Article
Chemistry, Multidisciplinary
Roberto Colombo, Daniele Versaci, Julia Amici, Federico Bella, Maria Laura Para, Nadia Garino, Marco Laurenti, Silvia Bodoardo, Carlotta Francia
Summary: In this study, a composite material based on doped reduced graphene oxide embedded with zinc sulfide nanoparticles was synthesized using a facile and solvent-free microwave method. The composite material showed improved battery performance, with a higher specific capacity at high rate and enhanced cycling stability. The heteroatomic doping process and the presence of zinc sulfide nanoparticles played a beneficial role in reducing polysulfide loss and improving redox kinetics.
Article
Chemistry, Multidisciplinary
Alfonso Pozio, Mariasole Di Carli, Annalisa Aurora, Mauro Falconieri, Livia Della Seta, Pier Paolo Prosini
Summary: Activated hard carbons from waste biomasses were used as active materials for battery electrodes, showing good performance in lithium-sulfur and lithium-ion batteries.
Article
Chemistry, Multidisciplinary
Nawraj Sapkota, Shailendra Chiluwal, Prakash Parajuli, Alan Rowland, Ramakrishna Podila
Summary: The practical applications of sulfurized polymer (SP) materials in Li-S batteries (LSBs) are often overlooked due to their low sulfur content. However, using a comprehensive array of tools, it has been shown that SP materials can function as pseudocapacitors with an active carbon backbone. Analysis of LSBs containing SP materials with an active carbon skeleton reveals their suitability for achieving high energy density targets at the cell level.
Article
Materials Science, Multidisciplinary
Amarsingh Bhabu Kanagaraj, Prerna Chaturvedi, Yeonho Kim, Daniel S. Choi
Summary: Different weight ratios of sulfur and multi-walled carbon nanotubes composite electrodes were prepared for lithium-sulfur batteries, with equal weight ratio showing the best electrochemical performance. The composite electrode delivered high initial discharge capacity and good capacity retention even at high current densities.
Article
Energy & Fuels
Christina Floraki, Antonis Sapountzis, Dimitra Vernardou
Summary: Lithium-ion batteries with composite electrodes based on graphene have advantages of low cost, high safety, and good performance. Chemical vapor deposition has been used to overcome electrode issues for large-scale deployment. This mini review summarizes the synthetic strategies of graphene-based composite electrodes and their potential applications.
Article
Chemistry, Physical
Liyuan Jiang, Zixi Wang, Peng Pan, Jieting Mao, Changke Ni, Mengmeng Zhang, Qian Chen, Ying Zeng, Yi Hu
Summary: By combining a glass fiber separator modified with excimer ultraviolet light with graphene, polysulfide diffusion can be effectively blocked and the utilization rate of active materials can be improved.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Nanoscience & Nanotechnology
Robert Ilango Pushparaj, Deniz Cakir, Xin Zhang, Shuai Xu, Michael Mann, Xiaodong Hou
Summary: A novel coal-derived graphene-intercalated MoS2 heterostructure was successfully prepared using a facile hydrothermal approach followed by high-temperature calcination. This heterostructure exhibited remarkable electrochemical performance, particularly in terms of Li-ion diffusion and high-rate capability.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Review
Chemistry, Physical
Lei Zhou, Dmitri L. Danilov, Ruediger-A. Eichel, Peter H. L. Notten
Summary: Lithium-sulfur batteries are seen as a viable alternative to future energy storage devices due to their high theoretical energy density. However, the main challenge lies in the leakage and migration of sulfur species. Recent research has focused on developing sulfur host materials that can effectively anchor polysulfides for improved battery performance.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Minggao Zuo, Hui Liu, Yanqi Feng, Junqi Li, Xuanmeng He, Xin Tian
Summary: In this study, a three-dimensional hollow heterostructure is developed as an electrode for lithium-sulfur batteries, effectively addressing the issues of shuttle effect and sluggish redox chemistry. The electrode can confine sulfur/polysulfides within hollow microspheres and achieve catalytic conversion of polysulfides to solid state. Experimental results show that the electrode exhibits an extremely low fading rate of 0.025% per cycle after 1000 cycles.
