期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 14, 页码 3747-3751出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201709445
关键词
aryl ethers; hydrogenation; methanolysis; palladium; selective bond cleavage
资金
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences
- DOE [DE-AC05-76RL01830]
Palladium on carbon catalyzes C-O bond cleavage of aryl ethers (diphenyl ether and cyclohexyl phenyl ether) by alcohols (R-OH) in H-2. The aromatic C-O bond is cleaved by reductive solvolysis, which is initiated by Pd-catalyzed partial hydrogenation of one phenyl ring to form an enol ether. The enol ether reacts rapidly with alcohols to form a ketal, which generates 1-cyclohexenyl-O-R by eliminating phenol or an alkanol. Subsequent hydrogenation leads to cyclohexyl-O-R.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据