Article
Chemistry, Physical
Junhu Zhao, Ming Li, Peng Yang, Xiangyang Jiang, Zhaojin Lv, Pier-Luc Tremblay, Tian Zhang
Summary: This study reports the production of aromatic ketones using a solid acid catalyst modified with p-divinylbenzene-vinylimidazole, 1,3-propanesultone, and trifluoromethanesulfonate. The catalyst showed high conversion and selectivity for anisole to p-methoxyacetophenone using acetic anhydride as the acylating agent. The porous acidic ionic liquid polymer efficiently acylated various aromatic substrates and was reusable.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Inorganic & Nuclear
Kaili Wang, Xiujuan Sun, Wen Huang, Qiuhan Cao, Yongjie Zhao, Rui Ding, Enhui Liu, Ping Gao, Weiwei Lin
Summary: Ni2P4O12 grown on carbon cloth exhibits excellent HER activity and stability in acid due to its unique polymer-like structure, mesoporous characteristics, and superhydrophilic surface.
DALTON TRANSACTIONS
(2021)
Article
Energy & Fuels
Kai Sun, Yuewen Shao, Peng Liu, Lijun Zhang, Guoming Gao, Dehua Dong, Shu Zhang, Guangzhi Hu, Leilei Xu, Xun Hu
Summary: A solid salt catalyst FeClx-D008 was prepared by introducing FeCl3 onto a solid acidic resin D008, replacing some acid sites and improving catalytic selectivity for the production of furfural from C5 sugars.
Article
Energy & Fuels
Yuewen Shao, Qingyin Li, Xinyi Dong, Junzhe Wang, Kai Sun, Lijun Zhang, Shu Zhang, Leilei Xu, Xiangzhou Yuan, Xun Hu
Summary: This study achieved a unprecedented yield of 90.5% in the direct conversion of biomass-derived furfural to GVL through consecutive hydrogenation and acid-catalyzed reactions over CuAl and a co-catalyst (i.e. H-ZSM-5) in ethanol. The abundance of hydrogenation sites and acidic sites plays a key role in determining the reaction network and product transfer, with different mechanisms of deactivation for the acid and hydrogenation catalysts needing consideration in future catalyst development.
Article
Polymer Science
Inchan Yang, Ji Hye Mok, Meenkyoung Jung, Jihoon Yoo, Myung-Soo Kim, Dalsu Choi, Ji Chul Jung
Summary: This study fabricates high-performance supercapacitors using activated carbons derived from polyethylene (PE), showing impressive electrochemical performance and high specific energy. It has significant implications for the development of commercial supercapacitors.
MACROMOLECULAR RAPID COMMUNICATIONS
(2022)
Article
Energy & Fuels
Sherouk M. Ibrahim, Ahmed M. El-Sherbeeny, Jae-Jin Shim, Ali A. AlHammadi, Mostafa R. Abukhadra
Summary: Raw coal treated with sulfuric acid as a controlled sulfonation process can be used as an acidic catalyst for transesterification reactions, showing good catalytic performance and reusability. The synthetic catalyst (S.Coal) exhibits remarkable acid density and surface area, leading to high catalytic efficiency in both low and high-temperature conditions. Additionally, the kinetic properties of transesterification reactions over S.Coal follow Pseudo-First order behavior with low activation energy.
Article
Energy & Fuels
Marwa M. Naeem, Eslam G. Al-Sakkari, Daria C. Boffito, Mamdouh A. Gadalla, Fatma H. Ashour
Summary: A KOH/corncobs-derived activated carbon (AC) heterogeneous catalyst was developed for single stage biodiesel production from highly acidic waste vegetable oil, showing activity in both esterification and transesterification reactions. Optimal conditions of sulfuric acid to raw corn cobs ratio, activation temperature, reaction time, catalyst loading, and temperature were identified to achieve a high yield of 97.8% meeting ASTM standards. The catalyst exhibited stability for up to five successive uses in esterification but easily leached KOH and became inactive in transesterification.
