4.6 Article

Rational design of a difluorobenzo[c]cinnoline-based low-bandgap copolymer for high-performance polymer solar cells

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 5, 期 16, 页码 7300-7304

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta00495h

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资金

  1. National Natural Science Foundation of China [51573153, 61564003, 21474081]
  2. Scientific Research Fund of Hunan Provincial Education Department [15A180]
  3. Hunan Collaborative Innovation Center of Chemical Engineering & Technology with Environmental Benignity and Effective Resource Utilization
  4. Guangxi Bagui Scholar Program
  5. Guangxi Natural Science Foundation [2015GXNSFGA139002]

向作者/读者索取更多资源

A copolymer with A-A structure is rationally designed and synthesized by using difluorobenzo[c]-cinnoline (DFBC) as weak electron-withdrawing (A) moieties and 1,4-diketo-pyrrolo[3,4-c]pyrrole (DPP) as strong A moieties. Polymer solar cells based on PDFBC-DPP and PC71BM showed a promising power conversion efficiency of 7.92%, which is one of the highest values in polymer solar cells based on A-A structure.

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