Review
Chemistry, Physical
Xuan Zhang, Huiyang Ma, Jiqiong Liu, Jiahang Chen, Huichao Lu, Yudai Huang, Jiulin Wang
Summary: The S@pPAN composite material, which provides a conductive pathway for sulfur active material at the molecular level, has shown promising electrochemical performances in lithium-sulfur batteries. However, the accurate structure of S@pPAN and its redox reaction mechanism during charge-discharge process have not been determined yet. This review summarizes previous research and inferences on the structure and electrochemical reaction mechanism of S@pPAN, providing a reference for future study of lithium-sulfur batteries.
Article
Chemistry, Multidisciplinary
Wei Zhang, Qiang Wu, Ziqi Zeng, Chuang Yu, Shijie Cheng, Jia Xie
Summary: An organoselenide compound, phenyl diselenide (PDSe), is used as a soluble electrolyte additive to improve the kinetics and battery performance of a sulfurized polyacrylonitrile cathode through the formation of dynamic S-Se bonds at the solid-liquid interface.
CHEMICAL COMMUNICATIONS
(2021)
Article
Nanoscience & Nanotechnology
Huihun Kim, Milan K. Sadan, Changhyeon Kim, Minyeong Jeon, Ki-Won Kim, Kwon-Koo Cho, Jou-Hyeon Ahn, Hyo-Jun Ahn
Summary: The research demonstrates a simple and low-cost approach for synthesizing Li/S batteries with improved capacity by synthesizing sulfurized polyacrylonitrile (S-PAN) electrodes through glass casting and heating method. The optimized electrode synthesis conditions were determined through various precursor ratios, resulting in high internal porosity and improved Li+ ion mobility. The S-PAN electrodes exhibited impressive capacity and cyclability without the use of binders or conducting agents, making it a promising method for large scale Li/S battery production.
SCIENCE OF ADVANCED MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Kunpeng Yu, Guorui Cai, Mingqian Li, Junlin Wu, Varun Gupta, Dong Ju Lee, John Holoubek, Zheng Chen
Summary: This study demonstrates the importance of electrolyte chemistry in high-sulfur loading sulfurized polyacrylonitrile (SPAN) cathodes, showing that a localized-high-concentration electrolyte can enhance the reversible capacity and cycling stability. The research provides guidance for electrolyte design and sulfur optimization in SPAN cathodes.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Electrochemistry
Strauss Langrud, Amir Abdul Razzaq, Shriram Santhanagopalan, Ryan Brow, Weibing Xing
Summary: This study investigates the impacts of different synthesis conditions on the formation of sulfur to PAN bonds and redox reaction mechanisms of multi-phase SPAN. It reveals that the synthesis conditions greatly affect the material properties and electrochemical performance of SPAN, with complete sulfurization leading to exceptional stability in Li-S cells.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2022)
Article
Engineering, Environmental
Shuxin Zhang, Wen Ren, Yanna NuLi, Baofeng Wang, Jun Yang, Jiulin Wang
Summary: The use of sulfurized-pyrolyzed polyacrylonitrile (S@pPAN) composite with 47.3 wt% sulfur as cathode material along with different types of electrolytes has shown to effectively suppress polysulfide dissolution and shuttle, leading to enhanced electrochemical performance in magnesium-sulfur (Mg-S) batteries.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Tao Ma, Youxuan Ni, Diantao Li, Zhengtai Zha, Song Jin, Weijia Zhang, Liqun Jia, Qiong Sun, Weiwei Xie, Zhanliang Tao, Jun Chen
Summary: By using a weakly solvating ether electrolyte, a stable cathode electrolyte interphase (CEI) can be formed on the sulfurized polyacrylonitrile (SPAN) electrode, effectively blocking the dissolution of polysulfides into the electrolyte, thus improving the electrochemical performance and cycle life of the battery.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Nanoscience & Nanotechnology
Zhaohui Wu, Seong-Min Bak, Zulipiya Shadike, Sicen Yu, Enyuan Hu, Xing Xing, Yonghua Du, Xiao-Qing Yang, Haodong Liu, Ping Liu
Summary: The study demonstrates the crucial role of LiNO3 additive in preventing LiSx species from dissolving into the electrolyte, thereby reducing shuttle effect and capacity loss. Carbonate electrolyte forms porous dendritic Li morphology on Li anode, while ether-based electrolyte forms dense spherical Li morphology, proving that ether-based electrolyte with LiNO3 is the preferred choice for stable cycling.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Polymer Science
Ting Ma, Xiuyun Ren, Liang Hu, Wanming Teng, Xiaohu Wang, Guanglei Wu, Jun Liu, Ding Nan, Baohua Li, Xiaoliang Yu
Summary: Lithium-metal batteries require electrolytes compatible with lithium-metal anodes. This research presents a diluted electrolyte that achieves high Coulombic efficiency for lithium plating/stripping and maintains high specific capacity during prolonged cycling.