Article
Chemistry, Physical
Kai Cui, Wei Qian, Zhengjiang Shao, Xiuge Zhao, Honghui Gong, Xinjia Wei, Jiajia Wang, Manyu Chen, Xiaoming Cao, Zhenshan Hou
Summary: Ru nanoparticles supported on a sulfonated carbon layer coated SBA-15 have been demonstrated as an efficient bi-functional catalyst for the one-step conversion of FFR into 1,4-PeDO. The introduction of acidic groups on the support surface and the highly dispersed Ru(0) sites in close proximity to the surface -SO3H groups were key factors contributing to the excellent selectivity and conversion rates.
Article
Chemistry, Multidisciplinary
Songdang Zhang, Hu Pan, Jinshu Huang, Yuncong Li, Heng Zhang
Summary: In this study, a renewable SiO2@Cs-SO3H solid acid catalyst was successfully prepared and demonstrated to exhibit high catalytic activity and good reusability in biodiesel production. The optimal reaction conditions were obtained using Response Surface Methodology, with the experimental biodiesel yield close to the predicted value, indicating good reliability of the method used.
FRONTIERS IN CHEMISTRY
(2022)
Article
Chemistry, Physical
Kristian Juul Omann, Raghunandan Sharma, Per Morgen, Saso Gyergyek, Mikkel Juul Larsen, Shuang Ma Andersen
Summary: In this study, the effects of the catalyst support surface chemical/physical state on the electrochemical performance of Pt/C electrocatalysts were investigated. Pt/C electrocatalysts were synthesized using a microwave-assisted polyol process, and their structural characteristics and surface properties were characterized. The results showed that the Pt/C catalysts supported on a carbon with a higher surface oxygen content exhibited better durability, attributed to the presence of oxygen functional groups that inhibit Ostwald ripening to some extent.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Multidisciplinary Sciences
Jie Dai, Yinlong Zhu, Yu Chen, Xue Wen, Mingce Long, Xinhao Wu, Zhiwei Hu, Daqin Guan, Xixi Wang, Chuan Zhou, Qian Lin, Yifei Sun, Shih-Chang Weng, Huanting Wang, Wei Zhou, Zongping Shao
Summary: This study presents the design of a Pt-containing complex oxide that utilizes atomic-scale hydrogen spillover to promote H-2 evolution electrocatalysis in acidic media. Experimental and theoretical calculations reveal the hydrogen evolution pathway and mechanism facilitated by hydrogen spillover, demonstrating the excellent performance and enhanced durability of the complex oxide catalyst compared to commercial ones.
NATURE COMMUNICATIONS
(2022)
Article
Multidisciplinary Sciences
Zesong Ma, Zhilong Yang, Wenchuan Lai, Qiyou Wang, Yan Qiao, Haolan Tao, Cheng Lian, Min Liu, Chao Ma, Anlian Pan, Hongwen Huang
Summary: This study demonstrates the successful electrochemical reduction of CO2 to multicarbon products in strongly acidic electrolyte by combining the confinement effect and cation effect, showing high Faradaic efficiency, partial current density, and stability. The cation effect is found to play a crucial role in C-C coupling.
NATURE COMMUNICATIONS
(2022)
Article
Agricultural Engineering
Alchris Woo L. Go, Yi Chang Xiao, Kristelle Quijote, Chintya Gunarto, Roxanne Kathlyn O. Alivio, Yi-Hsu Ju, Artik Elisa Angkawijaya, Shella Permatasari Santoso
Summary: This study presents a new approach and concept for the conversion of sugarcane bagasse (SCB) generated in the commercial sector, and successfully synthesizes a high-value product, solid acid catalyst (SAC). By conducting dilute acid hydrolysis (DAH) and drying carbonization sulfonation processes, SCB was transformed into carbonized and sulfonated post-hydrolysis SCB (PHSCB). The synthesized catalyst showed excellent conversion performance in biodiesel production.
