Article
Chemistry, Physical
Lei Guo, Bochuan Tan, Wenpo Li, Qingbiao Li, Xingwen Zheng, Ime Bassey Obot
Summary: In this study, experimental and theoretical methods were used to explore the corrosion inhibition properties of banana leaves water extract (BLWE) for X70 steel in hydrochloric acid solution. It was found that BLWE can effectively inhibit both the anodic and cathodic reactions of X70 steel, leading to a high corrosion inhibition efficiency of approximately 90%. Analysis shows that the compounds in BLWE, such as AHP, ATI, and DDA, demonstrate excellent anticorrosion characteristics by forming a dense barrier film on the steel surface.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Bo Jiang, Wenshou Sun, Jie Cai, Siming Chen, Bo Hou
Summary: This study introduced the environmentally benign ingredient DEAE into the FFA formulation based on unsaturated diamine, showing excellent corrosion inhibition effect in acidic environment. The results indicated that DEAE facilitated the adsorption of NOPDA onto carbon steel surface, with adsorption mechanisms involving chemisorption, electrostatic attraction, and hydrogen bonding. The protective film formed on the surface of carbon steel was found to prevent the transfer of charge, providing a good reference for the application of unsaturated fatty diamine.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Engineering, Chemical
Xianghong Li, Shuduan Deng, Guanben Du
Summary: Coconut diethanolamide (CDEA) is a potential corrosion inhibitor with good hydrolysis resistance. The study demonstrates that CDEA can act as an efficient inhibitor for cold rolled steel in HCl and H2SO4 solutions. The adsorption of CDEA follows the Langmuir isotherm.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2022)
Article
Chemistry, Physical
Shanghao Wu, Jinke Wang, Tong Liu, Xin Guo, Lingwei Ma
Summary: A novel carbon dots based complex with sulfosalicylic acid modification was synthesized, which showed both corrosion inhibition and corrosion sensing abilities. The corrosion inhibition behavior of the complex was greatly improved compared to carbon dots, sulfosalicylic acid, and their mixture. The complex formed a hydrophobic adsorption film to prevent the attack of corrosive media, and it exhibited high coverage and binding energy on the metal surface. Additionally, the complex showed a significant fluorescence quenching effect upon complexation with iron ions.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Chemistry, Physical
M. Abdallah, H. M. Altass, Arej S. Al-Gorair, Jabir H. Al-Fahemi, B. A. A. L. Jahdaly, K. A. Soliman
Summary: The study confirmed that nutmeg oil is an effective inhibitor for the corrosion of CSL-52 in hydrochloric acid solution, with increasing inhibition efficacy observed with higher nutmeg oil concentration and lower temperature. Electrochemical and computational studies showed that nutmeg oil acted as a mixed inhibitor and played a significant role in the corrosion inhibition process. This research also aimed to predict the inhibitory potency of the four molecular constituents of nutmeg oil through computational work.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Materials Science, Multidisciplinary
Shengjie Du, Shengyi Chen, Zekai Zhang, Zhicheng Ye, Huanv Mao, Huiting Yang, Cheng Lian, Chunyan Bao
Summary: In this study, a hydroxyl-terminated poly(amine-ester) hyperbranched polymer (HPAE-OHs) was used as a green, effective and economic corrosion inhibitor for mild steel. The results showed that HPAE-OHs can efficiently inhibit the corrosion of mild steel with a corrosion inhibition efficiency of 94.9% at a dosage of 100 mg/L.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Engineering, Chemical
Abdullah Salci, Handan Yuksel, Ramazan Solmaz
Summary: 2-(2-aminophneyl)benzimidazole (APBI) exhibits a high inhibition efficiency of 98.8% on the corrosion of mild steel in acidic solutions by adsorption and forming a protective organic film. It shows a mixed type corrosion inhibition effect and stable performance in corrosion processes.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2022)
Article
Chemistry, Physical
Ramazan Solmaz, Abdullah Salci, Yesim Aydin Dursuna, Gulfeza Kardasd
Summary: A comprehensive study was conducted to investigate the adsorption, corrosion inhibition efficiency and stability of acriflavine (ACF) on mild steel (MS) in 1 M HCl solution. The results showed that ACF adsorbs on the MS surface through chemical and physical interactions, forming a protective film that is uniform, adherent, and electrochemically stable. The inhibitor film exhibited high inhibition efficiencies of 92.8% and 97.1% after 1 h and 6 h immersion times, respectively. ACF was found to mitigate both anodic metal dissolution and cathodic hydrogen evolution reactions, making it an effective corrosion inhibitor for mild steel in acidic environments.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Chemistry, Multidisciplinary
