期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 35, 页码 11339-11343出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201806480
关键词
ball milling; mechanochemistry; organometallic; organozinc; solventless reactions
资金
- EPSRC [EP/P002951/1]
- CRD
- EPSRC U.K. National Mass Spectrometry Facility at Swansea University
- School of Chemistry at Cardiff University
A form independent activation of zinc, concomitant generation of organozinc species and engagement in a Negishi cross-coupling reaction via mechanochemical methods is reported. The reported method exhibits a broad substrate scope for both C(sp(3))-C(sp(2)) and C(sp(2))-C(sp(2)) couplings and is tolerant to many important functional groups. The method may offer broad reaching opportunities for the insitu generation organometallic compounds from base metals and their concomitant engagement in synthetic reactions via mechanochemical methods.
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