Article
Chemistry, Physical
Xianshuang Xia, Guantong Wei, Lian Wu, Yeyuan Du, Xu Tang, Jinyun Ju, Haichen Wu, Renjie Chen, Wenzong Yin, Aru Yan
Summary: To improve the utilization of heavy rare-earth resources in Nd-Fe-B magnets, a dual alloy process was used to implement intergranular diffusion of DyF3 aided by nano-Cu. The addition of 0.2 wt% nano-Cu resulted in higher coercivity increment and maintained high remanence compared to Cu-free magnets. The presence of nano-Cu facilitated the dissolution and infiltration of bulky Dy-rich phase into adjacent powder flakes. The higher Dy concentrations in the main phase and grain boundary phase of Cu-containing magnets contributed to the enhancement of coercivity.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Review
Materials Science, Multidisciplinary
Keiko Hioki
Summary: This study focused on the magnetic properties of hot-deformed anisotropic Nd-Fe-B magnets, improving the hot-deformation technique and optimizing microstructure to fabricate high-performance magnets.
SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Tingting Song, Xin Li, Xu Tang, Wenzong Yin, Yang Luo, Dunbo Yu, Wenlong Yan, Jinyun Ju, Renjie Chen, Aru Yan
Summary: Nb element was introduced to regulate the microstructure of melt-spun powder and die-upset magnets, effectively restricting grain growth in coarse grain regions. The addition of Nb significantly improved the magnetic properties and thermal stability of the magnets, forming an anisotropic magnet.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Xianshuang Xia, Xu Tang, Yeyuan Du, Haichen Wu, Jinyun Ju, Lian Wu, Renjie Chen, Wenzong Yin, Lanting Zhang, Aru Yan
Summary: High coercivities and excellent thermal stability were achieved in hot-deformed Nd-Fe-B magnets through intergranular addition of alloy powders, with a low consumption of rare-earth elements.
Article
Materials Science, Multidisciplinary
Hongxing Chen, Renquan Wang, Jun Li, Ying Liu
Summary: The evolution of Nd-rich phases in hot-deformed (HDed) Nd-Fe-B magnets with different height reductions was systematically studied. It was found that disorderly oriented platelet-like grains were generated in the magnets without any deformation, and the grain boundaries and triple junction regions provided storage space for Nd-rich phases. With height reduction, platelet-like grains grew and were arranged regularly, resulting in a decrease in the storage space and the formation of blocky Nd-rich phases under pressure.
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Yuyang Tang, Yuqing Li, Xiaochang Xu, Ming Yue, Weiqiang Liu, Hongguo Zhang, Qingmei Lu, Weixing Xia
Summary: This paper systematically studied the microstructure, micromagnetic structure, texture, and magnetic properties of hot-deformed Nd-Fe-B magnets to understand the formation mechanism of c-axis texture. The results revealed the formation and arrangement of platelet grains during deformation, as well as the diffusion of rare earth phase and grain growth in different grain regions. The deformation mechanism and formation of c-axis texture were deduced to be accomplished by dissolution-precipitation diffusion, grain rotation, and grain arrangement processes.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Materials Science, Multidisciplinary
Tieqiao Zhang, Wandong Xing, Fugang Chen, Lanting Zhang, Rong Yu
Summary: A new processing route involving Tb-Cu doping and Nd-Cu diffusion was used to produce hot-deformed Nd-Fe-B magnets with high coercivity and thermal stability. The core-shell structure with Tb-rich shell and Fe-rich amorphous intergranular phase played a crucial role in enhancing the magnetic properties of the magnets.
