期刊
ANALYTICAL METHODS
卷 10, 期 20, 页码 2360-2367出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ay00328a
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资金
- University Grants Commission (UGC), Delhi
- Department of Science and Technology, Delhi
Fluorescent nanoparticles of sodium dodecyl sulphate stabilized 2-naphthol (SDS-2-NNPs) were prepared using a reprecipitation method, and exhibited aggregation-induced enhanced emission (AIEE) at 410nm. A novel spectrofluorimetric method for the quantitative determination of crystal violet based on the fluorescence quenching of SDS-2-NNPs in aqueous solution was proposed. The FL (fluorescence) intensity of SDS-2-NNPs, monitored at an excitation wavelength of 297 nm, was quenched by the successive addition of increasing amounts of crystal violet solution. The quenching results were found to fit the Stern-Volmer relationship in the range of 0.1-40 g L-1, with a correlation coefficient of 0.9990. The limit of detection was found to be 0.38 ng L-1. The proposed sensing method based on FL quenching can be successfully applied for the quantitative analysis of crystal violet, over competitive ions, in water samples collected from different environments.
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