4.6 Article

A novel gelatin-guided mesoporous bowknot-like Co3O4 anode material for high-performance lithium-ion batteries

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 5, 期 11, 页码 5342-5350

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta10327h

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资金

  1. National Natural Science Foundation of China [21471006, 21271009]
  2. Programs for Science and Technology Development of Anhui Province [1501021019]
  3. Program for Innovative Research Team of Anhui Education Committee
  4. Program for Talents Team of University in Anhui Province

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A mesoporous bowknot-like Co3O4 material has been synthesized through a facile hydrothermal method, using cobalt nitrate as the cobalt source, urea as the precipitator and gelatin as the guide agent, followed by calcination at 600 degrees C in air. Morphology characterization reveals that this bowknot-like Co3O4 material possesses a mesoporous structure consisting of nanoparticles. Electrochemical experiments illustrate that the mesoporous bowknot-like Co3O4 anode material exhibits a superior first and 100th reversible specific capacity of 1427.9 mA h g(-1) and 1388.8 mA h g(-1) at 0.2C, respectively. This material also delivers a high charge capacity of 751.3 mA h g(-1) after 150 cycles at 2C. The novel preparation method and satisfactory performance make the bowknot-like Co3O4 a good candidate as a high-performance anode material for use in Lithium-Ion Batteries (LIBs).

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