Article
Materials Science, Multidisciplinary
Xin Tang, H. Sepehri-Amin, A. Bolyachkin, T. Ohkubo, K. Hono
Summary: This study explores the potential of low-cost (Nd,La,Ce)-Fe-B hot deformed magnets for the application in variable-magnetic-force (VMF) motors. The results show that the hot-deformed magnets have the ability to adjust the coercivity and exhibit flat reversal curves. The microstructure observation and magneto-optical Kerr effect microscopy reveal the origin of the flat reversal curves. Additionally, the hot-deformed magnets have a relatively high remanent magnetization compared to sintered magnets, making them excellent candidates for VMF motor applications.
Article
Materials Science, Multidisciplinary
Jun-Ming Wang, Zhao-Hui Guo, Zheng Jing, Xiao Du, Neng-Jun Yu, Meng-Yu Li, Ming-Gang Zhu, Wei Li
Summary: The effects of low-melting Pr-Cu alloy addition on the microstructure and magnetic properties of hot-deformation Nd-Fe-B magnets were investigated. A small amount of Pr-Cu addition significantly enhances the coercivity of the magnets. The presence of a uniform RE-rich phase wrapping the Nd2Fe14B main phase promotes the coercivity. The remanence, intrinsic coercivity, and maximum magnetic energy product of the magnets increase with Pr-Cu addition.
Article
Materials Science, Multidisciplinary
Renquan Wang, Qiaosen Yang, Ying Liu, Jun Li, Tingchuan Zhou, Xiaojiao Yang
Summary: The addition of SLG as an additive in hot-deformed Nd-Fe-B magnets forms a new bi-morphologically anisotropic microstructure, enhancing the magnetic properties of the magnet, particularly the coercivity. SLG acts on interfaces by inhibiting grain growth and eliminating the width of coarse grain regions, leading to improved magnetic properties of the magnet.
MATERIALS CHARACTERIZATION
(2021)
Article
Chemistry, Physical
Xianshuang Xia, Tieqiao Zhang, Mei Liu, Lanting Zhang, Renjie Chen, Xu Tang, Jinyun Ju, Wenzong Yin, Aru Yan
Summary: In this study, new efforts were made to recover the remanence and maximum energy product in diffusion-processed hot-deformed Nd-Fe-B magnets. Through annealing at 800 degrees C under pressure, improvements were seen in c-axis misalignment of grains, distribution of powder boundary phase, and squareness factor of the demagnetization curve. The enhanced squareness factor was attributed to the homogeneous magnetization reversal process caused by the uniform microstructure.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Tieqiao Zhang, Shengsheng Liu, Zhongwei Wu, Lanting Zhang, Rong Yu
Summary: In this study, a high-temperature short-term annealing process was used to simultaneously improve the coercivity, remanence, and squareness factor of hot-deformed Nd-Fe-B magnets. The increase in coercivity was attributed to the melting and infiltration of the Nd-6(Fe,Co)(13)Ga phase. The slightly anisotropic growth of Nd2Fe14B grains resulted in improved grain alignment and enhanced remanence. The addition of a small amount of Co element significantly reduced the melting point of the Nd6Fe13Ga phase. A balance between infiltration within the powder flakes and grain growth was achieved, leading to the simultaneous improvement of coercivity, remanence, and squareness factor in hot-deformed Nd-Fe-B samples.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Applied
Longquan Hou, Jinyun Ju, Xu Tang, Renjie Chen, Wenzong Yin, Aru Yan, Bin Chen, Yeyuan Du
Summary: The coercivity of hot-deformed Nd-Fe-B magnets can be effectively increased by adjusting the sandwiched structure and adding Nd-Cu eutectic alloys, while reducing remanence loss. In addition, the infiltrated Nd-Cu eutectic plays a critical role in inhibiting grain growth and intergranular magnetic interaction in the optimized microstructure, contributing positively to coercivity.
JOURNAL OF RARE EARTHS
(2021)
Article
Chemistry, Applied
Jiayi He, Yukun Liu, Zhigao Yu, Jiali Cao, Hongya Yu, Zhongwu Liu
Summary: Grain boundary diffusion (GBD) is an important method for producing Nd-Fe-B magnets with high coercivity and thermal stability. This study investigated the effects of different GBD methods on the magnetic properties and microstructure of hot deformed magnets. The coercivity of the hot-deformed magnet increased after treatment by the three GBD approaches. The conventional GBD exhibited a higher utilization efficiency of Tb compared to in-situ GBD.