Anil Kumar, Chandan Das
Summary: Metal corrosion has become a growing concern in local and industrial scales recently, affecting conventional production. The development of a novel and ecofriendly corrosion inhibitor using chayote fruit extract shows high efficiency, environmental friendliness, and economic benefits. The chayote extract adsorbs onto the metal surface, forming a protective layer that effectively inhibits corrosion.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2023)
Article
Chemistry, Physical
Yan-Li Lv, Fan-Yu Kong, Li Zhou, Yong-Xu Hu, Qi Wang, Yan-Qiu Wang, Xiao Li
Summary: IPB and DIPB were studied as inhibitors for mild steel in HCl solution, showing their ability to adsorb onto the steel surface by chemisorption and form complexes with Fe, demonstrating great potential in corrosion inhibition.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Engineering, Chemical
Xia Liu, Yue Sun, Meiheng Lu, Xuemei Pan, Zhengbin Wang
Summary: The transition metal complexes Ni(bpda)(2), Zn(bpda)(2), and Mn(bpda)(2) demonstrated superior corrosion inhibition performance compared to the bpda ligand, with Ni(bpda)(2) showing the most effective inhibition. Observations of corrosion morphology further confirmed the excellent performance of these complexes, while Fourier transform infrared and X-ray photoelectron spectroscopy analyses confirmed the adsorption mechanism of the corrosion inhibitors.
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
(2022)
Article
Chemistry, Physical
Fanhong Niu, Guanggang Zhou, Jianwei Zhu, Xiao Zhang, Yanyan Shi, Guiwu Lu, Zilong Liu
Summary: Nitrogen-doped carbon dots (NCDs) were synthesized with citric acid and thiourea as precursors to inhibit corrosion in the picking process of metal materials. The study found that NCDs had significant anti-corrosion capacity for X80 carbon steel, enhancing its corrosion resistance. The adsorption of NCDs on X80 surface followed Langmuir adsorption isotherm, dominated by physical adsorption.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Multidisciplinary
Fatma Kaya, Ramazan Solmaz, Ibrahim Halil Gecibesler
Summary: With the increasing sensitivity to the environment, people around the world have shown a tendency towards natural products. This study focuses on the adsorption and protection ability of Rheum ribes flower extract on mild steel corrosion in 1 M HCl solution. Various electrochemical techniques were employed to investigate the corrosion inhibition process, and the results showed that the flower extract formed a durable and protective film on the steel surface. The extract exhibited high protection efficiency, suggesting its potential as a natural corrosion inhibitor for mild steel in acidic environments.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2023)
Article
Biochemistry & Molecular Biology
Deshuai Zhen, Shaoqi Zhang, Xinyu Zhang, Hongjian Zhang, Jue Wang, Bo Chen, Yali Liu, Xiaohu Luo
Summary: In this study, polysaccharide chitosan and L-histidine were used to synthesize chitosan-based carbon dots (CA-CDs), which were then introduced as a corrosion inhibitor for mild steel in 1.0 M HCl solution. The CA-CDs exhibited high inhibition efficiency and their adsorption behavior well obeyed the Langmuir adsorption isotherm containing both chemisorption and physisorption. The study provides insights into the corrosion inhibition mechanism of CA-CDs.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Inorganic & Nuclear
Soumya Ferraa, Moussa Ouakki, Hanane Barebita, Abderrazak Nimour, Mohammed Cherkaoui, Taoufiq Guedira
Summary: The Phosphovanadate-based glass is an efficient inhibitor with predominant cathodic effectiveness as a mixed-type inhibitor. The inhibition efficiency increases with concentration but decreases with temperature rise.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Engineering, Chemical
Moses M. Solomon, Kufre E. Essien, Roland T. Loto, Olabisi T. Ademosun
Summary: The inhibition performance of 5-methyl-3-phenylisoxazole-4-carboxylic acid (MPC) alone and in combination with potassium iodide (KI) for low carbon steel in 1.0 M HCl and H2SO4 solutions was studied. Results showed that KI in combination with MPC significantly improved inhibition efficiency, making it suitable for use in acid cleaning operations.