BIOMASS & BIOENERGY
(2022)
Article
Materials Science, Paper & Wood
Zheng Qu, Ying Han, Zihao Ma, Qingyu Wang, Xing Wang, Yao Li, Guangwei Sun
Summary: This article examines the impact of raw material size on the shape, sulfonation degree, and catalytic activity of carbon-based solid acids. Different sizes of microcrystalline cellulose, cellulose nanocrystals, and cotton fiber pulp were used as carbon sources to synthesize carbon-based solid acids. The results show that the solid acids generated from microcrystalline cellulose have the most homogeneous shape, highest sulfonation degree, and highest catalytic activity.
Article
Agricultural Engineering
Yanan Dai, Shujuan Yang, Tianhao Wang, Rong Tang, Ye Wang, Liping Zhang
Summary: A solid acid catalyst based on corncob residue was used to improve furfural production. The addition of NaCl was found to increase furfural yield. The optimal reaction conditions were determined to be 1:1 xylose/catalyst ratio, 190°C, 60 minutes reaction time, and 60 g/L NaCl.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
Engineering, Environmental
Wenjiao Ge, Shan Cao, Yang Yang, Orlando J. Rojas, Xiaohui Wang
Summary: The study proposes a double network hydrogel synthesized by one-step polymerization reaction, utilizing LiCl to enhance interactions between the colloidal phase and water molecules, ensuring water retention capability and freezing tolerance over a wide temperature range. The synergy between LiCl and CNF maintains mechanical strength and enables high stretchability and ionic conductivity in the system at low temperatures.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Polymer Science
Yang Yang, Quanbo Huang, Wenjiao Ge, Junli Ren, Thomas Heinze, Xiaohui Wang
Summary: A novel approach to fabricate highly flexible and conductive paper using electroless deposition with the assistance of aminocellulose as the interface layer is proposed. The resulting paper coated with Cu nanoparticles demonstrates excellent conductivity and stability. This method opens up new opportunities for large-scale production of flexible and wearable electronics.
MACROMOLECULAR RAPID COMMUNICATIONS
(2021)
Article
Chemistry, Applied
Bin Gu, Qimeng Jiang, Bichong Luo, Chuanfu Liu, Junli Ren, Xiaohui Wang, Xiaoying Wang
Summary: A new nanocomposite film was synthesized in this study, showing durable antibacterial effect against E. coli and S. aureus and no toxicity to cells.
CARBOHYDRATE POLYMERS
(2021)
Article
Engineering, Environmental
Ruwei Chen, Xinsheng Li, Quanbo Huang, Hao Ling, Yang Yang, Xiaohui Wang
Summary: The reasonable design of hybrid graphene aerogels with low cost, high specific surface area, and excellent mechanical properties is significant for future large-scale energy storage applications. A composite aerogel of biomass carbon/reduced graphene oxide/nanocellulose was successfully prepared, showing high mechanical strength, specific surface area, and efficient capacitive performance. This work provides an effective method to fabricate low-cost hybrid graphene aerogel materials with excellent performances for wide applications.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Yijie Hu, Hao Zhuo, Yu Zhang, Haihong Lai, Jiwang Yi, Zehong Chen, Xinwen Peng, Xiaohui Wang, Chuanfu Liu, Runcang Sun, Linxin Zhong
Summary: Inspired by the function of ligaments in biological structure, graphene oxide nanosheets are introduced to encapsulate liquid metal droplets, forming a flexible LM/GO core-shell microstructure that creates a tough hydrogel with high strength and abrasion resistance, providing a new possibility for using LM in flexible devices.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Physical
Rui Li, Qixuan Lin, Yingxiong Wang, Weiran Yang, Xinxin Liu, Weiying Li, Xiaohui Wang, Xiaoying Wang, Chuanfu Liu, Junli Ren
Summary: Efficient conversion of glucose to pentose (xylose and arabinose) and formic acid was achieved using non-toxic artificial zeolite and green solvent of gamma-butyrolactone-H2O. The selective conversion of glucose to desired products was regulated by controlling Bronsted acid strength, offering a new approach to utilize glucose for expanding the varieties of platform chemicals.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Nanoscience & Nanotechnology
Manman Xu, Yunqing Huang, Ruwei Chen, Quanbo Huang, Yang Yang, Linxin Zhong, Junli Ren, Xiaohui Wang
Summary: This study successfully synthesized three-dimensional hierarchically porous carbon from Ganoderma lucidum residues, which exhibited excellent electrochemical performance and cycling stability when applied as supercapacitor electrodes. This research broadens the application of Chinese medicine residues in the field of energy storage and provides a new avenue for high value conversion of waste resources.
