期刊
ADVANCED SCIENCE
卷 4, 期 8, 页码 -出版社
WILEY
DOI: 10.1002/advs.201700101
关键词
conjugated microporous polymers; destannylation; palladium-free; photocatalysis; Stille coupling
资金
- Max Planck Society
- VCI, Verband der Chemischen Industrie
The Stille coupling reaction is a versatile method to mainly form aromatic C-C bonds. However, up to now, the use of palladium catalysts is necessary. Here, a palladium-free and photocatalytic Stille-type coupling reaction of aryl iodides and aryl stannanes catalyzing a conjugated microporous polymer-based phototcatalyst under visible light irradiation at room temperature is reported. The novel coupling reaction mechanism occurs between the photo-generated aryl radical under oxidative destannylation of the aryl stannane, and the electron-activated aryl iodide, resulting into the aromatic C-C bond formation reaction. The visible light-promoted Stille-type coupling reaction using the polymer-based pure organic photocatalyst offers a simple, sustainable, and more economic synthetic pathway toward palladium-free aromatic C-C bond formation.
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