Catalytic and Atom-Economic Csp3 −Csp3 Bond Formation: Alkyl Tantalum Ureates for Hydroaminoalkylation

Scandium-catalyzed C(sp3)–H alkylation of N,N-dimethyl anilines with alkenes

(2018) Hongjie Gao et al.   Organic Chemistry Frontiers

Bis(tert-butylimido)bis(N,O-chelate)tungsten(VI) Complexes: Probing Amidate and Pyridonate Hemilability

(2017) Joseph M. Clarkson et al.   INORGANIC CHEMISTRY

A Mild Hydroaminoalkylation of Conjugated Dienes Using a Unified Cobalt and Photoredox Catalytic System

(2017) Scott M. Thullen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective sp3 C–H alkylation via polarity-match-based cross-coupling

(2017) Chip Le et al.   NATURE

In Situ Generation of a Regio- and Diastereoselective Hydroaminoalkylation Catalyst Using Commercially Available Starting Materials

(2017) Peter M. Edwards et al.   ORGANIC LETTERS

Mechanistic Insights into Scandium-Catalyzed Hydroaminoalkylation of Olefins with Amines: Origin of Regioselectivity and Charge-Based Prediction Model

(2017) Fan Liu et al.   ORGANOMETALLICS

Amidate Complexes of Tantalum and Niobium for the Hydroaminoalkylation of Unactivated Alkenes

(2017) Jean Michel Lauzon et al.   ACS Catalysis

Ligand Effects and Kinetic Investigations of Sterically Accessible 2-Pyridonate Tantalum Complexes for Hydroaminoalkylation

(2017) Jason W. Brandt et al.   ACS Catalysis

Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts

(2016) Jérémie D. A. Pelletier et al.   ACCOUNTS OF CHEMICAL RESEARCH

One-Pot Procedure for the Synthesis of 1,5-Benzodiazepines fromN-Allyl-2-bromoanilines

(2016) Marco Weers et al.   CHEMISTRY-A EUROPEAN JOURNAL

Solid-State NMR and DFT Studies on the Formation of Well-Defined Silica-Supported Tantallaaziridines: From Synthesis to Catalytic Application

(2016) Bilel Hamzaoui et al.   CHEMISTRY-A EUROPEAN JOURNAL

Scandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines

(2016) Adi E. Nako et al.   Chemical Science

Diene hydroaminomethylation via ruthenium-catalyzed C–C bond forming transfer hydrogenation: beyond carbonylation

(2016) Susumu Oda et al.   Chemical Science

Ruthenium-Catalyzed Transfer Hydrogenation for C–C Bond Formation: Hydrohydroxyalkylation and Hydroaminoalkylation via Reactant Redox Pairs

(2016) Felix Perez et al.   Topics in Current Chemistry

N,O-Chelating Four-Membered Metallacyclic Titanium(IV) Complexes for Atom-Economic Catalytic Reactions

(2015) Scott A. Ryken et al.   ACCOUNTS OF CHEMICAL RESEARCH

An Aminopyridinato Titanium Catalyst for the Intramolecular Hydroaminoalkylation of Secondary Aminoalkenes

(2015) Jaika Dörfler et al.   ADVANCED SYNTHESIS & CATALYSIS

Isolation and Characterization of Well-Defined Silica-Supported Azametallacyclopentane: A Key Intermediate in Catalytic Hydroaminoalkylation Reactions

(2015) Bilel Hamzaoui et al.   ADVANCED SYNTHESIS & CATALYSIS

Efficient Access to Titanaaziridines by CH Activation ofN-Methylanilines at Ambient Temperature

(2015) Manfred Manßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular hydroaminoalkylation of alkenes and dienes using a titanium mono(formamidinate) catalyst

(2015) Jaika Dörfler et al.   DALTON TRANSACTIONS

A NewN-Trityl-Substituted Aminopyridinato Titanium Catalyst for Hydroamination and Hydroaminoalkylation Reactions - Unexpected Intramolecular C-H Bond Activation

(2015) Lars H. Lühning et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

A 2,6-Bis(phenylamino)pyridinato Titanium Catalyst for the Highly Regioselective Hydroaminoalkylation of Styrenes and 1,3-Butadienes

(2014) Jaika Dörfler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Commercially Available Tantalum Catalyst for the Highly Regioselective Intermolecular Hydroaminoalkylation of Styrenes

(2014) Jaika Dörfler et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

2-Pyridonate Tantalum Complexes for the Intermolecular Hydroaminoalkylation of Sterically Demanding Alkenes

(2014) Eugene Chong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroaminoalkylation: Early-Transition-Metal-Catalyzed α-Alkylation of Amines

(2014) Laurel Schafer et al.   SYNTHESIS-STUTTGART

Tethered Bis(amidate) and Bis(ureate) Supported Zirconium Precatalysts for the Intramolecular Hydroamination of Aminoalkenes

