4.7 Article

In situ preparation of silver-polyacrylonitrile nanocomposite fibres

期刊

EUROPEAN POLYMER JOURNAL
卷 69, 期 -, 页码 385-395

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2015.06.024

关键词

Polyacrylonitrile; Silver nanoparticles; Fibres; Nanocomposite

资金

  1. National Science Centre [DEC-2013/09/B/ST8/03679]
  2. [DI2012 005142]

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In the article a new method of volume modification of polyacrylonitrile (PAN) fibres with silver nanoparticles was presented. Nanoparticles were synthesized in situ in the polymer spinning mass. Fibres are formed in the wet spinning method. The precursor of silver ions and reductant was added directly to the spinning solution containing polyacrylonitrile and dimethylformamide (DMF) as a solvent. Tests performed by dynamic light scattering method showed that the average size of the resulting silver nanoparticles is approx. 10 nm. Polyacrylonitrile molecules were used as a polymer stabilising agent. Silver nanoparticles interact with nitrile groups from PAN molecules causing the formation polymeric micelles, which prevent their further growth and agglomeration. Observations performed by TEM confirmed the presence of the stabilising polymeric coating on silver nanoparticles formed in situ in spinning mass. (C) 2015 Elsevier Ltd. All rights reserved.

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