期刊
SCIENCE BULLETIN
卷 62, 期 18, 页码 1275-1282出版社
ELSEVIER
DOI: 10.1016/j.scib.2017.08.027
关键词
Benzotriazole (BTA); Malononitrile; Fullerene-free solar cells; Non-fullerene acceptor; PTB7-Th
资金
- National Key Research and Development Program of China [2017YFA0206600]
- Key Research Program of Frontier Sciences, Chinese Academy of Sciences [QYZDB-SSW-SLH033]
- National Natural Science Foundation of China [51673048, 51473040, 21602040]
- Natural Science Foundation of Beijing [2162045]
The open-circuit voltage (V-oc) of classical photovoltaic polymers, such as P3HT and PTB7-Th, are always restricted when combining with fullerene derivatives, due to the difficulty of modulating the energy levels of fullerene derivatives. Thus, design of new non-fullerene small molecule acceptor (NFSMA) is very significant to match with these mature polymer donors and improve the Voc and power conversion efficiency (PCE). Here, a new benzotriazole (BTA)-based NFSMA, BTA7 was synthesized by adopting A(2)=A(1)-D-A(1)=A(2) type molecular backbone. By using a strong electron-accepting unit of malononitrile (M) as terminal segment A2, BTA7 demonstrates strong crystallinity, red-shifted absorption spectrum and down-shifted lowest unoccupied molecular orbital (LUMO) energy levels in comparison with BTA1 and BTA2. Organic solar cells (OSCs) based on PTB7-Th: BTA7 realized a high V-oc of 1.05 V with a moderate PCE of 4.60%. The energy loss (E-loss = E-g - eV(oc)) of 0.53 eV is lower than the experiential minimum value of 0.6 eV, which indicates PTB7-Th still has large potential to improve the V-oc and photovoltaic performance after the development of novel electron acceptors. (C) 2017 Science China Press. Published by Elsevier B. V. and Science China Press. All rights reserved.
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