期刊
CHEMISTRYSELECT
卷 2, 期 23, 页码 6762-6766出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201701598
关键词
Aqueous-phase reaction; Catalytic transfer hydrogenation; Core-shell structure; Nitroreduction; Surface oxygen of carbon spheres
资金
- Fundamental Reaserch Funds for the Central Universitys [N160503001]
The carbon wrapped magnetic nanosphere Fe3O4@C (similar to 300 nm) was prepared under simple hydrothermal conditions, and it served as the carrier of Rh nanoparticles (2-3 nm), which acted as the highly efficient catalyst for reduction of nitro compounds, and reutilization of catalyst is convenient to achieve because the catalyst particles are magnetic. A scope of nitroarene derivatives were reduced to corresponding anilines in water, and the reactions completed in 10 min with nearly quantitative conversions and 100% selectivity. In addition, the abundant oxygen-containing functionality on the carbon shell which can strongly binds the Rh-NPs to offer extraordinary stability is investigated by using various techniques, including transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-Ray Diffraction (XRD), and Fourier transform infrared spectrometer (FT-IR).
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