). The catalytically active species formed in situ under PDH conditions consist of isolated ZnOx. ZnOx on the surface of LaZrOx shows the highest rate of propene formation.
Article
Chemistry, Applied
Hanbyeol Kim, Jung Rae Kim, Young-Kwon Park, Jeong-Myeong Ha, Jungho Jae
Summary: In this study, metal phosphates were used as catalysts for biomass conversion to produce sustainable aromatics through DielsAlder cycloaddition reactions. The effects of synthesis method, activation method, and P/Ti molar ratio on the structure and acid properties of titanium phosphate catalysts were systematically studied. The mesoporous titanium phosphate catalyst synthesized by hydrothermal method at 180℃ for 12 h followed by ethanol refluxing at 60℃ for 24 h at a molar P/Ti ratio of 1 showed the highest surface area and acid site density.
Article
Chemistry, Applied
Yasin Khani, Sumin Pyo, Kwang-Eun Jeong, Chul-Ung Kim, Moonis Ali Khan, Byong-Hun Jeon, Kun-Yi Andrew Lin, Siyoung Q. Choi, Young-Kwon Park
Summary: A protonated form of Zeolite Socony Mobil-5 (H-ZSM-5) catalyst was synthesized through a hydrothermal method using different sources of silica. The effect of loading the catalyst with yttrium, samarium, and gadolinium on the acidic properties was investigated. Among the metal-loaded catalysts, the Sm/LHZ catalyst showed the best performance in the methanol to propylene conversion due to its high amount of weak and intermediate acid sites, while the Gd-LHZ catalyst increased the selectivity towards ethane and propane.
Article
Chemistry, Applied
Michael Franc, Ivana Cisarova, Jan Vesely
Summary: The present study investigates an enantioselective cyclization of enals with imidazolone derivatives catalyzed by a combination of achiral Pd(0) complex and chiral secondary amine. Corresponding spirocyclic imidazolones were produced in high yields with moderate diastereoselectivity and excellent enantioselectivity. The developed co-operative catalytic methodology provides a highly substituted spirocyclic scaffold with four stereogenic centers under mild conditions.
Article
Chemistry, Applied
Mauro Alvarez, Jennifer Cueto, David P. Serrano, Pablo Marin, Salvador Ordonez
Summary: This study focuses on improving the formulation and preparation methods of catalysts for the production of dimethyl carbonate. By using suitable catalyst preparation methods and copper salt precursors, the researchers successfully produced catalysts with optimal performance for dimethyl carbonate formation.
Article
Chemistry, Applied
Claudia J. Keijzer, Luc C. J. Smulders, Dennie Wezendonk, Jan Willem de Rijk, Petra E. de Jongh
Summary: This study investigates the catalytic behavior of alpha-alumina supported silver catalysts in the presence of chloride. It is found that the particle size of silver can affect the selectivity of the catalyst, but different strategies lead to different results. In this size range, the selectivity of ethylene oxide is correlated to the Ag : Al2O3 surface ratio.
Article
Chemistry, Applied
Takeshi Aihara, Wataru Aoki, Michikazu Hara, Keigo Kamata
Summary: The development of acid-base bifunctional catalysts is important for promoting specific chemical transformations. In this study, Ti-based perovskite oxides were synthesized and used as catalysts for two C-C bond-forming reactions (cyanosilylation and Knoevenagel condensation). The highly pure SrTiO3 nanoparticles with a high specific surface area exhibited the highest catalytic performance, and could be easily recovered and reused.
Article
Chemistry, Applied
Olga Gorlova, Petra Pribylova, Eliska Vyskocilova, Katerina Peroutkova, Jan Kohout, Iva Paterova
Summary: This study investigates the Baeyer-Villiger oxidation of beta-cyclocitral using tin-modified mixed oxides as catalysts. The optimal reaction conditions and the effects of various factors on the reaction course and selectivity were determined. The results show that tin-modified mixed oxides exhibit high activity and selectivity in the oxidation reaction.
Article
Chemistry, Applied
M. I. Avila, M. M. Alonso-Doncel, L. Briones, G. Gomez-Pozuelo, J. M. Escola, D. P. Serrano, A. Peral, J. A. Botas
Summary: The catalytic fast pyrolysis of lignin using ion-exchanged zeolite catalysts showed significant improvements in bio-oil quality and the production of aromatic hydrocarbons and oxygenated compounds.
Article
Chemistry, Applied
Enrico Catizzone, Giorgia Ferrarelli, Paolo Bruno, Girolamo Giordano, Massimo Migliori
Summary: The acid-catalysed alcohol conversion reaction is a promising route for de-fossilization strategies. Research on pure alcohol conversion and simultaneous dehydration of mixed alcohols have shown different product compositions, with the type and distribution of acid sites affecting the reaction mechanism.
Article
Chemistry, Applied
Alireza Ranjbari, Juho Kim, Jihee Yu, Jiyun Kim, Mireu Park, Nayoung Kim, Kristof Demeestere, Philippe M. Heynderickx
Summary: This study investigated a novel kinetic model for the adsorption and photocatalytic degradation of methyl orange using commercial ZnO and reduced ZnO photocatalysts. The results provided new insights into the interaction of catalysts with molecules of different charges and compared with a previous study on methylene blue. The presence of oxygen vacancies in ZnO and their effects on adsorption and photocatalytic degradation were analyzed, and the photocatalytic degradation rate of reduced ZnO was found to increase significantly.