Article
Engineering, Chemical
Sepideh Niazi, Espen Olsen, Heidi S. Nygard
Summary: This study investigated the use of electrodeposition to remove impurities from molten salt. The results showed that Cu and Fe(III) can be completely removed in a relatively short time, but the removal of Fe(II) and Mn was less effective with some impurities remaining.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Physical
Akshay Bhujbal, K. A. Venkatesan, Bhalchandra M. Bhanage
Summary: A new protic ionic liquid [HmPip][OTf] was successfully synthesized and used for aluminum electrodeposition, resulting in bright aluminum deposits. The findings indicate the potential application of this new liquid in the field of aluminum electrodeposition.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Environmental Sciences
Aziz Aynaou, Boubaker Youbi, Youssef Lghazi, Mohammed Ait Himi, Chaimaa El Haimer, Jihane Bahar, Ahmed Sahlaoui, Itto Bimaghra
Summary: In this study, polyaniline films were fabricated on ITO substrates using different electrolytes. The effect of the counter ion on the electrochemical energy storage performances of polyaniline in supercapacitors was investigated. The specific capacitance was found to have a clear dependence on the counter ion.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Environmental Sciences
M. Ramya, P. Senthil Kumar, Gayathri Rangasamy, V. Uma Shankar, G. Rajesh, K. Nirmala
Summary: An electrochemical sensor using a copper oxide Molybdenum sulfide modified electrode was employed for the detection of sulfamethoxazole. The CuO/MoS2 modified electrode exhibited exceptional electrochemical performance, showing enhanced conductivity and linear correlation between peak current and SMX concentration, with a reliable detection limit of 0.3 mu M.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Zhongmin Hou, Xiaomin Wang, Jidong Li, Zhen Li, Yiyong Wang, Hongxuan Xing
Summary: In this study, the electrochemical behavior of indium was investigated using different electrochemical methods. It was found that the electrodeposition process of indium is irreversible. The average charge transfer coefficient of In3+ was determined using cyclic voltammetry. The nucleation mechanism of indium was analyzed using chronoamperometry, and the reduction process of In3+ was studied using alternating current impedance. SEM and XRD techniques confirmed the purity of the cathodic products deposited on the titanium electrode.
FRONTIERS IN CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Min Hee Joo, So Jeong Park, Sung-Min Hong, Choong Kyun Rhee, Youngku Sohn
Summary: In this study, a large dataset of lanthanide (III) ions' electrochemical behaviors and electrodeposition on bare and terpyridine-functionalized Ti sheets was established. The experimental results demonstrated that the electrodeposited lanthanide materials were similar lanthanide complexes, which could be valuable for understanding lanthanide ions' electrochemical behaviors and improving recovery methods.
MATERIALS TODAY COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Anoop Singh, Asha Sharma, Ashok K. Sundramoorthy, Sandeep Arya
Summary: Electrochemical deposition was used to generate cuprous oxide nanostructure on conductive fabric, which was analyzed by SEM, photoluminescence, XPS, and XRD. The cuprous oxide-coated fabric sensor exhibited high purity, clean morphological structure, and consistent crystallite size. The sensor showed good response to glucose with high stability, linear connection, and low detection limits.
Article
Chemistry, Physical
Daniela Mirela Lima Pinheiro, Lucas Lima Bezerra, Ana Aline Coelho Alcanfor, Filipe Xavier Feitosa, Norberto Kassio Vieira Monteiro, Adriana N. Correia, Pedro de Lima Neto, Hosiberto Batista de Sant'Ana
Summary: The thermodynamic and electrochemical properties of Ag+ ions in ChCl and G mixture were investigated, and MD and DFT methods were used for computational simulation. The specific mass, speed of sound, viscosity, and refractive index of the solution were measured at different temperatures. The electrochemical behavior of Ag+ ions was analyzed by cyclic voltammetry, and silver coatings were successfully electrodeposited on the Au surface. SEM analysis revealed the surface morphologies of the electrodeposits. The computational calculation showed that adding silver nitrate to the eutectic solvent had a predominant repulsive effect and negligible influence on sound velocity and refractive index. MD simulations demonstrated a strong interaction between Ag+ ions and Cl ions.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Inorganic & Nuclear
M. Vidhya, T. M. Selvakumari, R. Marnadu, I. M. Ashraf, Mohd. Shkir
Summary: This work describes the successful formation of two-dimensional MoS2 nanoflakes using temperature varying hydrothermal method and their application as effective electrode material for high performance supercapacitors. The electrode material prepared at 160 degrees Celsius exhibits the best supercapacitive performances.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Chemistry, Physical
S. Rajkumar, R. Subha, S. Gowri, A. Bella, J. Princy Merlin
Summary: The study successfully synthesized aminophenol-modified zinc oxide, which showed excellent electrochemical performance and is suitable for supercapacitors.
Article
Materials Science, Multidisciplinary
D. Vasanth Raj, N. Ponpandian, C. Viswanathan
Summary: Potentiostatic electrodeposition of SnO2 thin films from an oxygenated tin chloride bath on anodised copper substrates has been achieved at a bath temperature of 85 degrees C. The evolution of nanoplates, nanoparticles and nanocubes are observed at this temperature. The SnO2 nanostructures exhibit excellent performance as electrode materials for aqueous lithium batteries and show remarkable electro catalytic activity towards the oxidation of ascorbic acid (AA).