SOLID STATE IONICS
(2022)
Article
Nanoscience & Nanotechnology
Sajad Rahimi, Lorenzo Stievano, Laetitia Dubau, Cristina Iojoiu, Laureline Lecarme, Fannie Alloin
Summary: Lithium-sulfur (LSB) batteries have high theoretical energy density and low cost, making them a promising choice for next-generation energy storage. By using well-designed sulfur host materials, such as Fe or Co single atoms embedded on N-doped reduced graphene oxide, the challenges of LSB can be addressed and the electrochemical performance can be enhanced.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Inorganic & Nuclear
Xin-Yang Dong, Ming-Liang Wang, Yi Feng, Jia-Yuan Zhang, Yun-Dong Cao, Guang-Gang Gao, Yu-Xi Zhang, Lin-Lin Fan
Summary: The research demonstrates the effect of vanadium atom substitution on the cycling performance of a sulfur cathode and develops a PW11V-based sulfur cathode for high-performance lithium sulfur batteries.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Physical
Tingjiao Xiao, Qianwu Chen, Wen Zhong, Mingzhi Yang, Feipeng Cai, Weiliang Liu, Manman Ren, Yuanhao Wang
Summary: In this study, a composite of cobalt metal nanoparticles/three-dimensional carbon/reduced graphene oxide was synthesized using corn husk, ZIF-67, and graphene oxide. This composite was used as a modifier for commercial polypropylene to prepare a separator for lithium-sulfur batteries. The electrochemical performance of the composite separator was found to be better than that of the commercial separator due to the synergy effects of the three-dimensional carbon skeleton, reduced graphene oxide, and cobalt metal nanoparticles.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Multidisciplinary
Zhiyuan Han, Shiyong Zhao, Jiewen Xiao, Xiongwei Zhong, Jinzhi Sheng, Wei Lv, Qianfan Zhang, Guangmin Zhou, Hui-Ming Cheng
Summary: The study reveals that the d-p orbital hybridization between single-atom metals and sulfur species can serve as a descriptor for understanding the catalytic activity of SACs in Li-S batteries. Transition metals with lower atomic numbers, such as titanium, have been found to effectively bind lithium polysulfides and catalyze their electrochemical reaction. Single-atom metal catalysts embedded in three-dimensional electrodes prepared through a nitrogen coordination approach show high catalytic activity and low catalyst loading for improved sulfur utilization in Li-S batteries.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Ting-Yu Lee, Wei-Ren Liu
Summary: By introducing reduced graphene oxide, the study effectively buffered the volume expansion of CoIn2S4, leading to improved cycle performance in lithium ion batteries.
Article
Chemistry, Physical
Qi Cheng, Zhouhong Yin, Zhenxiao Pan, Xinhua Zhong, Huashang Rao
Summary: This study designed and prepared lightweight electrodes without binders and metal current collectors to assemble high energy density Li-S batteries, achieving high sulfur loading and content, thereby improving the cycling and rate performance of the batteries.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Ander Orue, Juan Miguel Lopez del Amo, Frederic Aguesse, Montse Casas-Cabanas, Pedro Lopez-Aranguren
Summary: By using multi-walled carbon nanotubes in the design and optimization of composite electrodes, high-performance Li-metal solid-state cells were achieved with a capacity retention rate of 92% at high current densities, demonstrating great potential.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Physical
Noel Diez, Marta Sevilla, Antonio B. Fuertes
Summary: N/S-co-doped carbon nanoparticles with small size and highly disordered microstructure, high N and S doping level, and short solid-state diffusion distances have been successfully synthesized for sodium storage applications.
Article
Chemistry, Physical
Miguel Granados-Moreno, Gelines Moreno-Fernandez, Roman Mysyk, Daniel Carriazo
Summary: In this study, a graphene-embedded Sn-based material and an activated carbon/lithium iron phosphate composite were developed for a high-performing hybrid lithium-ion capacitor (LIC). The negative electrode consisted of nano-sized crystalline tin pyrophosphate (SnP2O7) particles embedded in a graphenic matrix, and the positive electrode combined a high-loading lithium iron phosphate (LFP) with a graphene-activated carbon. The optimized LIC showed high energy densities and overcame the power limitations of LICs that use high-content battery-type materials.