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
(2022)
Article
Materials Science, Multidisciplinary
Roland Tolulope Loto, Temitayo Ikuerowo, Sophia Ifezue
Summary: The corrosion inhibition performance of Pelargonium and Citrus reticulata oil concentrates and their admixture on carbon steel in different media was studied using various techniques. The results showed that Citrus reticulata oil performed well in HCl solution, while Pelargonium oil was effective in H2SO4 solution. The admixture showed enhanced corrosion inhibition performance in HCl solution.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Chemistry, Physical
Roland Tolulope Loto, Victor Jonathan David, Chinazom Victor Iroanyanwu, Bilkisu Chineyeze Suleiman Atane
Summary: The corrosion resistance of A36 carbon steel in the presence of different concentrations of Commiphora myrrha (CM), Cymbopogon (CP) essential oil extracts, and their combined admixture (CMCP) was investigated. The results showed that CM extract exhibited poor reactivity at low concentrations but showed effective inhibition at higher concentrations, while CP extract showed good corrosion inhibition performance in both acids. CMCP performed poorly in H2SO4 but showed good inhibition efficiency in HCl. The oil extracts adsorbed onto the A36 steel surface to form protective films, resulting in inhibition of corrosion.
SURFACE REVIEW AND LETTERS
(2022)
Article
Green & Sustainable Science & Technology
Ifeanyi E. Uzoma, Moses M. Solomon, Roland T. Loto, Saviour A. Umoren
Summary: This study investigated the corrosion inhibition effect of aspartame, a natural compound, on T95 carbon steel in acidizing process. The results showed that aspartame effectively inhibited the corrosion at high temperatures and the inhibition efficiency increased with temperature. The findings were confirmed by various experimental techniques, indicating the potential of aspartame as a corrosion inhibitor for acidizing.
Article
Engineering, Multidisciplinary
Roland Tolulope Loto
Summary: The corrosion resilience of annealed and quenched 434 ferritic stainless steel (434FS) was studied in the presence of 1 M H2SO4 with different NaCl concentrations. The results showed that annealed 434FS had the highest corrosion rate output, while untreated and quenched 434FS had lower corrosion resistance. The increase in NaCl concentration significantly affected the corrosion behavior of untreated and heat-treated 434 steels. Annealed 434FS exhibited the best passivation performance and resistance to localized deterioration.
COGENT ENGINEERING
(2022)
Article
Materials Science, Multidisciplinary
Roland Tolulope Loto
Summary: The utilization of plant extracts for corrosion protection of metallic alloys has been significantly increasing in recent years. Ginger, tea tree, and grapefruit essential oil extracts were evaluated for their corrosion protection effect on mild steel. The results showed that the extracts effectively inhibited corrosion, with inhibition efficiency above 95%.
MATERIALS RESEARCH EXPRESS
(2022)
Article
Materials Science, Multidisciplinary
Roland Tolulope Loto, Williams Joseph Ajuwaeze
Summary: This study investigates the effect of maize husk particulates on the corrosion resistance of 1070 aluminium alloy matrix. The results show that the corrosion rate of the alloy decreases with an increase in maize husk content and particle size. The composite with 15% maize husk content and 300μm particle size demonstrates the lowest corrosion values. Optical microscopy and x-ray diffraction analysis confirm these findings.
MATERIALS RESEARCH EXPRESS
(2022)
Article
Materials Science, Multidisciplinary
Roland Tolulope Loto
Summary: This study evaluated the corrosion resistance of high carbon steel (HCS) in CH3COOH and C6H8O7 solutions with the addition of admixed citronella and myrrh essential oil extract (CNM). The results showed that CNM effectively inhibited corrosion in CH3COOH but performed poorly in C6H8O7 solution. Open circuit potential measurements indicated that CNM reduced the activation barrier for HCS corrosion. X-ray diffractometry and ATF-FTIR spectroscopy showed significant changes in the diffraction peaks and transmittance of certain compounds on the HCS surface in the presence of CNM.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Multidisciplinary Sciences
Roland Tolulope Loto, Moses M. Solomon
Summary: The corrosion inhibition properties of a mixture of ginger and grapefruit essential oils (GPP) on mild steel (MS) in 0.5 M H2SO4 solution were investigated. The results showed that GPP could effectively reduce the corrosion rate and current density of MS, with inhibition efficiency ranging from 76.52% to 93.5%.
