期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 27, 页码 8230-8234出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201805348
关键词
arsenic; cyanates; fundamental ions; main-group chemistry; phosphorus
资金
- EPSRC [EP/M027732/1]
- DFG [TA 1357/1-1]
- EPSRC [EP/M027732/1] Funding Source: UKRI
A general synthetic protocol for the synthesis of phosphorus- and arsenic-containing analogues of the thio- and seleno-cyanate anions is reported. This procedure allows for the isolation of three unprecedented species: the phosphaethynselenolate, PCSe- (1), the arsaethynthiolate, AsCS- (2), and the arsaethynselenolate, AsCSe- (3), anions. The structures, electronic properties, and spectroscopic signatures of these species are reported.
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