期刊
APPLIED SURFACE SCIENCE
卷 434, 期 -, 页码 871-878出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2017.10.049
关键词
NiWP free-standing film; Oxygen evolution reaction; Template method; Electrocatalytic properties
类别
资金
- National Natural Science Foundation of China [51402211]
- Natural Science Foundation of Tianjin [15JCQNJC03600]
High-efficient catalysts for oxygen evolution reaction (OER) is of great concern in improving energy efficiency for water splitting. Here we report a high-performance OER electrocatalyst of nickel-tungsten-phosphorus (NiWP) film prepared by template method. This free-standing ternary electrocatalyst exhibits a remarkable electrocatalytic activity of OER in alkaline medium due to the synergetic effect among these elements and the good electrical conductivity. The reported NiWP composite catalyst has an overpotential of as low as 0.4 V (vs. RHE) at 30 mA cm(-2), better than that of the commercial RuO2 catalyst. Moreover, a small charge transfer resistance of 4.06 Omega and a Tafel slope of 68 mV dec(-1) demonstrate the outstanding catalytic activity. (C) 2017 Published by Elsevier B.V.
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