Article
Chemistry, Physical
Chang-Xin Zhao, Wei-Jing Chen, Meng Zhao, Yun-Wei Song, Jia-Ning Liu, Bo-Quan Li, Tongqi Yuan, Cheng-Meng Chen, Qiang Zhang, Jia-Qi Huang
Summary: A redox mediation strategy is proposed to improve electron transfer processes in Li-S batteries with SPAN cathodes. By introducing a quinone-based redox mediator, an additional redox pathway with strengthened interfacial kinetics is provided. The redox mediator assisted SPAN cathodes show higher specific capacity, improved rate performance, reduced polarization, and longer cycling lifespan in both ether-based and carbonate-based electrolyte systems.
Article
Chemistry, Multidisciplinary
Xiaojing Zhang, Xinyi Ge, Zhigang Shen, Han Ma, Jingshi Wang, Shuai Wang, Lei Liu, Beibei Liu, Lixin Liu, Yizhi Zhao
Summary: Water-based binders offer numerous advantages in LIB cathodes over environmentally harmful binders like PVDF. Electrodes with SA and CMC/PTFE showed outstanding performance, with enhanced kinetics capability in Li+ transfer. The use of water-based binders resulted in smaller charge-transfer resistance values, lower polarization, and enhanced conductive network coverage on LFP electrodes, indicating promising prospects for their use in LIB cathodes.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Ke Wang, Teng Zhao, Nanxiang Zhang, Tao Feng, Li Li, Feng Wu, Renjie Chen
Summary: This study presents a salt-templating method for the fabrication of ultrathin SPAN nanosheets, improving its redox kinetics. In situ Raman analysis reveals the reversible breaking and formation of C-S/S-S bonds in SPAN nanosheets during cycling, demonstrating excellent performance at high current densities.
Article
Chemistry, Applied
Yangze Huang, Yongqin Wang, Yu Fu
Summary: In this study, an eco-friendly and porous cellulose gel electrolyte (GE) was designed and prepared to address safety issues in lithium-sulfur batteries. Additionally, covalent functional black phosphorous nanosheets (BP-Li) were used as superior Li+ conductors to enhance ion transmission and suppress lithium dendrite growth. Experimental results showed that the cellulose/BP-Li GE exhibited satisfactory ionic conductivity and maintained high capacity after 500 cycles.
CARBOHYDRATE POLYMERS
(2022)
Article
Chemistry, Physical
Chen-Jui Huang, Ju-Hsiang Cheng, Wei-Nien Su, Pouya Partovi-Azar, Liang-Yin Kuo, Meng-Che Tsai, Ming-Hsien Lin, Sara Panahian Jand, Ting-Shan Chan, Nae-Lih Wu, Payam Kaghazchi, Hongjie Dai, Peter Maria Bieker, Bing-Joe Hwang
Summary: By utilizing in-situ Raman and in-situ X-ray absorption spectroscopies, along with density functional theory calculations, the fundamental reaction mechanism of sulfurized polyacrylonitrile (S-cPAN) cathode material in lithium-sulfur batteries is unveiled. The formation of sulfur-nitrogen bonds and their strong interactions during the synthesis process are proposed, providing a new perspective on sulfur chemistry and paving the way for designing high capacity, shuttle-free cathode materials for next-generation Li-S batteries.
JOURNAL OF POWER SOURCES
(2021)
Article
Engineering, Chemical
Wei-Cheng Li, Chen-Hsueh Lin, Chih-Chi Ho, Tsung-Tien Cheng, Po-Hsin Wang, Ten-Chin Wen
Summary: This study demonstrates for the first time that CMC-SBMA, as a binder, regulates ion transportation to enhance the performance of energy storage devices. Through zwitterionic modification, CMC-SBMA exhibits lower activation energy and higher conductivity, resulting in higher specific capacitance and lower internal resistance in lithium-ion batteries and supercapacitors.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2022)
Article
Chemistry, Physical
Huabo Liu, Jiaxing Liang, John Watt, Richard D. Tilley, Rose Amal, Da-Wei Wang
Summary: In this study, a facile and scalable electrochemical deposition method for synthesizing quasi-layered conductive organic-inorganic hybrid films with controllable thickness and size was demonstrated. The films exhibited high gravimetric density and excellent capacitance performance, suggesting their great potential for electrochemical energy storage applications. The charge storage mechanism of the films was identified to be ion intercalation accompanied by change in oxidation states of the polymer backbone.