(2014) Jean Michel P. Lauzon et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Phosphoramidate Tantalum Complexes for Room-Temperature CH Functionalization: Hydroaminoalkylation Catalysis

(2013) Pierre Garcia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Titanium-Catalyzed Intermolecular Hydroaminoalkylation of Conjugated Dienes

(2013) Till Preuß et al.   CHEMISTRY-A EUROPEAN JOURNAL

TaMe3Cl2-Catalyzed Intermolecular Hydroaminoalkylation: A Simple Complex for Enhanced Reactivity and Expanded Substrate Scope

(2013) Zhengxing Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tantalum Catalyzed Hydroaminoalkylation for the Synthesis of α- and β-Substituted N-Heterocycles

(2013) Philippa R. Payne et al.   ORGANIC LETTERS

2-Pyridonate Titanium Complexes for Chemoselectivity. Accessing Intramolecular Hydroaminoalkylation over Hydroamination

(2013) Eugene Chong et al.   ORGANIC LETTERS

Easily assembled, modular N,O-chelating ligands for Ta(V) complexation: a comparative study of ligand effects in hydroaminoalkylation with N-methylaniline and 4-methoxy-N-methylaniline

(2013) Pierre Garcia et al.   TETRAHEDRON

Aminopyridinato Titanium Catalysts for the Hydroaminoalkylation of Alkenes and Styrenes

(2012) Jaika Dörfler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zirconium catalyzed alkyne dimerization for selective Z-enyne synthesis

(2012) Rachel H. Platel et al.   CHEMICAL COMMUNICATIONS

The Mechanism of Hydroaminoalkylation Catalyzed by Group 5 Metal Binaphtholate Complexes

(2012) Alexander L. Reznichenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinuclear Titanium Complexes with Sulfamide Ligands as Precatalysts for Hydroaminoalkylation and Hydroamination Reactions

(2012) Sven Doye et al.   SYNLETT

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Mechanism of the Titanium-Catalyzed Hydroaminoalkylation of Alkenes

(2011) Insa Prochnow et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric hydroamination catalyzed by in situ generated chiral amidate and ureate complexes of zirconium — Probing the role of the tether in ligand design

(2011) Philippa R. Payne et al.   CANADIAN JOURNAL OF CHEMISTRY

Synthesis and catalytic activity of group 5 metal amides with chiral biaryldiamine-based ligands

(2011) Furen Zhang et al.   DALTON TRANSACTIONS

Mechanistic Elucidation of Intramolecular Aminoalkene Hydroamination Catalyzed by a Tethered Bis(ureate) Complex: Evidence for Proton-Assisted C–N Bond Formation at Zirconium

(2011) David C. Leitch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Group 5 Metal Binaphtholate Complexes for Catalytic Asymmetric Hydroaminoalkylation and Hydroamination/Cyclization

(2011) Alexander L. Reznichenko et al.   ORGANOMETALLICS

Isolation of Catalytic Intermediates in Hydroamination Reactions: Insertion of Internal Alkynes into a Zirconium-Amido Bond

(2010) David C. Leitch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Ind2TiMe2]: A Catalyst for the Hydroaminomethylation of Alkenes and Styrenes

(2010) Raphael Kubiak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly enantioselective hydroaminoalkylation of secondary amines catalyzed by group 5 metal amides with chiral biarylamidate ligands

(2010) Guofu Zi et al.   CHEMICAL COMMUNICATIONS

Metal-catalyzed direct alkylations of (hetero)arenes via C–H bond cleavages with unactivated alkyl halides

(2010) Lutz Ackermann   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions

(2010) Patrick Eisenberger et al.   PURE AND APPLIED CHEMISTRY

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tantalum-Amidate Complexes for the Hydroaminoalkylation of Secondary Amines: Enhanced Substrate Scope and Enantioselective Chiral Amine Synthesis

(2009) Patrick Eisenberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Titanium-Catalyzed Hydroaminoalkylation of Alkenes by CH Bond Activation at sp3Centers in the α-Position to a Nitrogen Atom

(2009) Raphael Kubiak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Hydroaminoalkylation

(2009) Peter W. Roesky   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tetrabenzyltitanium: An Improved Catalyst for the Activation of sp3CH Bonds Adjacent to Nitrogen Atoms

(2009) Insa Prochnow et al.   ChemCatChem

Broadening the Scope of Group 4 Hydroamination Catalysis Using a Tethered Ureate Ligand

(2009) David C. Leitch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective C−H Activation α to Primary Amines. Bridging Metallaaziridines for Catalytic, Intramolecular α-Alkylation

(2009) Jason A. Bexrud et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Neutral Group-IV Metal Catalysts for the Intramolecular Hydroamination of Alkenes

(2008) Carsten Müller et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Hydroaminoalkylation of Unactivated Olefins with Dialkylamines

(2008) Seth B. Herzon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY