期刊
APPLIED SURFACE SCIENCE
卷 456, 期 -, 页码 403-409出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2018.06.090
关键词
CuO-ZnO-ZrO2 catalyst; CO2 hydrogenation; Methanol synthesis; Tungsten oxide
类别
资金
- Shanghai Municipal Education Commission [13YZ117]
- Science and Technology Commission of Shanghai Municipality [13ZR1441200]
A series of WO3 modified CuO-ZnO-ZrO2 mixed oxides with different WO3 contents (0-20 at.%) were prepared by co-precipitation method and used as catalyst for methanol synthesis from CO2 hydrogenation. The effects of WO3 content on the physicochemical and catalytic properties of the CuO-ZnO-ZrO2-WO3 catalysts were investigated by X-ray diffraction, X-ray photoelectron spectra, temperature-programed reduction of hydrogen, temperature-programed desorption of CO2, N-2 adsorption and desorption, reactive N2O adsorption, and activity testing. The results indicated that both CO2 conversion and methanol selectivity of the CuO-ZnO-ZrO2 catalyst was enhanced by the addition of small amounts (2 and 5 at.%) of WO3. However, the activity was significantly decreased by the addition of excessive WO 3 (20 at.%). The activity was closely related to the specific surface area of metallic Cu (S-cu), amount of weak basic sites, and reducibility of the catalyst.
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