MATERIALS SCIENCE AND TECHNOLOGY
(2023)
Article
Chemistry, Physical
Rusiri Rathnasekara, Grant Mayberry, Parameswar Hari
Summary: In this study, the thermoelectric, electrochemical, and dielectric properties of four different ZnO morphologies were investigated. ZnO nanorods exhibited the most favorable properties in terms of thermoelectric, electrochemical, and dielectric performance.
Article
Chemistry, Multidisciplinary
S. Rai, R. Bhujel, M. Khadka, R. L. Chetry, B. P. Swain, J. Biswas
Summary: In this study, ZnO/reduced graphene oxide (ZnG) nanohybrid was successfully fabricated using a non-hazardous material, ascorbic acid. The nanohybrid exhibited excellent morphology, structure, and performance, with a specific capacitance value of 345 Fg(-1) and good capacitance retention after 1,000 cycles in an electrolyte of 0.5 M H2SO4.
MATERIALS TODAY CHEMISTRY
(2021)
Article
Electrochemistry
Alassane Sorgho, El Amine Mernissi Cherigui, Moussa Bougouma, Fadi Kamal Aldibaja, Bernard Nisol, Francois Reniers, Claudine Buess-Herman, Thomas Doneux
Summary: The electrodeposition of copper-selenium binary compounds on a gold electrode is investigated in ChCl-U deep eutectic solvent. The formation of Cu2Se is observed through cyclic voltammetry and potentiostatic deposition followed by stripping voltammetries, and is supported by X-Ray Photoelectron Spectroscopy. The electrochemical stability domain of the compound is limited by the oxidation of Se(0) and reduction of Cu(0). Copper is kinetically favored in the co-deposition process, and requires longer deposition times or more negative potentials to avoid pure copper deposition.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Analytical
Chaimaa El Haimer, Youssef Lghazi, Jihane Bahar, Boubaker Youbi, Mohammed Ait Himi, Aziz Aynaou, Itto Bimaghra
Summary: The semiconductor Bi2Se3 layers were successfully deposited on ITO substrate via electrochemical deposition. The electrochemical behavior of Bi2Se3 was investigated, and it was found that the electrodeposition process was controlled by diffusion and followed a 3D instantaneous nucleation model. The resulting layers exhibited a specific structure and stoichiometric ratio, as confirmed by X-ray diffraction and EDS analysis.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2022)
Article
Nanoscience & Nanotechnology
Huali Li, Shuwen Luo, Liuqin Zhang, Zilong Zhao, Min Wu, Weihua Li, Fa-Qian Liu
Summary: The study successfully achieved long-term antifouling by establishing a special antifouling unit that locked copper ions, improved stability, and achieved slow release. Cu2O@Cu-MOF nanocapsules exhibit stable, controlled, and efficient release of copper ions in water and acidic environments.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Engineering, Environmental
Wanfeng Li, Licheng Wei, Ting Shen, Yanan Wei, Kuijiao Li, Faqian Liu, Weihua Li
Summary: This study successfully developed a layered-closed heterojunction photo-anode, exhibiting highly stable and sensitive photoelectrochemical protection performance in 3.5 wt% NaCl without the need for hole scavenging agents.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Chemical
Zhiwei Chen, Yu Liu, Weihua Li, Honglai Liu
Summary: A novel reaction-diffusion model combining BV equation and TDDFT was proposed to investigate the interfacial effect and molecular correlations in metal corrosion. The model successfully predicted the corrosion process of various metals and demonstrated the significance of interfacial effect.
CHEMICAL ENGINEERING SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Li Sun, Tianyu Zhao, Jie Qiu, Yangting Sun, Kuijiao Li, Haibing Zheng, Yiming Jiang, Yanhui Li, Jin Li, Weihua Li, Digby D. Macdonald
Summary: Passivity breakdown on HDSS 2707 has been studied and interpreted using the Point Defect Model. Pitting parameters of HDSS 2707, such as polarizability at bl/s interface, defect annihilation rate, and defect diffusion coefficient, have been determined. The breakdown potential is shown to have linear relationships with log [Br-], pH, and the square root of potential scan rate (v1/2), following a near-normal distribution. The critical vacancy concentration calculated from the PDM aligns with crystallographic estimates from the chromic barrier layer, and the dominant point defect is confirmed through Mott-Schottky measurements.
Article
Electrochemistry
Yumei Zhang, Hui Bao, Xiaoyan Liu, Xiaoying Zhang, Haiyan He, Tianyu Li, Heng Yang, Surendra P. Shah, Weihua Li
Summary: In this study, the photoelectrochemical cathodic protection performance was improved by modifying ZnO nanowires. The modified Bi2S3/ZnO heterostructure thin-film showed improved photo-response in the visible light range and effectively protected stainless steel and carbon steel.
