期刊
ACS ENERGY LETTERS
卷 2, 期 3, 页码 556-562出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.7b00015
关键词
-
类别
资金
- Zhejiang Provincial Natural Science Foundation [LR16F040002]
- National Natural Science Foundation of China [61674154, 61404144, 61431014, 61504121]
- International S&T Cooperation Program of Ningbo [2015D10021]
- Major Project and Key S&T Program of Ningbo [2016B10004, 2014B10026]
Heterojunction solar cells (HSCs) featuring half and full contact of poly(3,4-ethylenedioxythiophene):polystyrene (PEDOT:PSS) with pyramid-textured silicon (Si) were thoroughly compared via simulations and experiments, and the following conclusions have been reached: (1) The insufficient electrical passivation inherent to the half contact results in enormous decline in short-circuit current density (J(sc)) and open-circuit voltage (V-oc). (2) For the full-contact HSCs, J(sc) is mainly dependent on the recombination at the rear interface. With tuning of the contact properties from both sides, calculated (experimental) efficiencies of 14.46%/16.89% (13.94%/16.21%) for the half-/full-contact HSCs were finally obtained. A superior power conversion efficiency (PCE) over 21% is further predicted by considering more optimal contact resistance as well as doping concentration of Si. Our findings clarify why textured-Si/PEDOT:PSS HSCs show V-oc and PCE that are inferior to those of planar counterparts in previous reports and further suggest a pathway to fully explore the efficiency potential of Si/PEDOT:PSS hybrid solar cells.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据