期刊
APPLIED SURFACE SCIENCE
卷 434, 期 -, 页码 1137-1143出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2017.11.074
关键词
Topotactic structure conversion; Ion-exchange; Catalytic degradation; 4-Nitrophenol; Methylene blue
类别
资金
- National Natural Science Foundation of China [51502089, 51772010]
- Fundamental Research Funds for the Central Universities [2016MS03]
Metal nanoparticles such as Ag, Cu and Fe are effective catalysts for many reactions, whereas a facile method to prepare metal nanoparticles with high uniformed dispersion is still desirable. Herein, the topotactic structure conversion of layered silicate, RUB-15, was utilized to support metal nanoparticles. Through simple ion-exchange and following calcination step, metal nanoparticles were generated in situ inside the interlayer space of layered silica, and the topotactic structure conversion process assured nano-sized and highly uniformed dispersion of metal nanoparticles. The obtained Ag/SiO2 composite showed superior catalytic activity for the reduction of 4-nitrophenol (4-NP) and methylene blue (MB), with a rate constant as high as 0.0607 s(-1) and 0.0778 s(-1). The simple and universal synthesis method as well as high activity of the product composite endow the strategy good application prospect. (C) 2017 Elsevier B.V. All rights reserved.
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