SUSTAINABLE ENERGY & FUELS
(2023)
Article
Electrochemistry
M. Enterria, R. Mysyk, L. Medinilla, S. Villar-Rodil, J. I. Paredes, I. Rincon, F. J. Fernandez-Carretero, K. Gomez, J. M. Lopez del Amo, N. Ortiz-Vitoriano
Summary: In order to overcome the challenges of Na-O2 batteries and develop cheap, metal-free, and abundant electrocatalysts, boron and nitrogen-functionalized graphene aerogels were explored. The results showed an improvement in cycling overpotential and coulombic efficiency with the functionalized graphene aerogels. However, the nitrogen-containing cathode exhibited a shorter cycle life and decreased charging stability. On the other hand, functionalization with boron-containing groups showed promise with minimized parasitic products and enhanced cell efficiency, resulting in a cycle life of 70 cycles.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Physical
Julen Castillo, Alexander Santiago, Xabier Judez, Jose Antonio Coca-Clemente, Amaia Saenz de Buruaga, Juan Luis Gomez-Urbano, Jose Antonio Gonzalez-Marcos, Michel Armand, Chunmei Li, Daniel Carriazo
Summary: The increasing demand for electrical energy storage has led to the exploration of alternative battery technologies that can overcome the limitations of lithium-ion batteries. Lithium-sulfur batteries have attracted attention due to their low cost, high theoretical capacity, and sustainability. However, there are intrinsic limitations that need to be addressed for their commercialization. In this study, different formulations with functional carbonaceous additives were used to develop high-performing lithium-sulfur batteries. The additives improved the electrochemical properties of the sulfur cathodes, resulting in remarkable capacity and excellent C-rate response.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Polymer Science
Julen Castillo, Adrian Robles-Fernandez, Rosalia Cid, Jose Antonio Gonzalez-Marcos, Michel Armand, Daniel Carriazo, Heng Zhang, Alexander Santiago
Summary: Gel polymer electrolytes (GPEs) based on poly(vinylidene difluoride) (PVdF) are promising for high-performing lithium-sulfur batteries (LSBs), but their stability with lithium metal (Li-0) anode is a major drawback. This study investigates the stability of PVdF-based GPEs with Li-0 and their application in LSBs. The introduction of lithium nitrate in the electrolyte significantly improves the capacity retention of the GPEs. The study emphasizes the need for anode protection processes when using PVdF-based GPEs in LSBs.
Article
Nanoscience & Nanotechnology
Pierre Ranque, Nicola Boaretto, Haritz Perez-Furundarena, Hugo Arrou-Vignod, Kerman Gomez Castresana, Francisco Javier Bonilla, Rosaliaa Cid, Juan Miguel Lopez del Amo, Michel Armand, Shanmukaraj Devaraj
Summary: Li metal secondary batteries are highly anticipated energy storage systems, but their instability with common Li-ion battery electrolytes can be alleviated by using a polymer electrolyte. Current trends focus on improving ionic conductivity, mechanical stability, and electrochemical stability. This study presents a multifunctional polysalt synthesized from sustainable materials, which shows high compatibility with Li metal and quasi-single-ion conducting property, making it suitable for high-voltage Li metal anode polymer batteries.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Nekane Nieto, Julien Porte, Damien Saurel, Lisa Djuandhi, Neeraj Sharma, Alexander Lopez-Urionabarrenechea, Veronica Palomares, Teofilo Rojo
Summary: Hard carbons are produced from waste biomass (spent coffee grounds, sunflower seed shells and rose stems) by two methods: direct pyrolysis and by combined hydrothermal carbonization and pyrolysis. Electrochemical performance of as-obtained hard carbons using hydrothermal carbonization combined with pyrolysis is improved with up to 76% ICE and 280 mAh g-1 at C/5.