ADVANCED COMPOSITES AND HYBRID MATERIALS
(2021)
Article
Biochemistry & Molecular Biology
Boyu Du, Xing Wang, Lanfang Chai, Xiaohui Wang, Zheng Pan, Xiaohong Chen, Jinghui Zhou, Run-Cang Sun
Summary: The high-value utilization of food wastes in sustainable development has attracted great interest. Lightweight lignin-based carbon nanofibers, fabricated from melon seed shells and peanut shells, show excellent supercapacitor performance and electromagnetic absorption properties, making them ideal for lightweight supercapacitor electrodes and electromagnetic wave absorbers applications.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Review
Polymer Science
Wenjiao Ge, Jianbo Shuai, Yuyuan Wang, Yuxi Zhou, Xiaohui Wang
Summary: Cellulose is an excellent candidate for sustainable materials with its good availability, renewability, biodegradability, and biocompatibility. However, its poor solubility in water and common organic solvents restricts chemical modification to heterogeneous conditions or limited systems. Recent advancements in green solvents have enabled more efficient and sustainable chemical modification of cellulose.
Article
Chemistry, Multidisciplinary
Yang Yang, Heqin Huang, Dan Xu, Xiaojie Wang, Ye Chen, Xiaohui Wang, Kai Zhang
Summary: This study explores the preparation of complex 3D structures with aligned cellulose nanocrystals (CNCs) from dynamic hydrogels, forming pseudo catenoid hollow xerogels through mechanical stretching and air-drying. The mechanical properties of the pseudo catenoid architecture are controlled at two stages on diverse length scales by the aligned CNCs and the geometry of the xerogels, offering a new perspective for designing advanced materials with tailored mechanical properties and functions.
Article
Chemistry, Multidisciplinary
Ruwei Chen, Hao Ling, Quanbo Huang, Yang Yang, Xiaohui Wang
Summary: By engineering an active nitrogen-doped carbon interface with high conductivity, porosity, and electrolyte affinity on a flexible cellulose electrode surface, high-capacity flexible supercapacitors with fast electron transport and ion migration properties are achieved.
Article
Nanoscience & Nanotechnology
Shan Cao, Wenjiao Ge, Yang Yang, Quanbo Huang, Xiaohui Wang
Summary: This study demonstrates the feasibility of preparing high-strength, flexible, and conductive graphene/polypropylene fiber paper through a traditional papermaking process. The composite paper shows promising properties such as high strength, good conductivity, shielding effectiveness, water resistance, fungi-proof, and thermal conductivity, expanding the potential industrial application of graphene materials.
ADVANCED COMPOSITES AND HYBRID MATERIALS
(2022)
Article
Chemistry, Physical
Quanbo Huang, Yang Yang, Ruwei Chen, Xiaohui Wang
Summary: A fully paper-based all-solid-state supercapacitor was developed using functionalized cellulose paper as electrodes, carboxymethyl cellulose gel as solid electrolyte, and cellulose paper as separator. The supercapacitor exhibited high conductivity and high-rate capability, with the ability to recover capacitance efficiency through wetting.
Article
Chemistry, Organic
Xiye Yang, Shaofeng Huang, Michael Ortiz, Xubo Wang, Yunhao Cao, Oula Kareem, Yinghua Jin, Fei Huang, Xiaohui Wang, Wei Zhang
Summary: Dynamic alkyne metathesis has been used to synthesize shape-persistent macrocycles and COPs. Two new COPs, TC1 and TC3, designed based on truxene moieties, were successfully synthesized under open air conditions. The COPs can act as discrete fullerene acceptors, forming host-guest complexes with fullerenes, and have potential applications in artificial photosynthetic systems and optoelectronics.
ORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Physical
Tao Jia, Jiabin Zhang, Kai Zhang, Haoran Tang, Sheng Dong, Ching-Hong Tan, Xiaohui Wang, Fei Huang
Summary: This study designed a series of large-bandgap polymer donors and validated their device performances in all-polymer solar cells by combining them with a polymer acceptor, achieving high efficiency with a maximum of 15.8%. The systems showed more efficient charge transfer and less charge recombination as the energy-level offsets increased, leading to improved short-circuit current density, fill factors, and power conversion efficiency.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Applied
Qingyuan Zheng, Jack H. Williams, Scott Elgersma, Mick D. Mantle, Andrew J. Sederman, G. Leendert Bezemer, Constant M. Guedon, Lynn F. Gladden
Summary: In this study, a pilot-scale fixed-bed reactor compatible with NMR/MRI was developed for Fischer-Tropsch synthesis. Multiple magnetic resonance techniques were applied to quantitatively characterize different product species within catalyst pellets, providing valuable information for catalyst and reactor optimization.
Article
Chemistry, Applied
Lisa Ramisch, Sebastian Pfaff, Sabrina M. Gericke, Edvin Lundgren, Johan Zetterberg
Summary: We present a combination of optical operando techniques that allow simultaneous measurement of adsorbed species on catalyst surfaces, monitoring of surface oxide formation, and imaging of the gas phase above the catalyst surface. The experimental setup was validated by studying CO oxidation on Pd(100) at different pressures, revealing the effects of pressure on the heterogeneous catalytic reaction.
Article
Chemistry, Applied
Marta Paniagua, Gabriel Morales, Juan A. Melero, Daniel Garcia-Salgado
Summary: The influence of common impurities in levulinic acid on the catalytic performance of different acid catalysts for bio-jet fuel production was studied. It was found that furfural had the greatest detrimental effect on catalyst performance, while propyl-sulfonic acid-modified SBA-15 and sulfonic acid resin Amberlyst-70 showed good regeneration ability.
Article
Chemistry, Applied
Jesus Tapiador, Pedro Leo, Guillermo Calleja, Gisela Orcajo
Summary: This study presents a new MOF material, Zn-URJC-13, with acid and basic sites, permanent porosity, and high affinity to CO2 molecules. The Zn-URJC-13 catalyst exhibits efficient performance in CO2 cycloaddition reactions and can be reused multiple times.
Article
Chemistry, Applied
Dan Zhao, Vita A. Kondratenko, Dmitry E. Doronkin, Shanlei Han, Jan-Dierk Grunwaldt, Uwe Rodemerck, David Linke, Evgenii V. Kondratenko
Summary: This study demonstrates the potential of cheap and commercially available Zr or Ti-based supports and ZnO to serve as active and selective catalysts for propane dehydrogenation (PDH). The catalytically active species formed in situ under PDH conditions consist of isolated ZnOx. ZnOx on the surface of LaZrOx shows the highest rate of propene formation.
Article
Chemistry, Applied
Hanbyeol Kim, Jung Rae Kim, Young-Kwon Park, Jeong-Myeong Ha, Jungho Jae
Summary: In this study, metal phosphates were used as catalysts for biomass conversion to produce sustainable aromatics through DielsAlder cycloaddition reactions. The effects of synthesis method, activation method, and P/Ti molar ratio on the structure and acid properties of titanium phosphate catalysts were systematically studied. The mesoporous titanium phosphate catalyst synthesized by hydrothermal method at 180℃ for 12 h followed by ethanol refluxing at 60℃ for 24 h at a molar P/Ti ratio of 1 showed the highest surface area and acid site density.
Article
Chemistry, Applied
Yasin Khani, Sumin Pyo, Kwang-Eun Jeong, Chul-Ung Kim, Moonis Ali Khan, Byong-Hun Jeon, Kun-Yi Andrew Lin, Siyoung Q. Choi, Young-Kwon Park
Summary: A protonated form of Zeolite Socony Mobil-5 (H-ZSM-5) catalyst was synthesized through a hydrothermal method using different sources of silica. The effect of loading the catalyst with yttrium, samarium, and gadolinium on the acidic properties was investigated. Among the metal-loaded catalysts, the Sm/LHZ catalyst showed the best performance in the methanol to propylene conversion due to its high amount of weak and intermediate acid sites, while the Gd-LHZ catalyst increased the selectivity towards ethane and propane.