JOURNAL OF RARE EARTHS
(2023)
Article
Materials Science, Multidisciplinary
Xin Tang, J. Li, H. Sepehri-Amin, T. Ohkubo, K. Hioki, A. Hattori, K. Hono
Summary: A novel method was introduced to improve the squareness and coercivity of bulk hot-deformed Nd-Fe-B magnets through two step diffusion, resulting in a more uniform HRE shell. Magneto-optical Kerr effect microscopy showed strong pinning of magnetic domain wall motion at side grain boundaries in the two-step diffusion processed magnet.
Article
Chemistry, Physical
Zexuan Wang, Jinyun Ju, Jinzhi Wang, Wenzong Yin, Renjie Chen, Ming Li, Jie Sun, Chaoxiang Jin, Xu Tang, Don Lee, Aru Yan
JOURNAL OF ALLOYS AND COMPOUNDS
(2017)
Article
Materials Science, Multidisciplinary
Chaoxiang Jin, Renjie Chen, Xu Tang, Jinyun Ju, Wenzong Yin, Zexuan Wang, Ming Li, Don Lee, Aru Yan
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2018)
Article
Chemistry, Physical
Qiaobo Liu, Xu Tang, Renjie Chen, Zexuan Wang, Jinyun Ju, Wenzong Yin, Aru Yan, Hui Xu
JOURNAL OF ALLOYS AND COMPOUNDS
(2019)
Article
Materials Science, Multidisciplinary
Zexuan Wang, Ke Pei, Jijun Zhang, Renjie Chen, Weixing Xia, Jinzhi Wang, Ming Li, Aru Yan
Article
Materials Science, Multidisciplinary
Tingting Song, Haihang Wang, Xu Tang, Wenzong Yin, Zexuan Wang, Jinyun Ju, Renjie Chen, Aru Yan
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2019)
Article
Materials Science, Multidisciplinary
Yang Tang, Renjie Chen, Wenzong Yin, Xu Tang, Jinyun Ju, Zexuan Wang, Ying Li, Aru Yan
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
(2019)
Article
Materials Science, Multidisciplinary
Tingting Song, Xu Tang, Wenzong Yin, Jingyun Ju, Zexuan Wang, Qiaobo Liu, Yang Tang, Renjie Chen, Aru Yan
Article
Materials Science, Multidisciplinary
Y. Liu, K. Zweiacker, C. Liu, J. T. McKeown, J. M. K. Wiezorek
Summary: The evolution of rapid solidification microstructure and solidification interface velocity of hypereutectic Al-20at.%Cu alloy after laser melting has been studied experimentally. It was found that the formation of microstructure was dominated by eutectic, alpha-cell, and banded morphology grains, and the growth modes changed with increasing interface velocity.
Article
Materials Science, Multidisciplinary
Bharat Gwalani, Julian Escobar, Miao Song, Jonova Thomas, Joshua Silverstein, Andrew Chihpin Chuang, Dileep Singh, Michael P. Brady, Yukinori Yamamoto, Thomas R. Watkins, Arun Devaraj
Summary: Castable alumina forming austenitic alloys exhibit superior creep life and oxidation resistance at high temperatures. This study reveals the mechanism behind the enhanced creep performance of these alloys by suppressing primary carbide formation and offers a promising alloy design strategy for high-temperature applications.