Article
Chemistry, Physical
Maria Dolores Casal, Noel Diez, Sara Paya, Marta Sevilla
Summary: S-doped carbon sheets were easily prepared from cork through ball-milling, achieving >14 wt % S doping using a cost-effective and environmentally benign S dopant. The synthesized materials provided high Na storage capacities and could handle large current densities. Highly porous carbon sheets with a BET surface area > 2700 m(2) g(-1) were also obtained through chemical activation, showing good anion storage capacities. Sodium-ion capacitors assembled with the optimized S-doped carbon sheets and highly porous carbon sheets exhibited excellent energy/power characteristics and cycling stability.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Pedram Ghorbanzade, Arianna Pesce, Kerman Gomez, Grazia Accardo, Shanmukaraj Devaraj, Pedro Lopez-Aranguren, Juan Miguel Lopez del Amo
Summary: In this study, the chemical evolution and phase transitions of LLZO during heat treatment were investigated using solid state NMR, Raman, and XRD diffraction techniques. The results showed that the activation energy for Li jumps decreased after heat treatment, indicating improved Li dynamics. Furthermore, the pretreatment of powders was found to be an effective method for obtaining garnet-rich composite electrolytes with better flexibility and garnet-polymer interphases, enhancing the prospects of this material for processing.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Julen Castillo, Alexander Santiago, Xabier Judez, Jose Antonio Coca-Clemente, Amaia Saenz de Buruaga, Juan Luis Gomez-Urbano, Jose Antonio Gonzalez-Marcos, Michel Armand, Chunmei Li, Daniel Carriazo
Summary: The increasing demand for electrical energy storage has led to the exploration of alternative battery chemistries. Lithium-sulfur batteries (LSBs) have attracted attention due to their low cost and high theoretical capacity. However, there are inherent limitations that need to be addressed for commercialization. This study demonstrates the use of functional carbonaceous additives for sulfur cathode development, resulting in high-performing LSBs with improved electrochemical properties.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Electrochemistry
Ines Escher, Annica I. I. Freytag, Juan Miguel Lopez del Amo, Philipp Adelhelm
Summary: The possibility of co-intercalating sodium ions and glymes in graphite for use in sodium-ion batteries as negative electrode material needs further clarification regarding the storage mechanism and local interactions. Experiments using solid-state NMR provide insights into the storage mechanism depending on the state of charge and electrolyte solvent used, as well as information on sodium ion transport in the graphitic lattice. The inferior cycling performance of triglyme compared to diglyme and pentaglyme is reflected in the ss-NMR spectra, showing reduced mobility and stronger interactions between sodium ions, triglyme, and graphite.
BATTERIES & SUPERCAPS
(2023)
Article
Chemistry, Physical
Nahom Enkubahri Asres, Naiara Etxebarria, Iciar Monterrubio, Damien Saurel, Christian Fink Elkjaer, Montse Casas-Cabanas, Marine Reynaud, Marcus Fehse, Juan Miguel Lopez del Amo
Summary: In this study, Li-6, Li-7 solid state nuclear magnetic resonance (ssNMR) is used to characterize local disorder in LiNi0.5Mn1.5O4 spinel cathodes and understand their implications for the phase transformation mechanism during electrochemical cycling. The study demonstrates the high sensitivity of ssNMR in detecting transition metal order and disorder induced by stoichiometric variations. It also investigates the lithiation reaction mechanism of non-stoichiometric LNMO spinel cathode using Li-7 NMR and suggests that stoichiometrically induced transition metal disorder promotes a mixed solid solution and biphasic reaction mechanism.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Pierre L. Stigliano, Nagore Ortiz-Vitoriano, Lidia Medinilla, Jason E. Bara, Juan Miguel Lopez del Amo, Luis Lezama, Maria Forsyth, David Mecerreyes, Cristina Pozo-Gonzalo
Summary: This study investigates the use of a branched ether solvent, 1,2,3-trimethoxypropane (TMP), as an alternative electrolyte for sodium-air batteries (SABs). The addition of a co-solvent, N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyr][TFSI]), effectively limits the reactivity of TMP with sodium metal. The new cell design with a Na-beta-alumina disk for anode protection improves cell performance and achieves high discharge capacities. The findings highlight the potential of TMP as a base solvent and the importance of careful electrolyte composition design for greener and less toxic batteries.