JOURNAL OF APPLIED ELECTROCHEMISTRY
(2022)
Article
Polymer Science
Ran Deng, Liangpeng Zeng, Qing-Yun Wu, Weihua Li
Summary: Corrosion and biofouling pose severe threats to engineering equipment and materials. Oil-impregnated gel (OIG) shows promise for corrosion protection and biofouling prevention, but its weak mechanical strength has limited its applications. A self-repairable OIG coating based on the reversible sol-gel process of a specific copolymer and n-hexadecane was developed, showing outstanding sliding properties, bacterial repellence, and in-situ repair capabilities.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Engineering, Mechanical
Kuijiao Li, Li Sun, Zhiwei Chen, Si Chen, Weihua Li
Summary: Electrochemical tests were conducted to investigate the synergistic effects of chloride, sulfate, and carbonate ions on pitting. The results revealed that sulfate ions initially increased the pitting potential of 316L, reaching a peak at 0.2 M concentration, before decreasing. At this concentration, the highest critical pitting temperature, breakdown potential, and maximum impedance were obtained. On the other hand, carbonate ions increased the pitting potential but accelerated the general corrosion of the 316L surface. The study proposed an effective adsorption area based on the competitive adsorption mechanism to explain the pitting and passivation behaviors of 316L, and comprehensively analyzed the properties of the passive film.
ENGINEERING FAILURE ANALYSIS
(2022)
Article
Chemistry, Physical
Qiu-Ping Li, Xin-Liu, Xian-Lian Mu, Fa-Qian Liu, Hao-Wei Wang, Weihua Li
Summary: The UIO-66/Bi2S3 photoanode prepared through solvothermal method demonstrates enhanced redox reaction activity and charge carrier migration capability, providing effective protection for stainless steel cathodic protection.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Polymer Science
Zhentao Hao, Si Chen, Zhiwei Chen, Zhifeng Lin, Weihua Li
Summary: This study developed a self-healing coating using the water sensitivity of MOF-199. The release of corrosion inhibitors from the porous structure of MOF-199 improved the corrosion resistance performance of the damaged coating.
Article
Engineering, Chemical
Zhentao Hao, Si Chen, Zhifeng Lin, Weihua Li
Summary: A composite coating with self-healing function under accessible sunlight was developed by incorporating Fe3O4 nanoparticles and tetradecanol into epoxy resin. The Fe3O4 nanoparticles exhibited excellent photothermal properties and rapid thermal response under simulated solar irradiation. The tetradecanol can flow and fill defects through phase transition at low temperatures. The healed coating effectively protected the underlying carbon steel, making it a promising candidate for various engineering applications.
FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING
(2022)
Article
Construction & Building Technology
Ning Yang, Chandra Sekhar Das, Xiao Xue, Weihua Li, Jian-Guo Dai
Summary: A geopolymer anti-corrosion coating modified with in-situ reduced graphene oxide (RGO) was developed in this study, and its corrosion resistance and physicochemical properties were investigated. By optimizing the graphene oxide (GO) content, the corrosion resistance of geopolymer-coated steel was significantly improved. The study also explored the corrosion protection mechanism with RGO modification.
CONSTRUCTION AND BUILDING MATERIALS
(2022)
Article
Chemistry, Physical
Tao Ji, Xiao Liao, Shiping Zhang, Yan He, Xiaoying Zhang, Xiong Zhang, Weihua Li
Summary: Researchers developed a thermoelectric device using PANI/MnO2 composite in cement-based material, which showed improved electrical conductivity and Seebeck coefficient. The device effectively protected carbon steel from corrosion in alkaline chloride solution.
Article
Construction & Building Technology
Mengzhu Chen, Yanan Wei, Haibing Zheng, Linwen Yu, Qiang Liu, Yiren Wang, Huihui Yuan, Chong Wang, Weihua Li
Summary: This paper investigates the corrosion inhibition performance of Ca-Al-NO3 layered double hydroxides (Ca-LDH) modified cementitious coatings on steel bars. The results show that the incorporation of CaLDH increases the chloride consolidation ability of cement paste, effectively inhibiting corrosion of steel bars.
JOURNAL OF BUILDING ENGINEERING
(2022)
Article
Materials Science, Multidisciplinary
Liangpeng Zeng, Hongyuan Cui, Huilan Peng, Xiaohang Sun, Yi Liu, Jingliang Huang, Xinxing Lin, Hui Guo, Wei-Hua Li
Summary: Due to their semi-solid property and lubricant ability, organogels have potential applications in antifouling. However, their poor mechanical properties limit their practical use. In this study, a simple and effective method was developed to enhance the mechanical performance and surface lubrication of organogels using oleophobic and oleophilic chains. The reinforced organogels showed superior mechanical properties compared to traditional organogels, and demonstrated reduced protein and bacteria adhesion, making them promising materials for various functional requirements.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2022)
Article
Polymer Science
Liangpeng Zeng, Ziqi Liu, Jingliang Huang, Xiaolin Wang, Hui Guo, Wei-Hua Li
Summary: Recently invented hydrophobic hydrogels exhibit excellent anti-fouling ability, which is mainly attributed to their surface hydrophobicity, while excessive water content might be detrimental.