期刊
ACS PHOTONICS
卷 5, 期 2, 页码 324-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsphotonics.7b01093
关键词
Purcell effect; lifetime measurement; localized surface plasmon; neutral nitrogen-vacancy defect; electron energy loss spectroscopy; cathodoluminescence
类别
资金
- National Agency for Research under the program of future investment TEMPOS-CHROMATEM [ANR-10-EQPX-50]
- National Agency for Research under the program of future investment TEMPOS-CHROMATEM [ANR-10-EQPX-50]
The local density of optical states governs an emitters' lifetime and quantum yield through the Purcell effect. It can be modified by a surface plasmon electromagnetic field, but such a field has a spatial extension limited to a few hundreds of nanometers, complicating the use of optical methods to spatially probe emitter-plasmon coupling. Here we show that a combination of electron-based imaging, spectroscopies, and photon-based correlation spectroscopy enables measurement of the Purcell effect with nanometer and nanosecond spatiotemporal resolutions. Due to the large variability of radiative lifetimes of emitters in nanoparticles we relied on a statistical approach to probe the coupling between nitrogen-vacancy centers in nanodiamonds and surface plasmons in silver nanocubes. We quantified the Purcell effect by measuring the nitrogen-vacancy excited state lifetimes in a large number of either isolated nanodiamonds or nanodiamond-nanocube dimers and demonstrated a significant lifetime reduction for dimers.
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