FARADAY DISCUSSIONS
(2023)
Article
Chemistry, Physical
Brigette Althea Fortuin, Jon Otegi, Juan Miguel Lopez del Amo, Sergio Rodriguez Pena, Leire Meabe, Hegoi Manzano, Maria Martinez-Ibanez, Javier Carrasco
Summary: Model validation is used to predict the ionic structure and dynamics of alternative alkali metal ions in solid polymer electrolytes. A comprehensive study based on molecular dynamics is conducted to understand the ion coordination and transport properties. This approach can be extended to predict the performance of different alkali metal-based solid polymer electrolytes.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Physical
Jie Sheng, Jingshan He, Dun Ma, Yuanbo Wang, Wu Shao, Tian Ding, Ronghao Cen, Jingwen He, Zhihao Deng, Wenjun Wu
Summary: This study presents an innovative approach to improve the photovoltaic conversion characteristics and stability of perovskite solar cells through carbon electrode interface modification. By in-situ polymerization and carbonization on the surface of nano-graphite, a dendritic structure carbon electrode is formed, reducing the work function and aligning the energy levels with perovskite. This leads to improved charge and hole collection efficiency, resulting in increased photovoltaic conversion efficiency. Furthermore, the modified carbon electrode-based perovskite solar cells exhibit exceptional stability, maintaining high efficiency even without encapsulation.
Article
Chemistry, Physical
Guodong Shi, Jian Song, Xiaoxiao Tian, Tongtong Liu, Zhanjun Wu
Summary: This study demonstrates the improvement of mechanical properties and reduction of coefficient of thermal expansion (CTE) in graphene oxide (GO)/epoxy (EP) nanocomposites by enhancing the interface between GO and EP through functionalization and incorporating rigid-flexible interphases. The results reveal that the SiO2-PEA-GO hybrid exhibits better strengthening and toughening effects, as well as lower CTE, compared to the PEA-GO hybrid due to the presence of rigid-flexible interfaces with higher bonding strength and better energy dissipation mechanisms. Additionally, the nanocomposites with longer polyetheramine (PEA) molecules in the rigid-flexible interphases demonstrate higher strength and toughness, while maintaining a lower CTE. This work provides a promising strategy for constructing adjustable flexible-rigid interfacial structures and offers potential in developing GO/EP nanocomposites with high mechanical properties and low CTE.
Article
Chemistry, Physical
Rafal Janus, Sebastian Jarczewski, Jacek Jagiello, Piotr Natkanski, Mariusz Wadrzyk, Marek Lewandowski, Marek Michalik, Piotr Kustrowski
Summary: In this study, a facile procedure for the synthesis of CMK-1 and CMK-2 carbon replicas was developed. The method utilizes basic laboratory equipment and a renewable carbon source, and operates under mild conditions. The resulting carbon mesostructures exhibit exquisite replication fidelity and structural homogeneity, making them suitable for applications in various fields.
Article
Chemistry, Physical
Anqi Wang, Connor J. MacRobbie, Alex Baranovsky, Jean-Pierre Hickey, John Z. Wen
Summary: In this study, a novel polymer-free nanothermite aerogel with a wide range of nanoparticle loading was fabricated via a new additive manufacturing process. The SEM images showed a unique porous structure formed by extra thin rGO sheets, wrapping individual nanothermite clusters. The DSC-TGA results and high-speed combustion videos confirmed the enhanced energetic performance of the printed specimen.
Article
Chemistry, Physical
Wanze Wu, Misheng Zhao, Shiwei Miao, Xiaoyan Li, Yongzhong Wu, Xiao Gong, Hangxiang Wang
Summary: Superhydrophobic solar-driven interfacial evaporator is an energy-efficient technology for seawater desalination, which is easily fabricated using robust photothermal superhydrophobic coating and substrate. The created bifunctional coating on the melamine sponge substrate shows stable and highly efficient photothermal and superhydrophobic performance for seawater desalination. This superhydrophobic solar-driven interfacial evaporator is expected to have wide applications in seawater desalination.
Article
Chemistry, Physical
Zichen Xiang, Zhi Song, Tiansheng Wang, Menghang Feng, Yijing Zhao, Qitu Zhang, Yi Hou, Lixi Wang
Summary: This study presents a co-electrospinning synthesis strategy to fabricate lightweight and porous Co@C composite nanofibres with wideband microwave attenuation capacity. The addition of MOF-derived Co additives enhances the low-frequency absorption performance.
