4.8 Article

Transition metal assisted synthesis of tunable pore structure carbon with high performance as sodium/lithium ion battery anode

期刊

CARBON
卷 129, 期 -, 页码 667-673

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2017.12.054

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资金

  1. National Key Basic Research Program of China [2014CB932400]
  2. National Natural Science Foundation of China [51232005, 51372131, U1401243, 51672156]
  3. Shenzhen Technical Plan Project [JCYJ 20150529164918735, KQJSCX20160226191136, JCYJ20170412170911187]
  4. Guangdong Technical Plan Project [2015TX01N011]
  5. Production-study-research cooperation project of Guangdong province [2014B090901021]
  6. International Collaboration Project of Tsinghua University Initiative Scientific Research Program [20173080001]
  7. Hong Kong Scholars Program [XJ2015027]
  8. China Postdoctoral Science Foundation [2016M601018]
  9. 973 program of China [2015CB932500]
  10. gs10:National Natural Science Foundation of China [51722207]
  11. Beijing Nova Program [Z161100004916099]

向作者/读者索取更多资源

Template method has been used as an important method to prepare porous materials. However, there are few reports about template method employing potassium chloride as template. Here, potassium chloride is employed as a template to prepare the porous carbon, and transition metal nitrates (Fe(NO3)(2), d Co(NO3)(2), Ni(NO3)(2)) are introduced to catalyze graphitization and to result different carbon structure during carbonization (denoted as Fe@C, Co@C and Ni@C). The Fe@C shows a formicary-like structure with an about 20 nm pore diameter and the Co@C displays a completely compact structure. Whereas, the Ni@C exhibits a foam-like structure with hierarchical porous structure consisting of macroporous frameworks, mesopores and ultrathin porous walls (similar to 5 nm). Its macropore and mesopore diameter is around 100 nm and 4 nm, respectively, its specific surface area is 464.5 m(2) g(-1). When adopted as anode material, the Ni@C presents much outstanding rate and cycling capability for lithium and sodium storage than Fe@C and Co@C, the capacity for sodium storage is 260 mAh g(-1) after 100 cycles at 100mA g(-1) and 92 mAh g(-1) after 1000 cycles at 1A g(-1), and the capacity for lithium storage is 683 mAh g(-1) after 1000 cycles at a current density of 1 A g(-1). (C) 2017 Published by Elsevier Ltd.

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