SCIENTIFIC AFRICAN
(2023)
Proceedings Paper
Materials Science, Multidisciplinary
Victor David, Chinazom Iroanyanwu, Bilkisu Suleiman Atane, Roland Tolulope Loto
Summary: The corrosion inhibition properties of Commiphora myrrha (CM), Cymbopogon nardus (CN), and their combined admixture (CMCN) on low carbon steel in dilute H2SO4 and HCl solution were studied. Results showed that CM performed poorly at low concentrations, while CN performed effectively at all concentrations. The performance of CM and CN in HCl solution was generally similar. CMCN performed poorly in H2SO4 solution but effectively in HCl solution. Concentration was found to be the only statistically relevant variable influencing the performance outputs of the inhibitors.
MATERIALS TODAY-PROCEEDINGS
(2022)
Proceedings Paper
Materials Science, Multidisciplinary
Temitayo Ikuerowo, Sophia Ifezue, Roland Tolulope Loto
Summary: This study investigated the corrosion protection efficiency of Citrus reticulate (CR) and Pelargonium (PG) oil distillates, as well as their combined admixture (CRPG), on mild steel in sulfuric acid (H2SO4) and hydrochloric acid (HCl) solutions. The results showed that CR and PG performed well in HCl solution at all concentrations, with optimal protection values of 85.94% and 89.68% at 1% and 1.5% distillate concentrations. However, their performance in H2SO4 solution was significantly dependent on concentration, with poor protection values at certain concentrations. The CRPG mixture exhibited effective protection in H2SO4 solution, while performing poorly in HCl solution. Statistical analysis revealed that inhibitor concentration had a significant impact on the protection performance, while exposure time had a marginal effect. The data also indicated that CRPG and CR had stable inhibition properties over time and concentration. Furthermore, the protection efficiency of CR and PG in both HCl and H2SO4 solutions exceeded the threshold value in a certain range of error, indicating their effectiveness in corrosion protection.
MATERIALS TODAY-PROCEEDINGS
(2022)
Proceedings Paper
Materials Science, Multidisciplinary
Roland Tolulope Loto
Summary: This article presents data on the corrosion rate of mild steel and the protection efficiency of calcivitol. The study shows that increasing the concentration of calcivitol significantly improves the protection performance of the compound, while the effect of inspection time is relatively small.
MATERIALS TODAY-PROCEEDINGS
(2022)
Proceedings Paper
Materials Science, Multidisciplinary
Roland Tolulope Loto, Philip Babalola
Summary: The corrosion resistance of AA1070 aluminum alloy and AA1070 reinforced with alumina at different weight compositions and particle sizes was compared. The results showed that the solution with high chloride content caused the most severe corrosion, and increasing the alumina content and particle size of the composite could reduce the corrosion rate. The anodic and cathodic reaction mechanisms varied with different electrolytes.
MATERIALS TODAY-PROCEEDINGS
(2022)
Proceedings Paper
Materials Science, Multidisciplinary
Roland Tolulope Loto
Summary: The study showed that C70600 alloy exhibits better corrosion resistance at higher Cl(-) ion concentration, while C26000 alloy has higher corrosion susceptibility and undergoes selective dissolution after anodic polarization.
MATERIALS TODAY-PROCEEDINGS
(2022)
Proceedings Paper
Materials Science, Multidisciplinary
Roland Tolulope Loto, Cleophas Akintoye Loto, Muyiwa Fajobi, Gabriel Olanrewaju
Summary: Admixed rosemary and castor oil extracts showed effective corrosion inhibition properties on high carbon steel and low carbon mold steel in acid solutions, with the inhibition efficiency being influenced by exposure time.
MATERIALS TODAY-PROCEEDINGS
(2022)