Article
Chemistry, Physical
J. Snow, C. Olson, E. Torres, K. Shirley, E. Cazalas
Summary: This study investigates the use of a perovskite-based graphene field effect transistor (P-GFET) device for X-ray detection. The sensitivity and responsivity of the device were found to be influenced by factors such as X-ray tube voltage, current, and source-drain voltage. Simulation experiments were conducted to determine the dose rate and energy incident on the device during irradiation.
Article
Chemistry, Physical
Zuzana Jankovska, Lenka Matejova, Jonas Tokarsky, Pavlina Peikertova, Milan Dopita, Karolina Gorzolkova, Dominika Habermannova, Michal Vastyl, Jakub Belik
Summary: This study provides new insights into microwave-assisted pyrolysis of scrap tyres, demonstrating that it can produce microporous carbon black with potential application in xylene adsorption. Compared to conventional pyrolysis, microwave pyrolysis requires less time and energy while maintaining similar adsorption capacity.
Article
Chemistry, Physical
Max Bommert, Bruno Schuler, Carlo A. Pignedoli, Roland Widmer, Oliver Groning
Summary: A detailed understanding of the interaction between molecules and two-dimensional materials is crucial for incorporating functional molecular films into next-generation 2D material-organic hybrid devices. This study compares the energy level alignment of different-sized fullerenes on a Moire superstructure and finds that C-84 fullerenes can be either neutral or negatively charged depending on slight variations of the electrostatic potential. This discovery suggests a new path to achieve ambipolar charge transfer without overcoming the electronic gap of fullerenes.
Article
Chemistry, Physical
Yuanjing Cheng, Xianxian Sun, Ye Yuan, Shuang Yang, Yuanhao Ning, Dan Wang, Weilong Yin, Yibin Li
Summary: The dual-structure aerogel (GS) consisting of flexible silica fibers and graphene honeycomb structures exhibits excellent resilience, flexibility, and reliability. It also shows remarkable wave absorbing performance, making it an ideal candidate for microwave absorption applications such as flexible electronics and aerospace.
Article
Chemistry, Physical
Shuyu Fan, Yinong Chen, Shu Xiao, Kejun Shi, Xinyu Meng, Songsheng Lin, Fenghua Su, Yifan Su, Paul K. Chu
Summary: Graphene coatings are promising solid lubrication materials due to their mechanical properties. This study presents a new method for in situ deposition of high-quality graphene coatings on hard substrates using NiCo solid solution and competitive reaction strategies. The graphene coating deposited on substrates with deep NiCo solid solution demonstrates superior low-friction and durability.
Article
Chemistry, Physical
Mengdi Wang, Sanyin Qu, Yanling Chen, Qin Yao, Lidong Chen
Summary: The improved thermoelectric properties of conducting polymers are achieved by selectively capturing single-walled carbon nanotubes (SWNTs) in a conducting polymer film, leading to increased carrier mobility and reduced thermal conductivity. The resulting composite film exhibits significantly higher electrical conductivity and lower thermal conductivity compared to films with a mixture of SWNTs. This work provides a convenient and efficient method to enhance the thermoelectric properties of conducting polymers.
Review
Chemistry, Physical
Heng Wei, Weihua Li, Kareem Bachagha
Summary: This article reviews the research progress of carbon nanotube-based microwave absorbing materials (MAMs) in recent years, covering the fundamental theory, design strategies, synthesis methods, and future development directions.
Article
Chemistry, Physical
Chenguang Shi, Junlong Huang, Zongheng Cen, Tan Yi, Shaohong Liu, Ruowen Fu
Summary: This study developed a high-performance Li metal host material, which achieved dendrite-free Li deposition with a low nucleation overpotential and high Coulombic efficiencies through the combination of Ti3C2-g-PV4P sheets and Ag nanoparticles. The full cells assembled with the Li@host anode and LiFePO4 cathode exhibited high discharge capacity and excellent cycling stability, demonstrating a perspective design for future energy storage devices.
Article
Chemistry, Physical
Tomotaro Mae, Kentaro Kaneko, Hiroki Sakurai, Suguru Noda
Summary: A new partial prelithiation method for SiO/C-CNT electrodes was developed, which showed reduced irreversible capacity and achieved high energy densities with good reversibility. The method allows for precise control of the degree of prelithiation and is applicable to various chemistries.