Review
Chemistry, Multidisciplinary
Tengfei Qiu, Eser Metin Akinoglu, Bin Luo, Muxina Konarova, Jung-Ho Yun, Ian R. Gentle, Lianzhou Wang
Summary: Transparent conductive films (TCFs) are indispensable in optoelectronic applications, and the development of new materials that combine transparency, electrical conductivity, and variable functionality is needed. Nanomesh TCFs, with periodic or irregular structures, have emerged as promising candidates with superior mechanical properties compared to traditional metal oxide TCFs. Nanosphere lithography (NSL) is a versatile platform for fabricating nanomesh TCFs, offering a wide range of materials with diverse functions and device compatibility. This review provides a comprehensive overview of the NSL process, structure-property relationships of nanomesh TCFs, and their applications in various optoelectronic technologies.
ADVANCED MATERIALS
(2022)
Review
Chemistry, Physical
Shiwei Tao, Ming Li, Miaoqiang Lyu, Lingbing Ran, Roger Wepf, Ian Gentle, Ruth Knibbe
Summary: This paper reviews the opportunities and obstacles of closed-cell in operando TEM systems and compares them with open-cell configurations. By observing the processes in closed-cell configurations, a more reliable understanding of the electrochemical setups of most ion batteries under development can be obtained. However, the closed-cell configuration sacrifices imaging resolution.
Article
Nanoscience & Nanotechnology
Hui Li, Ronan Chu, Guanran Zhang, Paul L. Burn, Ian R. Gentle, Paul E. Shaw
Summary: The effect of alkylamine additives with different chain lengths on the performance of perovskite solar cells was studied. The length of the alkyl chain was found to have a critical effect on the structure and performance of the perovskite film. Shorter chain length additives were distributed throughout the film, with a 2D phase observable at high concentrations. In contrast, longer chain length additives phase-separated and concentrated at the film surface.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Nanoscience & Nanotechnology
Hui Li, Abdulaziz S. R. Bati, Ronan Chu, Guanran Zhang, Yanyan Li, Qianqian Lin, Paul L. Burn, Paul E. Shaw, Ian R. Gentle
Summary: This study demonstrates that the electronic properties of inorganic nickel oxide films can be modified by fluorination, resulting in reduced surface defects and improved performance and stability of perovskite solar cells.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Multidisciplinary Sciences
Ruopian Fang, Zhaojun Han, Jibiao Li, Zhichun Yu, Jian Pan, Soshan Cheong, Richard D. Tilley, Francisco Trujillo, Da-Wei Wang
Summary: This study reports the design of hyperbranched vertical arrays of defective graphene to enhance the practical cell-level energy density of Li metal batteries. By rationalizing the degradation dynamics of Li metal anodes, high-energy Li metal cells were prototyped under realistic conditions, paving the way towards practical Li metal batteries.
Article
Chemistry, Physical
Jiaxing Liang, Aditya Rawal, Mengying Yu, Kefeng Xiao, Huabo Liu, Yu Jiang, Alison Lennon, Da-Wei Wang
Summary: We report electrochemically tuned layered polyaniline with solidified SEI nanochannels as a new type of low potential anode for high voltage pseudocapacitive intercalation LISCs (PI-LISCs). The tuned layered polyaniline achieved high volumetric capacity of 196 mAh cm-3 at 0.01 V vs. Li/Li+ and allowed the fabrication of a high voltage PI-LISC with a high energy density of 100.5 Wh L-1, a high power density of 13.7 kW L-1, and excellent capacity retention of 90.1% after 10,000 cycles. Our findings present a significant step forward in opening up new opportunities for high energy and high power PI-LISCs.
Article
Chemistry, Multidisciplinary
Hui Li, Ronan Chu, Abdulaziz S. R. Bati, Satakshi Gupta, Paul L. Burn, Ian R. Gentle, Paul E. Shaw
Summary: The study investigates the impact of two fluorinated additives (FPAI and FMABr) on the performance of inverted perovskite solar cells. By adding FPAI to the anode modifying layer and blending 0.32 mol% of FMABr into the perovskite layer, hysteresis-free current density-voltage characteristics and a maximum power conversion efficiency of 22.3% were achieved, indicating a 1.7% improvement compared to the control device.