Article
Materials Science, Multidisciplinary
Jian Song, Qi Zhang, Songsong Yao, Kunming Yang, Houyu Ma, Jiamiao Ni, Boan Zhong, Yue Liu, Jian Wang, Tongxiang Fan
Summary: Recent studies have shown that achieving an atomically flat surface for metals can greatly improve their oxidation resistance and enhance their electronic-optical applications. Researchers have explored the use of graphene as a covering layer to achieve atomically flat surfaces. They found that high-temperature deposited graphene on copper surfaces formed mono-atomic steps, while annealed copper and transferred graphene on copper interfaces formed multi-atomic steps.
Article
Materials Science, Multidisciplinary
Jennifer A. Glerum, Jon-Erik Mogonye, David C. Dunand
Summary: Elemental powders of Al, Ti, Sc, and Zr are blended and processed via laser powder-bed fusion to create binary and ternary alloys. The microstructural analysis and mechanical testing show that the addition of Ti results in the formation of primary precipitates, while the addition of Sc and Zr leads to the formation of fine grain bands. The Al-0.25Ti-0.25Zr alloy exhibits comparable strain rates to Al-0.5Zr at low stresses, but significantly higher strain rates at higher stresses during compressive creep testing. Finite element modeling suggests that the connectivity of coarse and fine grain regions is a critical factor affecting the creep resistance of the alloys.
Article
Materials Science, Multidisciplinary
P. Jannotti, B. C. Hornbuckle, J. T. Lloyd, N. Lorenzo, M. Aniska, T. L. Luckenbaugh, A. J. Roberts, A. Giri, K. A. Darling
Summary: This work characterizes the thermo-mechanical behavior of bulk nanocrystalline Cu-Ta alloys under extreme conditions. The experiments reveal that the alloys exhibit unique mechanical properties, behaving differently from conventional nanocrystalline Cu. They do not undergo grain coarsening during extrusion and exhibit behavior similar to coarse-grained Cu.
Article
Materials Science, Multidisciplinary
Yiqing Wei, Jingwei Li, Daliang Zhang, Bin Zhang, Zizhen Zhou, Guang Han, Guoyu Wang, Carmelo Prestipino, Pierric Lemoine, Emmanuel Guilmeau, Xu Lu, Xiaoyuan Zhou
Summary: This study proposes a new strategy to modify microstructure by phase regulation, which can simultaneously enhance carrier mobility and reduce lattice thermal conductivity. The addition of Cu in layered SnSe2 induces a phase transition that leads to increased grain size and reduced stacking fault density, resulting in improved carrier mobility and lower lattice thermal conductivity.
Article
Materials Science, Multidisciplinary
Jia Chen, Zhengyu Zhang, Eitan Hershkovitz, Jonathan Poplawsky, Raja Shekar Bhupal Dandu, Chang-Yu Hung, Wenbo Wang, Yi Yao, Lin Li, Hongliang Xin, Honggyu Kim, Wenjun Cai
Summary: In this study, the structural origin of the pH-dependent repassivation mechanisms in multi-principal element alloys (MPEA) was investigated using surface characterization and computational simulations. It was found that selective oxidation in acidic to neutral solutions leads to enhanced nickel enrichment on the surface, resulting in reduced repassivation capability and corrosion resistance.
Article
Materials Science, Multidisciplinary
X. Y. Xu, C. P. Huang, H. Y. Wang, Y. Z. Li, M. X. Huang
Summary: The limited slip systems of magnesium (Mg) and its alloys hinder their wide applications. By conducting tensile straining experiments, researchers discovered a rate-dependent transition in the dislocation mechanisms of Mg alloys. At high strain rates, glissile dislocations dominate, while easy-glide dislocations dominate at low strain rates. Abundant glissile dislocations do not necessarily improve ductility.
Article
Materials Science, Multidisciplinary
M. S. Szczerba, M. J. Szczerba
Summary: Inverse temperature dependences of the detwinning stress were observed in face-centered cubic deformation twins in Cu-8at.%Al alloy. The detwinning stress increased with temperature when the pi detwinning mode was involved, but decreased when the pi/3 mode was involved. The dual effect of temperature on the detwinning stress was due to the reduction of internal stresses pre-existing within the deformation twins. The complete reduction of internal stresses at about 530 degrees C led to the equivalence of the critical stresses of different detwinning modes and a decrease in the yield stress anisotropy of the twin/matrix structure.
