期刊
ACS NANO
卷 12, 期 7, 页码 7206-7212出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.8b03115
关键词
core-shell nanowires; perovskite nanowires; copper thiocyanate; anodic aluminum oxide; charge extraction; coaxial lithography; electrodeposition
类别
资金
- National Science Foundation's MRSEC program at the Materials Research Center of Northwestern University [DMR-1121262]
- National Science Foundation Graduate Research Fellowship Program
- Sherman Fairchild Foundation
- Vannevar Bush Faculty Fellowship program - Basic Research Office of the Assistant Secretary of Defense for Research and Engineering
- Office of Naval Research [N00014-15-1-0043]
- Air Force Research Laboratory [FA8650-15-2-5518]
Realizing nanostructured interfaces with precise architectural control enables one to access properties unattainable using bulk materials. In particular, a nanostructured interface (e.g., a core shell nanowire) between two semiconductors leads to a short charge separation distance, such that photoexcited charge carriers can be more quickly and efficiently collected. While vapor-phase growth methods are used to synthesize uniform core-shell nanowire arrays of semiconductors such as Si and InP, more general strategies are required to produce related structures composed of a broader range of materials. Herein, we employ anodic aluminum oxide templates to synthesize CH3NH3PbI3 perovskite core copper thiocyanate shell nanowire arrays employing a combination of electrodeposition and solution casting methods. Using scanning electron microscopy, powder X-ray diffraction, and time-resolved photoluminescence spectroscopy, we confirm the target structure and show that adopting a core shell nanowire architecture accelerates the rate of charge quenching by nearly 3 orders of magnitude compared to samples with only an axial junction. Subsequently, we fit decay curves to a triexponential function to attribute fast quenching in core-shell nanowires to charge extraction by the copper thiocyanate nanotubes, as opposed to recombination within the perovskite nanowires. Dramatic improvements to charge extraction speed and efficiency result from the substantially reduced charge separation distance and increased interfacial area achieved via the core shell nanowire array architecture.
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