ADVANCED MATERIALS INTERFACES
(2023)
Review
Nanoscience & Nanotechnology
Norah S. Alghamdi, Masud Rana, Xiyue Peng, Yongxin Huang, Jaeho Lee, Jingwei Hou, Ian R. Gentle, Lianzhou Wang, Bin Luo
Summary: This article presents a comprehensive discussion on the recent advances in zinc-bromine rechargeable batteries with flow or non-flow electrolytes, including the challenges and solutions in zinc and bromine half-cells. It also discusses the key performance metrics of ZBRBs and assessment methods using various ex situ and in situ/operando techniques. Overall, ZBRBs are promising candidates for next-generation energy storage due to their lower material cost, deep discharge capability, non-flammable electrolytes, long lifetime, and good reversibility, although further improvements in efficiency and stability are needed.
NANO-MICRO LETTERS
(2023)
Article
Chemistry, Physical
Lachlan Packman, Neil Mallo, Aaron Raynor, Mile Gao, Mohammad Babazadeh, Hui Jin, David M. Huang, Paul L. Burn, Ian R. Gentle, Paul E. Shaw
Summary: The strategy of using a bulk-heterojunction light-absorbing layer has led to the most efficient organic solar cells. The factors that affect the thin film dielectric constants are still not well understood. In this work, we report an organic semiconductor material that can be solution processed or vacuum evaporated to form good quality thin films and explore its effect on the dielectric constant and other optoelectronic properties.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Qiyuan Li, Lixue Jiang, Gan Huang, Da-Wei Wang, Jack Shepherd, Rahman Daiyan, Christos N. Markides, Robert A. Taylor, Jason Scott
Summary: A solar-driven system is proposed for hydrogen production from waste biomass with low carbon and water footprints. The system consists of a waste biomass concentrator, a biomass preconditioning reactor integrated with hybrid PV-thermal collectors, and a flow electrolysis cell equipped with a high-performance electrode. The system achieved an overall solar-to-hydrogen efficiency of 7.5% and also produced clean water and a value-added chemical by-product. This work presents a new route towards efficient and economically feasible renewable hydrogen production.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Yao Li, Siyuan Liu, Runlu Liu, Jian Pan, Xin Li, Jianyu Zhang, Xiaoxiao Zhang, Yixin Zhao, Dawei Wang, Hengdao Quan, Shenmin Zhu
Summary: This study resolves the issue of carrier recombination on the dual surfaces of the m-BiVO4 component in water oxidation by constructing an m-BiVO4/carbon nitride (C3N4) Z-scheme heterostructure based on the m-BiVO4/reduced graphene oxide (rGO) Mott-Schottky heterostructure. The rGO effectively accumulates photogenerated electrons from m-BiVO4 and facilitates their diffusion through a highly conductive carbon network. The Z-scheme electron transfer at the heterointerface of m-BiVO4/C3N4 leads to spatial separation of electron-hole pairs and maintains strong redox potentials, resulting in significantly improved O-2 yield and the generation of center dot OH and center dot O-2(-) radicals.
NANOSCALE ADVANCES
(2023)
Review
Chemistry, Physical
Lixue Jiang, Xiaoxuan Luo, Da-Wei Wang
Summary: This review provides an overview of aqueous flexible metal-air batteries, focusing on their fundamental working principles, battery configurations, common issues, and recent advances in designing high-performance metal electrodes, solid-state electrolytes, and air electrodes. It summarizes bifunctional oxygen electrocatalysts for constructing efficient air electrodes, and provides a perspective on the existing challenges and possible future research directions.
Article
Chemistry, Physical
Kuang-Hsu Wu, Yuefeng Liu, Xin Tan, Yangyang Liu, Yangming Lin, Xing Huang, Yuxiao Ding, Bing-Jian Su, Bingsen Zhang, Jin-Ming Chen, Wensheng Yan, Sean C. Smith, Ian R. Gentle, Shenlong Zhao
Summary: Modulating the steric-electronic configuration of metal-organic centers is key for tuning the activity and selectivity of heterogeneous reactions. In this study, three different asymmetric metal-organic complexes with unique steric-electronic structures are immobilized on nanocarbon for an electron-transfer-controlled oxygen reduction reaction. The results show that acidic diamine ligands facilitate a four-electron transfer, while basic ligands drive a highly selective two-electron route, regulated by the ligand's proton transfer ability.
Article
Materials Science, Multidisciplinary
Jaber Saghaei, Manikandan Koodalingam, Paul L. Burn, Ian R. Gentle, Almantas Pivrikas, Paul E. Shaw
Summary: This study investigated efficient solution-processed organic light-emitting diodes based on a blue emissive phosphorescent dendrimer and exciplex host. By experimenting with different hole injection layers, the researchers identified the factors causing changes in device performance, providing insights for future research in this area.
MATERIALS ADVANCES
(2022)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
