4.8 Article

Preparation of 3D interconnected hierarchical porous N-doped carbon nanotubes

期刊

CARBON
卷 129, 期 -, 页码 199-206

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2017.12.018

关键词

Palygorskite; Polyaniline gel; N-doped carbon nanotube; Hierarchical porous structure; Supercapacitor

资金

  1. Fundamental Research Funds for the Central Universities [30916014103]
  2. Advanced Catalysis and Green Manufacturing Collaborative Innovation Center of Jiangsu Province [ACGM2016-06-11]
  3. Innovation Team of Six Talent Peaks of Jiangsu Province [XCL-CXTD-029]
  4. Key R & D Programs of Huaian City [HAG201630]
  5. National Science Foundation of China [51702026, 51772156, 51674043]

向作者/读者索取更多资源

3D interconnected hierarchical porous N-doped carbon nanotubes (IHPNCs) were fabricated using palygorskite as template and polyaniline gel as carbon source, respectively. The prepared 3D IHPNCs show high specific surface area (517.02 m(2) g(-1)), hierarchical porous structure (micropore (0.39 nm), mesopore (4.0 nm), macropore (>= 50 nm)) and N-containing surface functionalities (pyridinic-N, pyrrolic-N, graphitic-N, N-oxides). Notably, the obtained 3D IHPNC electrodes exhibit a high specific capacitance of 389 F g(-1) at 1 A g(-1), excellent rate capability (290 F g(-1) at 50 A g(-1), 75% of capacitance retention) and cycling stability with 90% retention after 10000 cycles. Furthermore, the assembled 3D IHPNC symmetric supercapacitor delivers a high energy density of 8.7 Wh.kg(-1) at a power density of 195 W.kg(-1) in 1.0 M Na2SO4 electrolyte, which is expected as a promising electrode candidate for supercapacitors. (C) 2017 Elsevier Ltd. All rights reserved.

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