期刊
CHEMISTRYSELECT
卷 2, 期 6, 页码 2205-2211出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201700303
关键词
Friction; Helical structure; Mechanical stimulation; Self-assembly; Two-step response
资金
- Japan Society for the Promotion of Science (JSPS) [15H00981]
- Takahashi Industrial and Economic Research Foundation
- Kao Foundation for Arts and Sciences
- Grants-in-Aid for Scientific Research [17H03050, 15H00981, 15K18825] Funding Source: KAKEN
A mixture of pseudoenantiomeric oxymethylene helicene (P)-pentamers and (M)-hexamers formed heteroaggregates and self-assembled as a result of mechanical stirring in solution at 25 degrees C. No aggregation occurred without stirring, and heteroaggregation was accelerated at high stirring rates. Repeatedly alternating between mechanical stirring and stopping respectively induced and then ceased the heteroaggregation. Sonication also promoted the heteroaggregation, which did not occur at high pressures or during centrifugation. Mechanisms based on friction due to mechanical stirring, which generated local and temporal high-temperature domains, are considered. It is shown that different methods of mechanical stimulation, namely, stirring and surface contact, induce enantiomeric heteroaggregate formation.
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