Article
Materials Science, Multidisciplinary
Taowen Dong, Tingting Qin, Wei Zhang, Yaowen Zhang, Zhuoran Feng, Yuxiang Gao, Zhongyu Pan, Zixiang Xia, Yan Wang, Chunming Yang, Peng Wang, Weitao Zheng
Summary: The interaction between the electrode and the electric double layer (EDL) significantly influences the energy storage mechanism. By studying the popular alpha-Fe2O3 electrode and the EDL interaction, we find that the energy storage mechanism of the electrode can be controlled by modulating the EDL.
Article
Materials Science, Multidisciplinary
Matthew R. Barnett, Jun Wang, Sitarama R. Kada, Alban de Vaucorbeil, Andrew Stevenson, Marc Fivel, Peter A. Lynch
Summary: The elastic-plastic transition in magnesium alloy Mg-4.5Zn exhibits bursts of deformation, which are characterized by sudden changes in grain orientation. These bursts occur in a coordinated manner among nearby grains, with the highest burst rate observed at the onset of full plasticity. The most significant burst events are associated with twinning, supported by the observation of twinned structures using electron microscopy. The bursts are often preceded and followed by a stasis in peak movement, indicating a certain "birth size" for twins upon formation and subsequent growth at a later stage.
Article
Materials Science, Multidisciplinary
Vaidehi Menon, Sambit Das, Vikram Gavini, Liang Qi
Summary: Understanding solute segregation thermodynamics is crucial for investigating grain boundary properties. The spectral approach and thermodynamic integration methods can be used to predict solute segregation behavior at grain boundaries and compare with experimental observations, thus aiding in alloy design and performance control.
Article
Materials Science, Multidisciplinary
Feiyu Qin, Lei Hu, Yingcai Zhu, Yuki Sakai, Shogo Kawaguchi, Akihiko Machida, Tetsu Watanuki, Yue-Wen Fang, Jun Sun, Xiangdong Ding, Masaki Azuma
Summary: This study reports on the negative and zero thermal expansion properties of Cd2Re2O7 and Cd1.95Ni0.05Re2O7 materials, along with their ultra-low thermal conductivity. Through investigations of their structures and phonon calculations, the synergistic effect of local structure distortion and soft phonons is revealed as the key to achieving these distinctive properties.
Article
Materials Science, Multidisciplinary
Thomas Beerli, Christian C. Roth, Dirk Mohr
Summary: A novel testing system for miniature specimens is designed to characterize the plastic response of materials for which conventional full-size specimens cannot be extracted. The system has an automated operation process, which reduces the damage to specimens caused by manual handling and improves the stability of the test results. The experiments show that the miniature specimens extracted from stainless steel and aluminum have high reproducibility, and the results are consistent with those of conventional-sized specimens. A correction procedure is provided to consider the influence of surface roughness and heat-affected zone caused by wire EDM.
Article
Materials Science, Multidisciplinary
Rani Mary Joy, Paulius Pobedinskas, Nina Baule, Shengyuan Bai, Daen Jannis, Nicolas Gauquelin, Marie-Amandine Pinault-Thaury, Francois Jomard, Kamatchi Jothiramalingam Sankaran, Rozita Rouzbahani, Fernando Lloret, Derese Desta, Jan D'Haen, Johan Verbeeck, Michael Frank Becker, Ken Haenen
Summary: This study investigates the influence of film microstructure and composition on the Young's modulus and residual stress in nanocrystalline diamond thin films. The results provide insights into the mechanical properties and intrinsic stress sources of these films, and demonstrate the potential for producing high-quality nanocrystalline diamond films under certain conditions.