Article
Chemistry, Applied
Michael Franc, Ivana Cisarova, Jan Vesely
Summary: The present study investigates an enantioselective cyclization of enals with imidazolone derivatives catalyzed by a combination of achiral Pd(0) complex and chiral secondary amine. Corresponding spirocyclic imidazolones were produced in high yields with moderate diastereoselectivity and excellent enantioselectivity. The developed co-operative catalytic methodology provides a highly substituted spirocyclic scaffold with four stereogenic centers under mild conditions.
Article
Chemistry, Applied
Mauro Alvarez, Jennifer Cueto, David P. Serrano, Pablo Marin, Salvador Ordonez
Summary: This study focuses on improving the formulation and preparation methods of catalysts for the production of dimethyl carbonate. By using suitable catalyst preparation methods and copper salt precursors, the researchers successfully produced catalysts with optimal performance for dimethyl carbonate formation.
Article
Chemistry, Applied
Claudia J. Keijzer, Luc C. J. Smulders, Dennie Wezendonk, Jan Willem de Rijk, Petra E. de Jongh
Summary: This study investigates the catalytic behavior of alpha-alumina supported silver catalysts in the presence of chloride. It is found that the particle size of silver can affect the selectivity of the catalyst, but different strategies lead to different results. In this size range, the selectivity of ethylene oxide is correlated to the Ag : Al2O3 surface ratio.
Article
Chemistry, Applied
Takeshi Aihara, Wataru Aoki, Michikazu Hara, Keigo Kamata
Summary: The development of acid-base bifunctional catalysts is important for promoting specific chemical transformations. In this study, Ti-based perovskite oxides were synthesized and used as catalysts for two C-C bond-forming reactions (cyanosilylation and Knoevenagel condensation). The highly pure SrTiO3 nanoparticles with a high specific surface area exhibited the highest catalytic performance, and could be easily recovered and reused.
Article
Chemistry, Applied
Olga Gorlova, Petra Pribylova, Eliska Vyskocilova, Katerina Peroutkova, Jan Kohout, Iva Paterova
Summary: This study investigates the Baeyer-Villiger oxidation of beta-cyclocitral using tin-modified mixed oxides as catalysts. The optimal reaction conditions and the effects of various factors on the reaction course and selectivity were determined. The results show that tin-modified mixed oxides exhibit high activity and selectivity in the oxidation reaction.
Article
Chemistry, Applied
M. I. Avila, M. M. Alonso-Doncel, L. Briones, G. Gomez-Pozuelo, J. M. Escola, D. P. Serrano, A. Peral, J. A. Botas
Summary: The catalytic fast pyrolysis of lignin using ion-exchanged zeolite catalysts showed significant improvements in bio-oil quality and the production of aromatic hydrocarbons and oxygenated compounds.
Article
Chemistry, Applied
Enrico Catizzone, Giorgia Ferrarelli, Paolo Bruno, Girolamo Giordano, Massimo Migliori
Summary: The acid-catalysed alcohol conversion reaction is a promising route for de-fossilization strategies. Research on pure alcohol conversion and simultaneous dehydration of mixed alcohols have shown different product compositions, with the type and distribution of acid sites affecting the reaction mechanism.
Article
Chemistry, Applied
Alireza Ranjbari, Juho Kim, Jihee Yu, Jiyun Kim, Mireu Park, Nayoung Kim, Kristof Demeestere, Philippe M. Heynderickx
Summary: This study investigated a novel kinetic model for the adsorption and photocatalytic degradation of methyl orange using commercial ZnO and reduced ZnO photocatalysts. The results provided new insights into the interaction of catalysts with molecules of different charges and compared with a previous study on methylene blue. The presence of oxygen vacancies in ZnO and their effects on adsorption and photocatalytic degradation were analyzed, and the photocatalytic degradation rate of reduced ZnO was found to increase significantly.